**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 129714-97-2 |3,5-Difluorobenzoyl Chloride | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Lachrymator (substance which
increases the flow of tears).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam. Do NOT get water
inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not get on
skin or in eyes. Do not ingest or inhale. Use with adequate
ventilation. Do not allow contact with water. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Keep from
contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances.
Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 129714-97-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 69 deg C ( 156.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.5031g/cm3
Molecular Formula: C7H3ClF2O
Molecular Weight: 176.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 129714-97-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,5-Difluorobenzoyl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 129714-97-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 129714-97-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 129714-97-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/26/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,3,5-Trichloro-2,4,6-Trifluorobenzene, 98%
| 319-88-0 |
|
Benzenesulfonyl fluoride, 99%
| 368-43-4 |
|
(S)-(+)-2-Phenylglycinol, 98%
| 20989-17-7 |
|
Ethyl Vinyl Sulfone, 98%
| 1889-59-4 |
|
Iodoacetic anhydride
| 54907-61-8 |
|
Ethyl phenyl sulfide, 97%
| 622-38-8 |
|
Indole-3-carboxylic acid, 99%
| 771-50-6 |
|
5-Acetyl-2,4-dimethylthiazole, 96%
| 38205-60-6 |
|
Ethyl Heptanoate, 99%
| 106-30-9 |
|
2-ETHYL-2-HEXENOIC ACID, 95%, PREDOMINANTLY TRANS
| 5309-52-4 |
|
Ethyl Isobutyrate, 99%
| 97-62-1 |
|
Furfuryl methyl sulfide, 97%
| 1438-91-1 |
|
trans-2-Hexenyl acetate, 98%
| 2497-18-9 |
|
2,5-Dimethyl-4-Hydroxy-3(2H)-Furanone, 95%
| 3658-77-3 |
|
Isobutyl Propionate, 98%
| 540-42-1 |
|
8-Mercaptomenthone, Mixture of Isomers, Tech., 80%
| 7732-18-5 |
|
Methyl propyl disulfide, 95%
| 2179-60-4 |
|
3-(Methylthio)-1-hexanol, 97%
| 51755-66-9 |
|
1,8-Octanedithiol, 99%
| 1191-62-4 |
|
Octyl acetate, 99+%
| 112-14-1 |
|
Poly(vinyl Stearate), Average MW ca. 90000 (GPC)
| 9003-95-6 |
|
Poly(2,6-Dimethyl-1,4-Phenylene Oxide)
| 25134-01-4 |
|
Polyacrylonitrile
| 25014-41-9 |
|
Poly(Ethylene Adipate), Average M.W. ca. 10.000 (GPC)
| 24937-78-8 |
|
Poly(methyl acrylate), solution in toluene, average MW ca. 40000
| 108-88-3 |
|
3-Chloropropyl acetate
| 628-09-1 |
|
Poly(Styrene-Co-Butadiene), 5% Styrene
| 9003-55-8 |
|
Poly(Vinyl Cinnamate), Average MW ca. 200000 (GPC)
| 9050-06-0 |
|
Poly(ethyl acrylate), approx. 20% solution in toluene, average M.W.
| 108-88-3 |
|
Poly(4-Methylstyrene), Average MW ca. 70000 (GPC)
| 24936-41-2 |
|
Poly(1-Butene), Isotactic, Average MW ca. 185000 (GPC)
| 9003-28-5 |
|
Polyethylene, Oxidized
| 68441-17-8 |
|
Poly(styrene-acrylonitrile), 25 wt.% acrylonitrile, average MW ca.
| 9003-54-7 |
|
Acenaphthylene, 99+%
| 208-96-8 |
|
Cyclohexyl Methacrylate, 97+%
| 101-43-9 |
|
4-Hydroxybutyl Acrylate, 96%
| 2478-10-6 |
|
Poly(acrylonitrile-co-butadiene-co-styrene)
| 9003-56-9 |
|
6-Methylnicotinic Acid, 99%
| 3222-47-7 |
|
Diphenyl Isophthalate, 99%
| 744-45-6 |
|
Diethyl Fluoromalonate, 97%
| 685-88-1 |
|
Phloretin, 98%
| 60-82-2 |
|
2,2,2-Trifluoroethyl Ether, 99%
| 333-36-8 |
|
Trifluoroacetic Acid Lithium Salt, 95%
| 2923-17-3 |
|
3,5-Bis(trifluoromethyl)benzaldehyde, 97%
| 401-95-6 |
|
3,5-Bis(Trifluoromethyl)Bromobenzene, 99%
| 328-70-1 |
|
3,5-Difluorobenzoic acid, 97%
| 455-40-3 |
|
3,5-Difluorobenzonitrile, 99%
| 64248-63-1 |
|
3,5-Difluorobenzoyl Chloride, 98%
| 129714-97-2 |
|
2,3-Difluorobenzyl Alcohol, 94%
| 75853-18-8 |
|
2,4-Difluorobenzyl alcohol, 99%
| 56456-47-4 |
|
|