**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2567-83-1 |Tetraethylammonium Perchlorate | 95 | 219-904-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36/37/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Contact with
combustible material may cause fire.
Potential Health Effects
Eye:
Causes eye irritation. May cause permanent corneal opacification.
May cause chemical conjunctivitis.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause burns to the gastrointestinal tract. May cause
nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. May cause acute pulmonary edema, asphyxia, chemical
pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. This material is an explosion hazard
when exposed to heat, mechanical shock, or friction. Material is
shock sensitive and potentially explosive. Greatly increases the
burning rate of combustible materials. Containers may explode when
heated.
Extinguishing Media:
Do NOT get water inside containers. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out. For small fires, do NOT use
dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not get water
inside containers. Do not use combustible materials such as paper
towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid contact with clothing and
other combustible materials. Avoid ingestion and inhalation. Avoid
mechanical shock and friction. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2567-83-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: almost white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 344 deg C
Solubility in water: slightly soluble in water.
Specific Gravity/Density: >1.0
Molecular Formula: C8H20ClNO4
Molecular Weight: 229.70
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Substance is shock sensitive and thermally
unstable.
Conditions to Avoid:
Mechanical shock, incompatible materials, ignition sources, dust
generation, excess heat, combustible materials, reducing agents,
temperatures above 250C.
Incompatibilities with Other Materials:
Benzene, acids (mineral, non-oxidizing, e.g. hydrochloric acid,
hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic,
e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic
acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol,
ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral
hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide,
dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl
amine, propylamine, pyridine, triethylamine), azo, diazo, and
hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine),
carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium
cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb,
metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl
formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)),
hydrocarbons (aromatic, e.g. benzene, chrysene, cumene, toluene),
halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl
chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate),
ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other
organic sulfides (e.g. butyl mercaptan, carbon disulfide,
methanethiol), metals (alkali and alkaline, e.g. cesium, potassium,
sodium), metals as powders (e.g. hafnium, raney nickel), metals as
non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium
nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl
cyanide), nitro compounds (organic, e.g. nitrobenzene,
nitroglycerine, picric acid, trinitrotoluene), hydrocarbons
(aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene),
hydrocarbons (aliphatic, saturated, e.g. butane, heptane,
isooctane), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol,
phenol, resorcinol), organophosphates, phosphothioates (e.g.
methylparathion, parathion, phorate, thionazin), su.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, ammonia and
hydrochloric acid fumes.
Hazardous Polymerization: Will occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2567-83-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraethylammonium Perchlorate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID (TETRAETHYLAMMONIUM PERCHLORATE ,D
RY)
Hazard Class: 5.1
UN Number: 1479
Packing Group: I
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: I
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 2567-83-1: No information available.
Canada
CAS# 2567-83-1 is listed on Canada's DSL List.
CAS# 2567-83-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2567-83-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/14/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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