**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4461-39-6 |N-(2-Hydroxyethyl)-1,3-propanediamine | 97+ | 224-718-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns.Corrosive.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. The toxicological properties of this
substance have not been fully investigated. May cause systemic
effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated. May
cause systemic effects.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Do not breathe dust, vapor, mist, or gas. Keep container
tightly closed. Avoid ingestion and inhalation. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4461-39-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: 11-12 (20g/L aq. soln)
Vapor Pressure: <0.1 mbar @ 20
Viscosity: 164 mPas 20 deg C
Boiling Point: 255 deg C @ 760.00mm Hg
Freezing/Melting Point: 15-19 deg C
Autoignition Temperature: 325 deg C ( 617.00 deg F)
Flash Point: 152 deg C ( 305.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: miscible
Specific Gravity/Density: 1.0070g/cm3
Molecular Formula: C5H14N2O
Molecular Weight: 118.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Moisture, excess heat.
Incompatibilities with Other Materials:
Acidic conditions, acids, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia
(NH3).
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4461-39-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-(2-Hydroxyethyl)-1,3-propanediamine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: II
IMO
Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: II
RID/ADR
Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4461-39-6: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4461-39-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4461-39-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 10/28/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorobenzyl Alcohol, 99+%
| 873-63-2 |
|
N-(2-Hydroxyethyl)-1,3-propanediamine, 97+%
| 4461-39-6 |
|
Tetrabutylammonium tetrafluoroborate, 99%
| 429-42-5 |
|
Adamantane, 99+%
| 281-23-2 |
|
3-Carbomethoxy-2-Pyrone, 99% (GC)
| 25991-27-9 |
|
Aflatoxin B2, crystalline
| 7220-81-7 |
|
2,2,6,6-Tetramethyl-4-Piperidone, Monohydrate, 98% (GC)
| 826-35-7 |
|
4-Ethoxymethylene-2-Phenyl-2-Oxazolin- 5-One, 97%
| 15646-46-5 |
|
Drimarene Red Z 2B, 78% (HPLC)
| 15792-41-3 |
|
Carbol Fuchsin Solution
| 64-17-5 |
|
Fehling Solution, Part A
| 7732-18-5 |
|
Buffer Solution pH 10
| 584-08-7 |
|
Buffer Solution pH 7
| 1310-73-2 |
|
4-Normal-Butoxyphenol, 99%
| 122-94-1 |
|
Buffer Solution pH 10.0 (Color-Coded Blue)
| 584-08-7 |
|
9-Methylanthracene, 99%
| 779-02-2 |
|
Phenoxyacetic acid, 98+%
| 122-59-8 |
|
5-(4-Hydroxyphenyl)-5-(p-tolyl)hydantoin, 99%
| 71766-23-9 |
|
Barium Chloranilate Trihydrate
| 13435-46-6 |
|
N-(Trimethylsilyl)acetamide, 97%
| 13435-12-6 |
|
2,4,6-Trimethoxybenzaldehyde, 98%
| 830-79-5 |
|
(1R,2R,3S,5R)-(-)-2,3-Pinanediol, 98%
| 22422-34-0 |
|
Dimethyl Sulfate
| 77-78-1 |
|
6-Hydroxynicotinic Acid, 99%
| 5006-66-6 |
|
2-Chlorocyclohexanone, 95%, Stabilized with CaCO3/MgO
| 822-87-7 |
|
n-Nonylamine, 98%
| 112-20-9 |
|
Oxamic Acid, Sodium Salt, 98%
| 565-73-1 |
|
Alpha-Terthienyl,99+%
| 1081-34-1 |
|
4-Pyridinecarboxaldehyde, 98%
| 872-85-5 |
|
4-3-(Trifluoromethyl)Phenyl??-4-Piperidino L Hydrochloride, 99% (TLC)
| 1683-49-4 |
|
1,3-Diphenylisobenzofuran, 99+%
| 5471-63-6 |
|
(S)-2-??n'-(N-Benzylprolyl)Amino??Benzo-Phenone, 99.5+%
| 96293-17-3 |
|
Sebaconitrile, 98% (GC)
| 1871-96-1 |
|
Tricyclohexyl Phosphine
| 2622-14-2 |
|
3-Ethoxyacrylonitrile, 98+%, mixture of cis and trans
| 61310-53-0 |
|
2-Chloro-5-(trifluoromethyl)pyridine 98+%
| 52334-81-3 |
|
Diisopropyl fluorophosphate
| 55-91-4 |
|
2,3,6-Trichlorobenzaldehyde,98%
| 4659-47-6 |
|
2-Diethylaminoethyl Chloride Hydrochloride, 99.5%
| 869-24-9 |
|
Tetramethylene glutarimide,99%
| 1075-89-4 |
|
1,4-Diacetoxybenzene, 98%
| 1205-91-0 |
|
2-Chloropyrimidine, 98+%
| 1722-12-9 |
|
5(6)-Carboxyfluorescein, 99% (UV-VIS)
| 72088-94-9 |
|
Silver Cyclohexanebutyrate
| 62638-04-4 |
|
1,2-Benzenedimethanol, 97%
| 612-14-6 |
|
4-Nitrobenzamide, 98%
| 619-80-7 |
|
Potassium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
D(-)-Lyxose, 99+%, Mixture of Anomers
| 1114-34-7 |
|
Neodymium atomic absorption standard solution, 1 mg/ml Nd in 2% HNO3
| 7440-00-8 |
|
1,3-Dihydroxynaphthalene,99+%
| 132-86-5 |
|
|