**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 122-59-8 |Phenoxyacetic acid | 98+ | 204-556-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause digestive tract disturbances. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Use with adequate ventilation.
Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 122-59-8:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 285 deg C (some decompn)
Freezing/Melting Point: 98 - 100 deg C
Autoignition Temperature: Not available.
Flash Point: 165 deg C ( 329.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 285 deg C
Solubility in water: 1 g/75 ml
Specific Gravity/Density:
Molecular Formula: C8H8O3
Molecular Weight: 152.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 122-59-8: AJ2230000
LD50/LC50:
CAS# 122-59-8: Draize test, rabbit, skin: 500 mg/24H Mild; Oral,
mouse: LD50 = 3750 mg/kg; Oral, rabbit: LD50 = >200 mg/kg; Oral, rat:
LD50 = 1500 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Dermal, rabbit: LD50 = > 5 gm/kg
Carcinogenicity:
Phenoxyacetic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Harmful to plant life.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 122-59-8: No information available.
Canada
CAS# 122-59-8 is listed on Canada's DSL List.
CAS# 122-59-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 122-59-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/29/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorobenzyl Alcohol, 99+%
| 873-63-2 |
|
N-(2-Hydroxyethyl)-1,3-propanediamine, 97+%
| 4461-39-6 |
|
Tetrabutylammonium tetrafluoroborate, 99%
| 429-42-5 |
|
Adamantane, 99+%
| 281-23-2 |
|
3-Carbomethoxy-2-Pyrone, 99% (GC)
| 25991-27-9 |
|
Aflatoxin B2, crystalline
| 7220-81-7 |
|
2,2,6,6-Tetramethyl-4-Piperidone, Monohydrate, 98% (GC)
| 826-35-7 |
|
4-Ethoxymethylene-2-Phenyl-2-Oxazolin- 5-One, 97%
| 15646-46-5 |
|
Drimarene Red Z 2B, 78% (HPLC)
| 15792-41-3 |
|
Carbol Fuchsin Solution
| 64-17-5 |
|
Fehling Solution, Part A
| 7732-18-5 |
|
Buffer Solution pH 10
| 584-08-7 |
|
Buffer Solution pH 7
| 1310-73-2 |
|
4-Normal-Butoxyphenol, 99%
| 122-94-1 |
|
Buffer Solution pH 10.0 (Color-Coded Blue)
| 584-08-7 |
|
9-Methylanthracene, 99%
| 779-02-2 |
|
Phenoxyacetic acid, 98+%
| 122-59-8 |
|
5-(4-Hydroxyphenyl)-5-(p-tolyl)hydantoin, 99%
| 71766-23-9 |
|
Barium Chloranilate Trihydrate
| 13435-46-6 |
|
N-(Trimethylsilyl)acetamide, 97%
| 13435-12-6 |
|
2,4,6-Trimethoxybenzaldehyde, 98%
| 830-79-5 |
|
(1R,2R,3S,5R)-(-)-2,3-Pinanediol, 98%
| 22422-34-0 |
|
Dimethyl Sulfate
| 77-78-1 |
|
6-Hydroxynicotinic Acid, 99%
| 5006-66-6 |
|
2-Chlorocyclohexanone, 95%, Stabilized with CaCO3/MgO
| 822-87-7 |
|
n-Nonylamine, 98%
| 112-20-9 |
|
Oxamic Acid, Sodium Salt, 98%
| 565-73-1 |
|
Alpha-Terthienyl,99+%
| 1081-34-1 |
|
4-Pyridinecarboxaldehyde, 98%
| 872-85-5 |
|
4-3-(Trifluoromethyl)Phenyl??-4-Piperidino L Hydrochloride, 99% (TLC)
| 1683-49-4 |
|
1,3-Diphenylisobenzofuran, 99+%
| 5471-63-6 |
|
(S)-2-??n'-(N-Benzylprolyl)Amino??Benzo-Phenone, 99.5+%
| 96293-17-3 |
|
Sebaconitrile, 98% (GC)
| 1871-96-1 |
|
Tricyclohexyl Phosphine
| 2622-14-2 |
|
3-Ethoxyacrylonitrile, 98+%, mixture of cis and trans
| 61310-53-0 |
|
2-Chloro-5-(trifluoromethyl)pyridine 98+%
| 52334-81-3 |
|
Diisopropyl fluorophosphate
| 55-91-4 |
|
2,3,6-Trichlorobenzaldehyde,98%
| 4659-47-6 |
|
2-Diethylaminoethyl Chloride Hydrochloride, 99.5%
| 869-24-9 |
|
Tetramethylene glutarimide,99%
| 1075-89-4 |
|
1,4-Diacetoxybenzene, 98%
| 1205-91-0 |
|
2-Chloropyrimidine, 98+%
| 1722-12-9 |
|
5(6)-Carboxyfluorescein, 99% (UV-VIS)
| 72088-94-9 |
|
Silver Cyclohexanebutyrate
| 62638-04-4 |
|
1,2-Benzenedimethanol, 97%
| 612-14-6 |
|
4-Nitrobenzamide, 98%
| 619-80-7 |
|
Potassium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
D(-)-Lyxose, 99+%, Mixture of Anomers
| 1114-34-7 |
|
Neodymium atomic absorption standard solution, 1 mg/ml Nd in 2% HNO3
| 7440-00-8 |
|
1,3-Dihydroxynaphthalene,99+%
| 132-86-5 |
|
|