**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7791-03-9 |Lithium perchlorate | >95 | 232-237-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36/37/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Contact with
combustible material may cause fire.Hygroscopic (absorbs moisture
from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion.
Extinguishing Media:
Use flooding quantities of water as spray. May require flooding with
water in order to eliminate hazardous reactions since the materials
generate their own oxygen.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not use combustible materials such as paper towels to clean up
spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep from contact with clothing and
other combustible materials. Avoid breathing dust. Destroy
contaminated leather clothing. Inform laundry personnel of
contaminant's hazards. Do not take working clothes home.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from reducing agents. Avoid
storage on wood floors.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7791-03-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: odorless
pH: 6-7.5 (5% aq soln)
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point: 236 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 400 deg C
Solubility in water: Very soluble in water.
Specific Gravity/Density: 2.43 g/cm3
Molecular Formula: LiClO4
Molecular Weight: 106.39
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, moisture, excess heat, contamination.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, amines, ammonia, finely
powdered metals, sulfur, hydrocarbons, combustible materials.
Hazardous Decomposition Products:
Chlorine, oxygen, chlorine dioxide, which may be spontaneously
explosive, lithium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7791-03-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Lithium perchlorate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing Group: II
IMO
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing Group: II
RID/ADR
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7791-03-9: No information available.
Canada
CAS# 7791-03-9 is listed on Canada's DSL List.
CAS# 7791-03-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7791-03-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/14/1998 Revision #3 Date: 7/01/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Phenethyl alcohol, 99+%
| 60-12-8 |
|
1,8-Diaminonaphthalene, 99%
| 479-27-6 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline) 99+%
| 13680-35-8 |
|
Poly(styrene), average m.w. 250.000
| 9003-53-6 |
|
Poly(styrene), ultra high molecular weight
| 9003-53-6 |
|
Heptafluorobutyric Acid, 99%
| 375-22-4 |
|
3-Chloro-1,2-Propanediol, 98%
| 96-24-2 |
|
1,2-Dibromobenzene, 99%
| 583-53-9 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99%
| 115-69-5 |
|
Aflatoxin G2, crystalline
| 7241-98-7 |
|
2-Imidazolidone hemihydrate, 99+%
| 120-93-4 |
|
4-Chloro-1-butanol, 90-95% (GC), balance THF and HCl
| 109-99-9 |
|
Dibromomethane, 99%
| 74-95-3 |
|
N,N,3,5-Tetramethylaniline, 99% (GC)
| 4913-13-7 |
|
7-Bromoheptanonitrile, 98%
| 20965-27-9 |
|
o-Phthaloyl dichloride, remainder mainly phthalic acid, 90%
| 88-95-9 |
|
Vanadium(V) oxide, 99.6+%
| 1314-62-1 |
|
2,6-Bis(Hydroxymethyl)-P-Cresol, 97%
| 91-04-3 |
|
Anthrone, 98%
| 90-44-8 |
|
4-tert-Butyltoluene, p.a.
| 98-51-1 |
|
Methyl 4-Nitrobenzenesulfonate, 99+%
| 6214-20-6 |
|
7-Amino-4-Methylcoumarin, 98%
| 26093-31-2 |
|
Ammonium Sulfamate P.A.
| 7773-06-0 |
|
Trans-Stilbene, 96%
| 103-30-0 |
|
tert-Butyl chloroacetate, 99%
| 107-59-5 |
|
Cinnamoyl chloride 98%, Predominantly Trans
| 102-92-1 |
|
Iodine Monochloride, 98%
| 7790-99-0 |
|
Allyl phenyl ether, 99%
| 1746-13-0 |
|
N,N-Diethylethanolamine
| 100-37-8 |
|
Lithium perchlorate
| 7791-03-9 |
|
(S)-(-)-Amino-2-(1'-methoxy-1'-methylethyl )pyrrolidine
| 118535-61-8 |
|
Dl-2,4-pentanediol, 97%
| 625-69-4 |
|
Sodium hexafluoroantimonate, tech.
| 16925-25-0 |
|
1,3-Diphenylguanidine, 97%
| 102-06-7 |
|
4-Butoxyaniline, 97% (gc)
| 4344-55-2 |
|
L(-)-Epinephrine, 99%
| 51-43-4 |
|
Lithium bis(trimethylsilyl)amide 1M solution in THF/cyclohexane
| 109-99-9 |
|
2-Chloro-5-Nitrobenzaldehyde, 97%
| 6361-21-3 |
|
Tetraethylammonium Perchlorate, 95% (Titr.)
| 2567-83-1 |
|
l-Tartaric acid, disodium salt dihydrate, p.a.
| 6106-24-7 |
|
Digoxin, 95% HPLC (on Dried Substance)
| 20830-75-5 |
|
n-Acetylneuraminic acid, from bovine milk, 98%
| 131-48-6 |
|
1,4-Naphthoquinone, 99% (GC), contains up to 6% moisture
| 130-15-4 |
|
Methyl disulfide, 99%
| 624-92-0 |
|
Dowex 1x8-100 ion-exchange resin
| 12627-85-9 |
|
Dowex 1x8-400 ion-exchange resin
| 12627-85-9 |
|
Ethyl red
| 76058-33-8 |
|
Glycylglycine, 99+%
| 556-50-3 |
|
Lithium aluminum hydride, 95+%
| 16853-85-3 |
|
Cerium(IV) Oxide, 99.999%, - 325 Mesh
| 1306-38-3 |
|
|