**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 93.3 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 7758-98-7 |Cupric sulfate | 6.7 | 231-847-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes eye irritation. Exposure to particulates or solution may
cause conjunctivitis, ulceration, and corneal abnormalities.
Skin:
Causes irritation with burning pain, itching, and redness.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver damage.
Inhalation:
Causes respiratory tract irritation. May cause ulceration and
perforation of the nasal septum if inhaled in excessive quantities.
Chronic:
May cause reproductive and fetal effects. Individuals with Wilson's
disease are unable to metabolize copper. Thus, copper accumulates
in various tissues and may result in liver, kidney, and brain damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 7732-18-5:
CAS# 7758-98-7:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: 0.5 mg/m3 TWA
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: not available
Odor: none reported
pH: Not available.
Vapor Pressure: 14 mm Hg @20C
Viscosity: Not available.
Boiling Point: > 212 deg F
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Completely soluble in water.
Specific Gravity/Density: ~1.0
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Oxides of sulfur, copper fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 7758-98-7: GL8800000
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 7758-98-7: Oral, mouse: LD50 = 369 mg/kg; Oral, mouse: LD50 =
87 mg/kg; Oral, rat: LD50 = 300 mg/kg; Oral, rat: LD50 = 960 mg/kg.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
Cupric sulfate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7758-98-7: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7758-98-7: 2
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7758-98-7 is listed on Canada's DSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7758-98-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7758-98-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/12/1997 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorobenzyl Alcohol, 99+%
| 873-63-2 |
|
N-(2-Hydroxyethyl)-1,3-propanediamine, 97+%
| 4461-39-6 |
|
Tetrabutylammonium tetrafluoroborate, 99%
| 429-42-5 |
|
Adamantane, 99+%
| 281-23-2 |
|
3-Carbomethoxy-2-Pyrone, 99% (GC)
| 25991-27-9 |
|
Aflatoxin B2, crystalline
| 7220-81-7 |
|
2,2,6,6-Tetramethyl-4-Piperidone, Monohydrate, 98% (GC)
| 826-35-7 |
|
4-Ethoxymethylene-2-Phenyl-2-Oxazolin- 5-One, 97%
| 15646-46-5 |
|
Drimarene Red Z 2B, 78% (HPLC)
| 15792-41-3 |
|
Carbol Fuchsin Solution
| 64-17-5 |
|
Fehling Solution, Part A
| 7732-18-5 |
|
Buffer Solution pH 10
| 584-08-7 |
|
Buffer Solution pH 7
| 1310-73-2 |
|
4-Normal-Butoxyphenol, 99%
| 122-94-1 |
|
Buffer Solution pH 10.0 (Color-Coded Blue)
| 584-08-7 |
|
9-Methylanthracene, 99%
| 779-02-2 |
|
Phenoxyacetic acid, 98+%
| 122-59-8 |
|
5-(4-Hydroxyphenyl)-5-(p-tolyl)hydantoin, 99%
| 71766-23-9 |
|
Barium Chloranilate Trihydrate
| 13435-46-6 |
|
N-(Trimethylsilyl)acetamide, 97%
| 13435-12-6 |
|
2,4,6-Trimethoxybenzaldehyde, 98%
| 830-79-5 |
|
(1R,2R,3S,5R)-(-)-2,3-Pinanediol, 98%
| 22422-34-0 |
|
Dimethyl Sulfate
| 77-78-1 |
|
6-Hydroxynicotinic Acid, 99%
| 5006-66-6 |
|
2-Chlorocyclohexanone, 95%, Stabilized with CaCO3/MgO
| 822-87-7 |
|
n-Nonylamine, 98%
| 112-20-9 |
|
Oxamic Acid, Sodium Salt, 98%
| 565-73-1 |
|
Alpha-Terthienyl,99+%
| 1081-34-1 |
|
4-Pyridinecarboxaldehyde, 98%
| 872-85-5 |
|
4-3-(Trifluoromethyl)Phenyl??-4-Piperidino L Hydrochloride, 99% (TLC)
| 1683-49-4 |
|
1,3-Diphenylisobenzofuran, 99+%
| 5471-63-6 |
|
(S)-2-??n'-(N-Benzylprolyl)Amino??Benzo-Phenone, 99.5+%
| 96293-17-3 |
|
Sebaconitrile, 98% (GC)
| 1871-96-1 |
|
Tricyclohexyl Phosphine
| 2622-14-2 |
|
3-Ethoxyacrylonitrile, 98+%, mixture of cis and trans
| 61310-53-0 |
|
2-Chloro-5-(trifluoromethyl)pyridine 98+%
| 52334-81-3 |
|
Diisopropyl fluorophosphate
| 55-91-4 |
|
2,3,6-Trichlorobenzaldehyde,98%
| 4659-47-6 |
|
2-Diethylaminoethyl Chloride Hydrochloride, 99.5%
| 869-24-9 |
|
Tetramethylene glutarimide,99%
| 1075-89-4 |
|
1,4-Diacetoxybenzene, 98%
| 1205-91-0 |
|
2-Chloropyrimidine, 98+%
| 1722-12-9 |
|
5(6)-Carboxyfluorescein, 99% (UV-VIS)
| 72088-94-9 |
|
Silver Cyclohexanebutyrate
| 62638-04-4 |
|
1,2-Benzenedimethanol, 97%
| 612-14-6 |
|
4-Nitrobenzamide, 98%
| 619-80-7 |
|
Potassium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
D(-)-Lyxose, 99+%, Mixture of Anomers
| 1114-34-7 |
|
Neodymium atomic absorption standard solution, 1 mg/ml Nd in 2% HNO3
| 7440-00-8 |
|
1,3-Dihydroxynaphthalene,99+%
| 132-86-5 |
|
|