**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 88-15-3 |2-Acetylthiophene | 98 | 201-804-6 |
|----------------|--------------------------------------|----------|-----------|
| 1468-83-3 |3-Acetylthiophene | 2.0 | 215-996-4 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Stench.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Aspiration may lead to pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 88-15-3:
CAS# 1468-83-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless or slight yellow
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 214 deg C @ 760.00mm Hg
Freezing/Melting Point: 10 - 11 deg C
Autoignition Temperature: Not available.
Flash Point: 91 deg C ( 195.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1680g/cm3
Molecular Formula: (C4H3S)COCH3
Molecular Weight: 126.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 88-15-3: OB6300000
CAS# 1468-83-3 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
2-Acetylthiophene -
Not listed by ACGIH, IARC, or NTP.
3-Acetylthiophene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 88-15-3: No information available.
CAS# 1468-83-3: No information available.
Canada
CAS# 88-15-3 is listed on Canada's DSL List.
CAS# 88-15-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 1468-83-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-15-3 is listed on the TSCA inventory.
CAS# 1468-83-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ytterbium, 99,9%, -12 mm
| 7440-64-4 |
|
5-Chloro-1-indanone, 98%
| 42348-86-7 |
|
2-Methyl-1-butanethiol, 95%
| 1878-18-8 |
|
2-Methyl-3-Nitrobenzyl Chloride
| 60468-54-4 |
|
3-Methoxypropylamine, 99+%
| 5332-73-0 |
|
Eicosane, 99%
| 112-95-8 |
|
3-Benzylpyridine, 97%
| 620-95-1 |
|
Chloro-(chloromethyl)-dimethylsilane, 98%
| 1719-57-9 |
|
Rhodium on 1/8-inch alumina pellets ( 0.5% rh)
| |
|
3-Methyl-1-hexene, 99%
| 3404-61-3 |
|
4-Fluorobenzimidazole-2-carboxylic acid
| 83431-74-7 |
|
(S)-(-)-5-(Hydroxymethyl)-2(5H)-furanone, 99% (99% e.e.)
| 78508-96-0 |
|
2-Acetylthiophene, 98%, Balance Mainly 3-Acetylthiophene
| 88-15-3 |
|
Phenylphosphinic acid sodium salt (50% aqueous solution), 46% (titr.)
| 4297-95-4 |
|
m-(Hydrazinosulfonyl)benzoic acid, 99%
| 7385-52-6 |
|
2-Hydroxyquinoline, 99% (UV-VIS)
| 59-31-4 |
|
Acrylamido Glycolic Acid, Anhydrous, 98%
| 6737-24-2 |
|
Naphthalene-d8, 98+ atom % D
| 1146-65-2 |
|
N-Ethyl-m-toluidine, 99+%
| 102-27-2 |
|
Thiazole, 99%
| 288-47-1 |
|
Ferrozine Iron Reagent, Monohydrate, 95+% (UV-Vis)
| 69898-45-9 |
|
1-(4-Methoxyphenyl)-2-methylpiperazine
| 35947-12-7 |
|
7-(2-Chloroethyl)-Theophylline, 97%
| 5878-61-5 |
|
Ammonium Hexabromoplatinate(IV), 99.99%
| 17363-02-9 |
|
2,3-Dibromopropanol, 96%
| 96-13-9 |
|
4-(Methylamino)butyric acid hydrochloride, 99%
| 6976-17-6 |
|
1,3-Propanediol, 98%
| 504-63-2 |
|
2-Fluorobenzylamine, 96%
| 89-99-6 |
|
L-Arabinose
| 5328-37-0 |
|
4-N,N-Dimethylaminoazobenzene-4'-isothiocyanate
| 7612-98-8 |
|
DL-aspartic acid magnesium salt tetrahydrate, 98%
| 215528-79-3 |
|
2-(Diisopropylamino)ethyl Chloride Hydro-Chloride, 97%
| 4261-68-1 |
|
5-Methoxysalicylic Acid, 98%
| 2612-02-4 |
|
1,2-Benzisoxazole, 95%
| 271-95-4 |
|
2,2'-(1,2-Ethenediyldi-4,1-Phenylene)- Bisbenzoxazole
| 1533-45-5 |
|
6,7-Dimethoxy-1,2,3,4-Tetrahydroisoquinoline-1-Thione, 99%
| 24456-59-5 |
|
3,3'-Dichloropivalic Acid, 99%
| 67329-11-7 |
|
3-Indoleacrylic acid, 99%
| 1204-06-4 |
|
1,2,3,6,7,8-Hexahydropyrene,98%
| 1732-13-4 |
|
9H-fluorene-4-carboxylic acid, 96%
| 6954-55-8 |
|
Methylamine Hydrochloride, P.A.
| 593-51-1 |
|
Potassium superoxide (chunks)
| 12030-88-5 |
|
N-Methyl-N-(trimethylsilyl)acetamide, 99%
| 7449-74-3 |
|
1-[4,4-Bis(4-fluorophenyl)butyl]piperazine
| 5631-35-6 |
|
2-(2-Hydroxyethyl)Pyridine, 99%
| 103-74-2 |
|
Scandium(iii)nitrate hydrate, 99.9%
| |
|
9,10-Diphenylanthracene, 99%
| 1499-10-1 |
|
Nocodazole 99+%
| 31430-18-9 |
|
1-Octanesulfonic Acid Sodium Salt, 99+%, HPLC Grade anhydrous
| 5324-84-5 |
|
Barium perchlorate, anhydrous, 99%
| 13465-95-7 |
|
|