**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1146-65-2 |Naphthalene-d8 | 98+ | 214-552-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause lacrimation (tearing), blurred vision, and photophobia.
May cause chemical conjunctivitis and corneal damage. Absorption of
more than 15 ppm into the eye may cause cataracts, optical neuritis,
corneal injury, and eye irritation.
Skin:
May be harmful if absorbed through the skin. May cause skin
irritation and possible burns.
Ingestion:
May cause liver and kidney damage. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, and death. May cause severe digestive
tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Exposure may cause anemia and other blood abnormalities. May be
harmful if swallowed. May cause nausea, vomiting, abdominal pain, and
increased salivation.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. Olfactory fatigue may occur. Can
produce delayed pulmonary edema. Material volatilizes at room
temperature.
Chronic:
Chronic inhalation, skin absorption or ingestion of naphthalene have
caused severe hemolytic anemia.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Individuals with a glucose-6-phosphate dehyrogenase deficiency are
hypersensitive to the effects of naphthalene.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Dust can be an
explosion hazard when exposed to heat or flame. Flammable solid. May
burn rapidly with flare burning effect. May re-ignite after fire is
extinguished.
Extinguishing Media:
Use carbon dioxide or dry chemical. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Scoop up with a nonsparking tool, then place into a suitable
container for disposal. Avoid generating dusty conditions. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Use spark-proof tools and explosion
proof equipment. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Take precautionary measures
against static discharges. Keep away from heat, sparks and flame. Do
not get on skin or in eyes. Do not ingest or inhale. Use only in a
chemical fume hood. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture. Separate from oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 1146-65-2:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: 0.3 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 81 - 83 deg C
Autoignition Temperature: 979 deg F ( 526.11 deg C)
Flash Point: 174 deg F ( 78.89 deg C)
Explosion Limits, lower: 0.9 vol %
Explosion Limits, upper: 5.9 vol %
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C10D8
Molecular Weight: 136.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1146-65-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Naphthalene-d8 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing Group: III
IMO
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing Group: III
RID/ADR
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1146-65-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1146-65-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1146-65-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ytterbium, 99,9%, -12 mm
| 7440-64-4 |
|
5-Chloro-1-indanone, 98%
| 42348-86-7 |
|
2-Methyl-1-butanethiol, 95%
| 1878-18-8 |
|
2-Methyl-3-Nitrobenzyl Chloride
| 60468-54-4 |
|
3-Methoxypropylamine, 99+%
| 5332-73-0 |
|
Eicosane, 99%
| 112-95-8 |
|
3-Benzylpyridine, 97%
| 620-95-1 |
|
Chloro-(chloromethyl)-dimethylsilane, 98%
| 1719-57-9 |
|
Rhodium on 1/8-inch alumina pellets ( 0.5% rh)
| |
|
3-Methyl-1-hexene, 99%
| 3404-61-3 |
|
4-Fluorobenzimidazole-2-carboxylic acid
| 83431-74-7 |
|
(S)-(-)-5-(Hydroxymethyl)-2(5H)-furanone, 99% (99% e.e.)
| 78508-96-0 |
|
2-Acetylthiophene, 98%, Balance Mainly 3-Acetylthiophene
| 88-15-3 |
|
Phenylphosphinic acid sodium salt (50% aqueous solution), 46% (titr.)
| 4297-95-4 |
|
m-(Hydrazinosulfonyl)benzoic acid, 99%
| 7385-52-6 |
|
2-Hydroxyquinoline, 99% (UV-VIS)
| 59-31-4 |
|
Acrylamido Glycolic Acid, Anhydrous, 98%
| 6737-24-2 |
|
Naphthalene-d8, 98+ atom % D
| 1146-65-2 |
|
N-Ethyl-m-toluidine, 99+%
| 102-27-2 |
|
Thiazole, 99%
| 288-47-1 |
|
Ferrozine Iron Reagent, Monohydrate, 95+% (UV-Vis)
| 69898-45-9 |
|
1-(4-Methoxyphenyl)-2-methylpiperazine
| 35947-12-7 |
|
7-(2-Chloroethyl)-Theophylline, 97%
| 5878-61-5 |
|
Ammonium Hexabromoplatinate(IV), 99.99%
| 17363-02-9 |
|
2,3-Dibromopropanol, 96%
| 96-13-9 |
|
4-(Methylamino)butyric acid hydrochloride, 99%
| 6976-17-6 |
|
1,3-Propanediol, 98%
| 504-63-2 |
|
2-Fluorobenzylamine, 96%
| 89-99-6 |
|
L-Arabinose
| 5328-37-0 |
|
4-N,N-Dimethylaminoazobenzene-4'-isothiocyanate
| 7612-98-8 |
|
DL-aspartic acid magnesium salt tetrahydrate, 98%
| 215528-79-3 |
|
2-(Diisopropylamino)ethyl Chloride Hydro-Chloride, 97%
| 4261-68-1 |
|
5-Methoxysalicylic Acid, 98%
| 2612-02-4 |
|
1,2-Benzisoxazole, 95%
| 271-95-4 |
|
2,2'-(1,2-Ethenediyldi-4,1-Phenylene)- Bisbenzoxazole
| 1533-45-5 |
|
6,7-Dimethoxy-1,2,3,4-Tetrahydroisoquinoline-1-Thione, 99%
| 24456-59-5 |
|
3,3'-Dichloropivalic Acid, 99%
| 67329-11-7 |
|
3-Indoleacrylic acid, 99%
| 1204-06-4 |
|
1,2,3,6,7,8-Hexahydropyrene,98%
| 1732-13-4 |
|
9H-fluorene-4-carboxylic acid, 96%
| 6954-55-8 |
|
Methylamine Hydrochloride, P.A.
| 593-51-1 |
|
Potassium superoxide (chunks)
| 12030-88-5 |
|
N-Methyl-N-(trimethylsilyl)acetamide, 99%
| 7449-74-3 |
|
1-[4,4-Bis(4-fluorophenyl)butyl]piperazine
| 5631-35-6 |
|
2-(2-Hydroxyethyl)Pyridine, 99%
| 103-74-2 |
|
Scandium(iii)nitrate hydrate, 99.9%
| |
|
9,10-Diphenylanthracene, 99%
| 1499-10-1 |
|
Nocodazole 99+%
| 31430-18-9 |
|
1-Octanesulfonic Acid Sodium Salt, 99+%, HPLC Grade anhydrous
| 5324-84-5 |
|
Barium perchlorate, anhydrous, 99%
| 13465-95-7 |
|
|