**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1314-98-3 |Zinc sulfide | 99.99 | 215-251-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture
sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Place under an inert atmosphere. Do not get
water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Handle
under an inert atmosphere. Store protected from air. Do not allow
contact with water. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Do not expose to air. Store protected from
moisture. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1314-98-3:
Russia: 5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: very slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 4.100
Molecular Formula: SZn
Molecular Weight: 97.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, exposure to air, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Air, moisture, strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1314-98-3: ZH5400000
LD50/LC50:
CAS# 1314-98-3: Inhalation, rat: LC50 = >5040 mg/m3/4H; Oral, rat:
LD50 = >2 gm/kg; Skin, rat: LD50 = >2 gm/kg.
Carcinogenicity:
Zinc sulfide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1314-98-3: 0
Canada
CAS# 1314-98-3 is listed on Canada's DSL List.
CAS# 1314-98-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-98-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-4'-Methylbenzophenone, 99%
| 36192-63-9 |
|
2-Thiophenecarbonyl chloride, 98%
| 5271-67-0 |
|
Hexanoyl chloride, 97%
| 142-61-0 |
|
N-Benzoyl-L-Tyrosine Ethyl Ester, 99%
| 3483-82-7 |
|
4,5-Dimethyl-2-Oxo-1,3,2-Dioxathiolane
| 4440-90-8 |
|
4-Octylphenyl 2-Chloro-4-(4-Heptylbenzoyl-oxy)Benzoate
| 41161-57-3 |
|
3,5-Dimethylaniline, 98%
| 108-69-0 |
|
Methyl 5-Chloropentanoate, 97%
| 14273-86-0 |
|
2',5'-Dihydroxyacetophenone 97%
| 490-78-8 |
|
n-Ethyl-2,3-xylidine, 99%
| 41115-23-5 |
|
3(and 4)-(Vinylbenzyl)-2-Chloroethyl Sulfone, 99% (Titr.)
| |
|
3-(Trifluoromethyl)phenylacetonitrile, 97+ %
| 2338-76-3 |
|
Methyl (1R,3S)-2,2-Dimethyl-3-(2-Oxopropyl )-Cyclopropaneacetate, 96%
| 54878-01-2 |
|
Methyl Benzenesulfonate, 99% (HPLC)
| 80-18-2 |
|
2-Ethoxybenzyl alcohol, 98%
| 71672-75-8 |
|
Zinc sulfide, 99.99%, < 10 microns
| 1314-98-3 |
|
2,5-Dimethoxybenzaldehyde, 97%
| 93-02-7 |
|
2,4,6-Trichloroaniline, 98.5%
| 634-93-5 |
|
Chrysin
| 480-40-0 |
|
5-Hydroxy-1-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 122431-37-2 |
|
Dicyclohexano-24-Crown-8, 97%
| 17455-23-1 |
|
Neutron activation standard, short irradiation
| |
|
2,6-Di-Tert- Butylphenol (Pract)
| 128-39-2 |
|
5-Bromoisophthalic Acid, 96% (Titr.)
| 7732-18-5 |
|
Palladium Atomic Absorption Standard Solution, 1mg/ml Pd in 10% HCl.
| 7440-05-3 |
|
(Acetic anhydride)-d6, 98.5 atom % D
| 108-24-7 |
|
3,6-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt, Tech.,
| 7153-21-1 |
|
4-Chloro-2-Methylaniline, 99%
| 95-69-2 |
|
o-Tolyl Isothiocyanate, 99%
| 614-69-7 |
|
1-(Dimethylamino)-Pyrrole 99%
| 78307-76-3 |
|
Picrolonic Acid, 93% (Titr.)
| 550-74-3 |
|
2-Chloro-4-Fluorophenol, 97+%
| 1996-41-4 |
|
Bis(2-Ethoxyethyl) Sebacate, 93% (GC)
| 624-10-2 |
|
4-tert-Butylcalix (6) Arene
| 78092-53-2 |
|
2-Iodobenzoic acid, 98%
| 88-67-5 |
|
p-Aminomethylated polystyrene: 1% divinylbenzene copolymer beads
| 0-00-1 |
|
1-(2-Furoyl)piperazine, 98%
| 40172-95-0 |
|
DL-Tropic Acid, 97%
| 529-64-6 |
|
2,3-Dihydroxybenzoic acid, 99%
| 303-38-8 |
|
Methyl alcohol-d, 99.5+ atom % D
| 67-56-1 |
|
Paraffin Liquid, Suitable for Nujol Mull Preparations for IR-Spect.
| 8042-47-5 |
|
N,n'-dicyclohexylurea, 98%
| 2387-23-7 |
|
1,2-Naphthoquinone-4-sulfonic acid potassi um salt, tech., 90%
| 5908-27-0 |
|
1,3-Benzenedimethanol, 98%
| 626-18-6 |
|
3-Hydroxy-4-methyl-2(3H)-thiazolethione, 97%
| 49762-08-5 |
|
(R)-2-Methyl glycidol
| 86884-89-1 |
|
(4S,2RS)-2-Methylthiazolidine-4-carboxylic acid, 97%
| 0-01-1 |
|
8-Anilino-1-naphthalenesulfonic acid ammonium salt, 95% (uv-vis)
| 28836-03-5 |
|
Bismuth Pentafluoride, 99%
| 7787-62-4 |
|
2-Vinylpyridine, 97%, stabilized with 0.1% tert-butylcatechol
| 100-69-6 |
|
|