**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 61310-53-0 |3-Ethoxyacrylonitrile | >98 | 262-706-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Aspiration may lead to pulmonary edema. Vapors may cause dizziness
or suffocation. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Flammable liquid and
vapor. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Fire or excessive heat
may result in violent rupture of the container due to bulk
polymerization.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Use water spray to cool
fire-exposed containers. Water may be ineffective. Use agent most
appropriate to extinguish fire. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Use only with adequate ventilation. Keep away from
heat, sparks and flame. Pure vapor will be uninhibited and may
polymerize in vents or other confined spaces.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Keep containers tightly closed. Some have
recommended storage in an explosion-proof refrigerator.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels. See 29CFR 1910.1045 for regulations applying to
all occupational exposures to acrylonitrile.
Exposure Limits
CAS# 61310-53-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.4 hPa @ 20 deg C
Viscosity: Not available.
Boiling Point: 90-91 deg C @ 10 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: 428 deg C ( 802.40 deg F)
Flash Point: 50 deg C ( 122.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 19 g/l @ 20C
Specific Gravity/Density: .9400 g/cm3
Molecular Formula: C5H7NO
Molecular Weight: 97.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May polymerize.
Conditions to Avoid:
Light, ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, polymerizing
initiators.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 61310-53-0: AT6475000
LD50/LC50:
Not available.
Carcinogenicity:
3-Ethoxyacrylonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 61310-53-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 61310-53-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 61310-53-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 10/16/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Chlorobenzyl Alcohol, 99+%
| 873-63-2 |
|
N-(2-Hydroxyethyl)-1,3-propanediamine, 97+%
| 4461-39-6 |
|
Tetrabutylammonium tetrafluoroborate, 99%
| 429-42-5 |
|
Adamantane, 99+%
| 281-23-2 |
|
3-Carbomethoxy-2-Pyrone, 99% (GC)
| 25991-27-9 |
|
Aflatoxin B2, crystalline
| 7220-81-7 |
|
2,2,6,6-Tetramethyl-4-Piperidone, Monohydrate, 98% (GC)
| 826-35-7 |
|
4-Ethoxymethylene-2-Phenyl-2-Oxazolin- 5-One, 97%
| 15646-46-5 |
|
Drimarene Red Z 2B, 78% (HPLC)
| 15792-41-3 |
|
Carbol Fuchsin Solution
| 64-17-5 |
|
Fehling Solution, Part A
| 7732-18-5 |
|
Buffer Solution pH 10
| 584-08-7 |
|
Buffer Solution pH 7
| 1310-73-2 |
|
4-Normal-Butoxyphenol, 99%
| 122-94-1 |
|
Buffer Solution pH 10.0 (Color-Coded Blue)
| 584-08-7 |
|
9-Methylanthracene, 99%
| 779-02-2 |
|
Phenoxyacetic acid, 98+%
| 122-59-8 |
|
5-(4-Hydroxyphenyl)-5-(p-tolyl)hydantoin, 99%
| 71766-23-9 |
|
Barium Chloranilate Trihydrate
| 13435-46-6 |
|
N-(Trimethylsilyl)acetamide, 97%
| 13435-12-6 |
|
2,4,6-Trimethoxybenzaldehyde, 98%
| 830-79-5 |
|
(1R,2R,3S,5R)-(-)-2,3-Pinanediol, 98%
| 22422-34-0 |
|
Dimethyl Sulfate
| 77-78-1 |
|
6-Hydroxynicotinic Acid, 99%
| 5006-66-6 |
|
2-Chlorocyclohexanone, 95%, Stabilized with CaCO3/MgO
| 822-87-7 |
|
n-Nonylamine, 98%
| 112-20-9 |
|
Oxamic Acid, Sodium Salt, 98%
| 565-73-1 |
|
Alpha-Terthienyl,99+%
| 1081-34-1 |
|
4-Pyridinecarboxaldehyde, 98%
| 872-85-5 |
|
4-3-(Trifluoromethyl)Phenyl??-4-Piperidino L Hydrochloride, 99% (TLC)
| 1683-49-4 |
|
1,3-Diphenylisobenzofuran, 99+%
| 5471-63-6 |
|
(S)-2-??n'-(N-Benzylprolyl)Amino??Benzo-Phenone, 99.5+%
| 96293-17-3 |
|
Sebaconitrile, 98% (GC)
| 1871-96-1 |
|
Tricyclohexyl Phosphine
| 2622-14-2 |
|
3-Ethoxyacrylonitrile, 98+%, mixture of cis and trans
| 61310-53-0 |
|
2-Chloro-5-(trifluoromethyl)pyridine 98+%
| 52334-81-3 |
|
Diisopropyl fluorophosphate
| 55-91-4 |
|
2,3,6-Trichlorobenzaldehyde,98%
| 4659-47-6 |
|
2-Diethylaminoethyl Chloride Hydrochloride, 99.5%
| 869-24-9 |
|
Tetramethylene glutarimide,99%
| 1075-89-4 |
|
1,4-Diacetoxybenzene, 98%
| 1205-91-0 |
|
2-Chloropyrimidine, 98+%
| 1722-12-9 |
|
5(6)-Carboxyfluorescein, 99% (UV-VIS)
| 72088-94-9 |
|
Silver Cyclohexanebutyrate
| 62638-04-4 |
|
1,2-Benzenedimethanol, 97%
| 612-14-6 |
|
4-Nitrobenzamide, 98%
| 619-80-7 |
|
Potassium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
D(-)-Lyxose, 99+%, Mixture of Anomers
| 1114-34-7 |
|
Neodymium atomic absorption standard solution, 1 mg/ml Nd in 2% HNO3
| 7440-00-8 |
|
1,3-Dihydroxynaphthalene,99+%
| 132-86-5 |
|
|