**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 130-15-4 |1,4-Naphthoquinone | 97 | 204-977-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye burns. Quinones were
suspected and shown to cause discoloration of the cornea. May cause
visual disturbances.
Skin:
Causes skin irritation. May cause skin burns. Effects may be
delayed. May cause discoloration, erythema (redness), swelling, and
the formation of papules and vesicles (blisters).
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Ingestion may cause the following: a decreased number of erythrocytes
in the blood, decreased hemoglobin levels in the blood and depressed
phagocytic activity of leukocytes.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Prolonged
contact may cause severe eye irritation or burns.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce irritating, corrosive and/or toxic
fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: Odor like that of benzoquinone
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 126 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Sparingly soluble in water
Specific Gravity/Density: 1.422
Molecular Formula: C10H6O2
Molecular Weight: 158.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 130-15-4: QL7175000
LD50/LC50:
CAS# 130-15-4: Oral, rat: LD50 = 190 mg/kg; Oral, rat: LD50 = 190
mg/kg; Skin, rat: LD50 = 202 mg/kg.
Carcinogenicity:
1,4-Naphthoquinone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
USA RQ:CAS# 130-15-4: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 130-15-4: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 130-15-4 is listed on Canada's DSL List.
CAS# 130-15-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 130-15-4: OEL-RUSSIA:STEL 0.1 mg/m3;Skin
US FEDERAL
TSCA
CAS# 130-15-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Phenethyl alcohol, 99+%
| 60-12-8 |
|
1,8-Diaminonaphthalene, 99%
| 479-27-6 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline) 99+%
| 13680-35-8 |
|
Poly(styrene), average m.w. 250.000
| 9003-53-6 |
|
Poly(styrene), ultra high molecular weight
| 9003-53-6 |
|
Heptafluorobutyric Acid, 99%
| 375-22-4 |
|
3-Chloro-1,2-Propanediol, 98%
| 96-24-2 |
|
1,2-Dibromobenzene, 99%
| 583-53-9 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99%
| 115-69-5 |
|
Aflatoxin G2, crystalline
| 7241-98-7 |
|
2-Imidazolidone hemihydrate, 99+%
| 120-93-4 |
|
4-Chloro-1-butanol, 90-95% (GC), balance THF and HCl
| 109-99-9 |
|
Dibromomethane, 99%
| 74-95-3 |
|
N,N,3,5-Tetramethylaniline, 99% (GC)
| 4913-13-7 |
|
7-Bromoheptanonitrile, 98%
| 20965-27-9 |
|
o-Phthaloyl dichloride, remainder mainly phthalic acid, 90%
| 88-95-9 |
|
Vanadium(V) oxide, 99.6+%
| 1314-62-1 |
|
2,6-Bis(Hydroxymethyl)-P-Cresol, 97%
| 91-04-3 |
|
Anthrone, 98%
| 90-44-8 |
|
4-tert-Butyltoluene, p.a.
| 98-51-1 |
|
Methyl 4-Nitrobenzenesulfonate, 99+%
| 6214-20-6 |
|
7-Amino-4-Methylcoumarin, 98%
| 26093-31-2 |
|
Ammonium Sulfamate P.A.
| 7773-06-0 |
|
Trans-Stilbene, 96%
| 103-30-0 |
|
tert-Butyl chloroacetate, 99%
| 107-59-5 |
|
Cinnamoyl chloride 98%, Predominantly Trans
| 102-92-1 |
|
Iodine Monochloride, 98%
| 7790-99-0 |
|
Allyl phenyl ether, 99%
| 1746-13-0 |
|
N,N-Diethylethanolamine
| 100-37-8 |
|
Lithium perchlorate
| 7791-03-9 |
|
(S)-(-)-Amino-2-(1'-methoxy-1'-methylethyl )pyrrolidine
| 118535-61-8 |
|
Dl-2,4-pentanediol, 97%
| 625-69-4 |
|
Sodium hexafluoroantimonate, tech.
| 16925-25-0 |
|
1,3-Diphenylguanidine, 97%
| 102-06-7 |
|
4-Butoxyaniline, 97% (gc)
| 4344-55-2 |
|
L(-)-Epinephrine, 99%
| 51-43-4 |
|
Lithium bis(trimethylsilyl)amide 1M solution in THF/cyclohexane
| 109-99-9 |
|
2-Chloro-5-Nitrobenzaldehyde, 97%
| 6361-21-3 |
|
Tetraethylammonium Perchlorate, 95% (Titr.)
| 2567-83-1 |
|
l-Tartaric acid, disodium salt dihydrate, p.a.
| 6106-24-7 |
|
Digoxin, 95% HPLC (on Dried Substance)
| 20830-75-5 |
|
n-Acetylneuraminic acid, from bovine milk, 98%
| 131-48-6 |
|
1,4-Naphthoquinone, 99% (GC), contains up to 6% moisture
| 130-15-4 |
|
Methyl disulfide, 99%
| 624-92-0 |
|
Dowex 1x8-100 ion-exchange resin
| 12627-85-9 |
|
Dowex 1x8-400 ion-exchange resin
| 12627-85-9 |
|
Ethyl red
| 76058-33-8 |
|
Glycylglycine, 99+%
| 556-50-3 |
|
Lithium aluminum hydride, 95+%
| 16853-85-3 |
|
Cerium(IV) Oxide, 99.999%, - 325 Mesh
| 1306-38-3 |
|
|