**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 96-24-2 |3-Chloro-1,2-Propanediol | 98 | 202-492-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May be fatal if swallowed. May cause gastrointestinal irritation
with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause liver damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before
reuse. Get medical aid if symptoms occur.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Avoid breathing dust, vapor, mist, or gas.
Keep container tightly closed. Keep away from heat, sparks and flame.
Use only in a chemical fume hood.
Storage:
Do not store in direct sunlight. Keep container closed when not in
use. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 96-24-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to pale yellow
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 0.03 mbar @ 20
Viscosity: 728 mPa 20.00 deg C
Boiling Point: 213 deg C @ 760.00mmHg
Freezing/Melting Point: -40 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.3220g/cm3
Molecular Formula: C3H7ClO2
Molecular Weight: 110.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide,
chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96-24-2: TY4025000
LD50/LC50:
CAS# 96-24-2: Draize test, rabbit, eye: 100 mg Severe; Inhalation,
mouse: LC50 = >90 ppm/4H; Oral, mouse: LD50 = 160 mg/kg; Oral, mouse:
LD50 = 135 mg/kg; Oral, rat: LD50 = 26 mg/kg; Skin, rabbit: LD50 =
800 uL/kg; Skin, rat: LD50 = 1057 mg/kg.
Carcinogenicity:
3-Chloro-1,2-Propanediol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: GLYCEROL alpha-MONOCHLOROHYDRIN
Hazard Class: 6.1
UN Number: 2689
Packing Group: III
IMO
Shipping Name: GLYCEROL alpha-MONOCHLOROHYDRIN
Hazard Class: 6.1
UN Number: 2689
Packing Group: III
RID/ADR
Shipping Name: GLYCEROL alpha-MONOCHLOROHYDRIN
Hazard Class: 6.1
UN Number: 2689
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 96-24-2: 2
Canada
CAS# 96-24-2 is listed on Canada's NDSL List.
CAS# 96-24-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-24-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/09/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Phenethyl alcohol, 99+%
| 60-12-8 |
|
1,8-Diaminonaphthalene, 99%
| 479-27-6 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline) 99+%
| 13680-35-8 |
|
Poly(styrene), average m.w. 250.000
| 9003-53-6 |
|
Poly(styrene), ultra high molecular weight
| 9003-53-6 |
|
Heptafluorobutyric Acid, 99%
| 375-22-4 |
|
3-Chloro-1,2-Propanediol, 98%
| 96-24-2 |
|
1,2-Dibromobenzene, 99%
| 583-53-9 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99%
| 115-69-5 |
|
Aflatoxin G2, crystalline
| 7241-98-7 |
|
2-Imidazolidone hemihydrate, 99+%
| 120-93-4 |
|
4-Chloro-1-butanol, 90-95% (GC), balance THF and HCl
| 109-99-9 |
|
Dibromomethane, 99%
| 74-95-3 |
|
N,N,3,5-Tetramethylaniline, 99% (GC)
| 4913-13-7 |
|
7-Bromoheptanonitrile, 98%
| 20965-27-9 |
|
o-Phthaloyl dichloride, remainder mainly phthalic acid, 90%
| 88-95-9 |
|
Vanadium(V) oxide, 99.6+%
| 1314-62-1 |
|
2,6-Bis(Hydroxymethyl)-P-Cresol, 97%
| 91-04-3 |
|
Anthrone, 98%
| 90-44-8 |
|
4-tert-Butyltoluene, p.a.
| 98-51-1 |
|
Methyl 4-Nitrobenzenesulfonate, 99+%
| 6214-20-6 |
|
7-Amino-4-Methylcoumarin, 98%
| 26093-31-2 |
|
Ammonium Sulfamate P.A.
| 7773-06-0 |
|
Trans-Stilbene, 96%
| 103-30-0 |
|
tert-Butyl chloroacetate, 99%
| 107-59-5 |
|
Cinnamoyl chloride 98%, Predominantly Trans
| 102-92-1 |
|
Iodine Monochloride, 98%
| 7790-99-0 |
|
Allyl phenyl ether, 99%
| 1746-13-0 |
|
N,N-Diethylethanolamine
| 100-37-8 |
|
Lithium perchlorate
| 7791-03-9 |
|
(S)-(-)-Amino-2-(1'-methoxy-1'-methylethyl )pyrrolidine
| 118535-61-8 |
|
Dl-2,4-pentanediol, 97%
| 625-69-4 |
|
Sodium hexafluoroantimonate, tech.
| 16925-25-0 |
|
1,3-Diphenylguanidine, 97%
| 102-06-7 |
|
4-Butoxyaniline, 97% (gc)
| 4344-55-2 |
|
L(-)-Epinephrine, 99%
| 51-43-4 |
|
Lithium bis(trimethylsilyl)amide 1M solution in THF/cyclohexane
| 109-99-9 |
|
2-Chloro-5-Nitrobenzaldehyde, 97%
| 6361-21-3 |
|
Tetraethylammonium Perchlorate, 95% (Titr.)
| 2567-83-1 |
|
l-Tartaric acid, disodium salt dihydrate, p.a.
| 6106-24-7 |
|
Digoxin, 95% HPLC (on Dried Substance)
| 20830-75-5 |
|
n-Acetylneuraminic acid, from bovine milk, 98%
| 131-48-6 |
|
1,4-Naphthoquinone, 99% (GC), contains up to 6% moisture
| 130-15-4 |
|
Methyl disulfide, 99%
| 624-92-0 |
|
Dowex 1x8-100 ion-exchange resin
| 12627-85-9 |
|
Dowex 1x8-400 ion-exchange resin
| 12627-85-9 |
|
Ethyl red
| 76058-33-8 |
|
Glycylglycine, 99+%
| 556-50-3 |
|
Lithium aluminum hydride, 95+%
| 16853-85-3 |
|
Cerium(IV) Oxide, 99.999%, - 325 Mesh
| 1306-38-3 |
|
|