**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 333-36-8 |2,2,2,-Trifluoroethyl Ether | 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to eyes, respiratory system and skin.Highly
flammable.The toxicological properties of this material have not been
fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Will be easily ignited by heat, sparks or flame.
Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Avoid contact with skin and eyes. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 333-36-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: ether-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 62 - 63 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 1 deg C ( 33.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4040g/cm3
Molecular Formula: C4H4F6O
Molecular Weight: 182.07
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 333-36-8: KN3675000
LD50/LC50:
Not available.
Carcinogenicity:
2,2,2,-Trifluoroethyl Ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 333-36-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 333-36-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 333-36-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/12/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,3,5-Trichloro-2,4,6-Trifluorobenzene, 98%
| 319-88-0 |
|
Benzenesulfonyl fluoride, 99%
| 368-43-4 |
|
(S)-(+)-2-Phenylglycinol, 98%
| 20989-17-7 |
|
Ethyl Vinyl Sulfone, 98%
| 1889-59-4 |
|
Iodoacetic anhydride
| 54907-61-8 |
|
Ethyl phenyl sulfide, 97%
| 622-38-8 |
|
Indole-3-carboxylic acid, 99%
| 771-50-6 |
|
5-Acetyl-2,4-dimethylthiazole, 96%
| 38205-60-6 |
|
Ethyl Heptanoate, 99%
| 106-30-9 |
|
2-ETHYL-2-HEXENOIC ACID, 95%, PREDOMINANTLY TRANS
| 5309-52-4 |
|
Ethyl Isobutyrate, 99%
| 97-62-1 |
|
Furfuryl methyl sulfide, 97%
| 1438-91-1 |
|
trans-2-Hexenyl acetate, 98%
| 2497-18-9 |
|
2,5-Dimethyl-4-Hydroxy-3(2H)-Furanone, 95%
| 3658-77-3 |
|
Isobutyl Propionate, 98%
| 540-42-1 |
|
8-Mercaptomenthone, Mixture of Isomers, Tech., 80%
| 7732-18-5 |
|
Methyl propyl disulfide, 95%
| 2179-60-4 |
|
3-(Methylthio)-1-hexanol, 97%
| 51755-66-9 |
|
1,8-Octanedithiol, 99%
| 1191-62-4 |
|
Octyl acetate, 99+%
| 112-14-1 |
|
Poly(vinyl Stearate), Average MW ca. 90000 (GPC)
| 9003-95-6 |
|
Poly(2,6-Dimethyl-1,4-Phenylene Oxide)
| 25134-01-4 |
|
Polyacrylonitrile
| 25014-41-9 |
|
Poly(Ethylene Adipate), Average M.W. ca. 10.000 (GPC)
| 24937-78-8 |
|
Poly(methyl acrylate), solution in toluene, average MW ca. 40000
| 108-88-3 |
|
3-Chloropropyl acetate
| 628-09-1 |
|
Poly(Styrene-Co-Butadiene), 5% Styrene
| 9003-55-8 |
|
Poly(Vinyl Cinnamate), Average MW ca. 200000 (GPC)
| 9050-06-0 |
|
Poly(ethyl acrylate), approx. 20% solution in toluene, average M.W.
| 108-88-3 |
|
Poly(4-Methylstyrene), Average MW ca. 70000 (GPC)
| 24936-41-2 |
|
Poly(1-Butene), Isotactic, Average MW ca. 185000 (GPC)
| 9003-28-5 |
|
Polyethylene, Oxidized
| 68441-17-8 |
|
Poly(styrene-acrylonitrile), 25 wt.% acrylonitrile, average MW ca.
| 9003-54-7 |
|
Acenaphthylene, 99+%
| 208-96-8 |
|
Cyclohexyl Methacrylate, 97+%
| 101-43-9 |
|
4-Hydroxybutyl Acrylate, 96%
| 2478-10-6 |
|
Poly(acrylonitrile-co-butadiene-co-styrene)
| 9003-56-9 |
|
6-Methylnicotinic Acid, 99%
| 3222-47-7 |
|
Diphenyl Isophthalate, 99%
| 744-45-6 |
|
Diethyl Fluoromalonate, 97%
| 685-88-1 |
|
Phloretin, 98%
| 60-82-2 |
|
2,2,2-Trifluoroethyl Ether, 99%
| 333-36-8 |
|
Trifluoroacetic Acid Lithium Salt, 95%
| 2923-17-3 |
|
3,5-Bis(trifluoromethyl)benzaldehyde, 97%
| 401-95-6 |
|
3,5-Bis(Trifluoromethyl)Bromobenzene, 99%
| 328-70-1 |
|
3,5-Difluorobenzoic acid, 97%
| 455-40-3 |
|
3,5-Difluorobenzonitrile, 99%
| 64248-63-1 |
|
3,5-Difluorobenzoyl Chloride, 98%
| 129714-97-2 |
|
2,3-Difluorobenzyl Alcohol, 94%
| 75853-18-8 |
|
2,4-Difluorobenzyl alcohol, 99%
| 56456-47-4 |
|
|