**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1871-96-1 |Sebaconitrile | 98% | 217-494-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause skin irritation. May be metabolized to cyanide which in
turn acts by inhibiting cytochrome oxidase impairing cellular
respiration. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause central nervous
system depression. Metabolism may release cyanide, which may result
in headache, dizziness, weakness, collapse, unconsciousness and
possible death.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. May cause cardiac abnormalities. May be metabolized
to cyanide which in turns act by inhibiting cytochrome oxidase
impairing cellular respiration. Inhalation at high concentrations may
cause CNS depression and asphixiation.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. Effects may be
delayed. Chronic exposure to cyanide solutions may lead to the
development of a "cyanide" rash, characterized by itching, and by
macular, papular, and vesicular eruptions, and may be accompanied by
secondary infections.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Get medical
aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
May be partially metabolized to cyanide in the body.
Antidote:
Always have a cyanide antidote kit on hand when working with cyanide
compounds. Get medical advice to use.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1871-96-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 7 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 93 deg C (> 199.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9130g/cm3
Molecular Formula: C10H16N2
Molecular Weight: 164.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1871-96-1: VS1500000
LD50/LC50:
CAS# 1871-96-1: Oral, mouse: LD50 = 165 mg/kg.
Carcinogenicity:
Sebaconitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1871-96-1: 1
Canada
CAS# 1871-96-1 is listed on Canada's NDSL List.
CAS# 1871-96-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1871-96-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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Tetrabutylammonium tetrafluoroborate, 99%
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3-Carbomethoxy-2-Pyrone, 99% (GC)
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4-Ethoxymethylene-2-Phenyl-2-Oxazolin- 5-One, 97%
| 15646-46-5 |
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Drimarene Red Z 2B, 78% (HPLC)
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Carbol Fuchsin Solution
| 64-17-5 |
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Fehling Solution, Part A
| 7732-18-5 |
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Buffer Solution pH 10
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Buffer Solution pH 7
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Buffer Solution pH 10.0 (Color-Coded Blue)
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| 71766-23-9 |
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Barium Chloranilate Trihydrate
| 13435-46-6 |
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N-(Trimethylsilyl)acetamide, 97%
| 13435-12-6 |
|
2,4,6-Trimethoxybenzaldehyde, 98%
| 830-79-5 |
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(1R,2R,3S,5R)-(-)-2,3-Pinanediol, 98%
| 22422-34-0 |
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Dimethyl Sulfate
| 77-78-1 |
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6-Hydroxynicotinic Acid, 99%
| 5006-66-6 |
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| 822-87-7 |
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| 112-20-9 |
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Oxamic Acid, Sodium Salt, 98%
| 565-73-1 |
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Alpha-Terthienyl,99+%
| 1081-34-1 |
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4-Pyridinecarboxaldehyde, 98%
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1,3-Diphenylisobenzofuran, 99+%
| 5471-63-6 |
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| 1871-96-1 |
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| 2622-14-2 |
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| 61310-53-0 |
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2-Chloro-5-(trifluoromethyl)pyridine 98+%
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Diisopropyl fluorophosphate
| 55-91-4 |
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2,3,6-Trichlorobenzaldehyde,98%
| 4659-47-6 |
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2-Diethylaminoethyl Chloride Hydrochloride, 99.5%
| 869-24-9 |
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Tetramethylene glutarimide,99%
| 1075-89-4 |
|
1,4-Diacetoxybenzene, 98%
| 1205-91-0 |
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2-Chloropyrimidine, 98+%
| 1722-12-9 |
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Silver Cyclohexanebutyrate
| 62638-04-4 |
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| 612-14-6 |
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4-Nitrobenzamide, 98%
| 619-80-7 |
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| 109-99-9 |
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| 1114-34-7 |
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Neodymium atomic absorption standard solution, 1 mg/ml Nd in 2% HNO3
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| 132-86-5 |
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