**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1498-51-7 |Ethyl dichlorophosphate | 97 | 216-099-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ C
Risk Phrases: 22 26 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Very toxic by inhalation. Causes
burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. May cause systemic effects.
Inhalation:
May be fatal if inhaled. May cause severe irritation of the
respiratory tract with sore throat, coughing, shortness of breath
and delayed lung edema. Causes chemical burns to the respiratory
tract. Aspiration may lead to pulmonary edema. May cause systemic
effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Do NOT get water inside containers. Cool containers with flooding
quantities of water until well after fire is out. In case of fire,
use carbon dioxide, dry chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Do
not allow contact with water. Discard contaminated shoes. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1498-51-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear light brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 60.0 - 65.0 deg C @ 10.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3730 g/cm3
Molecular Formula: C2H5Cl2O2P
Molecular Weight: 162.94
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus,
irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1498-51-7: TD4390000
LD50/LC50:
CAS# 1498-51-7: Inhalation, rat: LC50 = 564 mg/m3; Oral, rat: LD50 =
220 mg/kg; Skin, rabbit: LD50 = 2350 mg/kg.
Oral, rat: LD50 = 200 mg/kg.
mg/m3.
Carcinogenicity:
Ethyl dichlorophosphate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 22 Harmful if swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 1498-51-7: No information available.
Canada
CAS# 1498-51-7 is listed on Canada's NDSL List.
CAS# 1498-51-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1498-51-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Melamine, P.A.
| 108-78-1 |
|
Chlorodifluoroacetic Acid, 98%
| 76-04-0 |
|
O-Anisic Acid, 99%
| 579-75-9 |
|
3,4'-Dichloropropiophenone, 95%
| 3946-29-0 |
|
cis-3-Hexen-1-ol, 98%
| 928-96-1 |
|
2,4,6-Tribromophenol, 98%
| 118-79-6 |
|
1-Ethyl-3-Piperidone Hydrochloride, 97%
| 41361-28-8 |
|
Propionyl chloride, 98%
| 79-03-8 |
|
n-Methylhippuric acid, 99%
| 2568-34-5 |
|
2-Hydroxybenzyl Alcohol, 97%
| 90-01-7 |
|
3-Acetamidophenol, 99+%
| 621-42-1 |
|
2-(4-Chlorobenzyl)pyridine
| 4350-41-8 |
|
2,5-Diaminopyridine dihydrochloride, 98%
| 26878-35-3 |
|
1-(4-Chlorophenyl)-1-Cyclopropanemethanol, 98%
| 80866-81-5 |
|
Ethyl dichlorophosphate, 97%
| 1498-51-7 |
|
Merocyanine 540, 99% (UV-Vis)
| 62796-23-0 |
|
Thallous Malonate, 98% (Titr.)
| 2757-18-8 |
|
Thiofluorescein, 99% (uv-vis)
| 25319-73-3 |
|
N,N-Diethyl-P-Toluidine, 99% (GC)
| 613-48-9 |
|
Hexyl isocyanate, 99% (GC)
| 2525-62-4 |
|
1-(4-Chlorophenyl)-1-Cyclopropane- Carbonitrile 98%
| 64399-27-5 |
|
(-)-2,3-o-isopropylidene-2,3-dihydroxy-
| 32305-98-9 |
|
1-(4-Methylphenyl)-1-Cyclopropane Carboxylic Acid, 98%
| 0-00-1 |
|
Palladium(ii) bromide
| 13444-93-4 |
|
2,5-Dimethoxytetrahydrofuran, 99%, mixture of cis- and trans- isomers
| 696-59-3 |
|
Ethyl formate, 98+%
| 109-94-4 |
|
Gallium(iii) nitrate hydrate, 99.9998%,
| 13494-90-1 |
|
4-Nitrophenyl trimethylacetate, 98+%
| 4195-17-9 |
|
DL-10-Camphorsulfonic Acid, 98%
| 5872-08-2 |
|
Anthracene, 98%
| 120-12-7 |
|
4-Cyanophenyl Isocyanate, 95% (HPLC)
| 40465-45-0 |
|
2-Furoyl chloride, 98+% (gc)
| 527-69-5 |
|
Nitron, 95% (UV-VIS)
| 2218-94-2 |
|
Benzyltriphenylphosphonium chloride, 98%
| 1100-88-5 |
|
4-Chloro-2-Fluorobenzonitrile, 99.5+%
| 57381-51-8 |
|
Trans-3-Chloroacrylic Acid, 99%
| 2345-61-1 |
|
2-Thiouracil, 99% (UV-Vis)
| 141-90-2 |
|
Dl-threonine, 99.5%
| 80-68-2 |
|
4-Phenyl-1,3-Dioxane, 99+%
| 772-00-9 |
|
N-Methylanilinium Trifluoroacetate, 99%
| 29885-95-8 |
|
Phloroglucinol anhydr., min. 99%(gc)
| 108-73-6 |
|
Pyrene, 98+%(gc)
| 129-00-0 |
|
2-Iodotoluene, 98%
| 615-37-2 |
|
4,4' -Azoxyanisole, 98+%
| 1562-94-3 |
|
2-Fluorobenzyl alcohol, 98%
| 446-51-5 |
|
Bbd
| 18378-20-6 |
|
Ethylene glycol monoethyl ether
| 110-80-5 |
|
4',5'-Dibromofluorescein
| 596-03-2 |
|
Ethylene Glycol Monoethyl Ether Acetate
| 111-15-9 |
|
1-[(3-Nitrobenzyloxy)methyl] pyridinium chloride, 99% (titr.)
| 3009-13-0 |
|
|