**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7787-62-4 |Bismuth Pentafluoride | 99 | 232-125-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.Moisture
sensitive.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Ingestion of large amounts of fluoride may cause salivation, nausea,
vomiting, abdominal pain, fever, labored breathing. Inorganic
fluorides can be harmful. Acute exposure to fluorine compounds can
lead to digestive tract burns, and abdominal pain. Exposure to
fluoride compounds can result in systemic toxic effects on the
heart, liver, and kidneys. It may also deplete calcium levels in the
body leading to hypocalcemia and death. Contains fluoride. Fluoride
can reduce calcium levels leading to fatal hypocalcemia.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic exposure to
fluoride compounds may cause systemic toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Do not allow contact with water. Keep from contact
with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7787-62-4:
United Kingdom, WEL - TWA: (listed as fluorides, inorganic): 2.5
mg/m3 TWA (as F)
United Kingdom, WEL - STEL: (listed as fluorides, inorganic): 6.2
mg/m3 STEL (as F)
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under
Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
Belgium - TWA: (listed as fluorides, inorganic): 2.5 mg/m3 VLE (a
France - VME: (listed as fluorides): 2.5 mg/m3 VME (as F)
Germany: (listed as fluorides): 2.5 mg/m3 VME (as F)
Malaysia: (listed as fluorides): 2.5 mg/m3 TWA (as F)
Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F)
Spain: (listed as fluorides, inorganic): 2.5 mg/m3 VLA-ED (except
uranium hexafluoride, as F)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: almost white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density:
Molecular Formula: BiF5
Molecular Weight: 303.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, fluoride fumes, bismuth oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7787-62-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bismuth Pentafluoride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7787-62-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7787-62-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7787-62-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Amino-4'-Methylbenzophenone, 99%
| 36192-63-9 |
|
2-Thiophenecarbonyl chloride, 98%
| 5271-67-0 |
|
Hexanoyl chloride, 97%
| 142-61-0 |
|
N-Benzoyl-L-Tyrosine Ethyl Ester, 99%
| 3483-82-7 |
|
4,5-Dimethyl-2-Oxo-1,3,2-Dioxathiolane
| 4440-90-8 |
|
4-Octylphenyl 2-Chloro-4-(4-Heptylbenzoyl-oxy)Benzoate
| 41161-57-3 |
|
3,5-Dimethylaniline, 98%
| 108-69-0 |
|
Methyl 5-Chloropentanoate, 97%
| 14273-86-0 |
|
2',5'-Dihydroxyacetophenone 97%
| 490-78-8 |
|
n-Ethyl-2,3-xylidine, 99%
| 41115-23-5 |
|
3(and 4)-(Vinylbenzyl)-2-Chloroethyl Sulfone, 99% (Titr.)
| |
|
3-(Trifluoromethyl)phenylacetonitrile, 97+ %
| 2338-76-3 |
|
Methyl (1R,3S)-2,2-Dimethyl-3-(2-Oxopropyl )-Cyclopropaneacetate, 96%
| 54878-01-2 |
|
Methyl Benzenesulfonate, 99% (HPLC)
| 80-18-2 |
|
2-Ethoxybenzyl alcohol, 98%
| 71672-75-8 |
|
Zinc sulfide, 99.99%, < 10 microns
| 1314-98-3 |
|
2,5-Dimethoxybenzaldehyde, 97%
| 93-02-7 |
|
2,4,6-Trichloroaniline, 98.5%
| 634-93-5 |
|
Chrysin
| 480-40-0 |
|
5-Hydroxy-1-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 122431-37-2 |
|
Dicyclohexano-24-Crown-8, 97%
| 17455-23-1 |
|
Neutron activation standard, short irradiation
| |
|
2,6-Di-Tert- Butylphenol (Pract)
| 128-39-2 |
|
5-Bromoisophthalic Acid, 96% (Titr.)
| 7732-18-5 |
|
Palladium Atomic Absorption Standard Solution, 1mg/ml Pd in 10% HCl.
| 7440-05-3 |
|
(Acetic anhydride)-d6, 98.5 atom % D
| 108-24-7 |
|
3,6-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt, Tech.,
| 7153-21-1 |
|
4-Chloro-2-Methylaniline, 99%
| 95-69-2 |
|
o-Tolyl Isothiocyanate, 99%
| 614-69-7 |
|
1-(Dimethylamino)-Pyrrole 99%
| 78307-76-3 |
|
Picrolonic Acid, 93% (Titr.)
| 550-74-3 |
|
2-Chloro-4-Fluorophenol, 97+%
| 1996-41-4 |
|
Bis(2-Ethoxyethyl) Sebacate, 93% (GC)
| 624-10-2 |
|
4-tert-Butylcalix (6) Arene
| 78092-53-2 |
|
2-Iodobenzoic acid, 98%
| 88-67-5 |
|
p-Aminomethylated polystyrene: 1% divinylbenzene copolymer beads
| 0-00-1 |
|
1-(2-Furoyl)piperazine, 98%
| 40172-95-0 |
|
DL-Tropic Acid, 97%
| 529-64-6 |
|
2,3-Dihydroxybenzoic acid, 99%
| 303-38-8 |
|
Methyl alcohol-d, 99.5+ atom % D
| 67-56-1 |
|
Paraffin Liquid, Suitable for Nujol Mull Preparations for IR-Spect.
| 8042-47-5 |
|
N,n'-dicyclohexylurea, 98%
| 2387-23-7 |
|
1,2-Naphthoquinone-4-sulfonic acid potassi um salt, tech., 90%
| 5908-27-0 |
|
1,3-Benzenedimethanol, 98%
| 626-18-6 |
|
3-Hydroxy-4-methyl-2(3H)-thiazolethione, 97%
| 49762-08-5 |
|
(R)-2-Methyl glycidol
| 86884-89-1 |
|
(4S,2RS)-2-Methylthiazolidine-4-carboxylic acid, 97%
| 0-01-1 |
|
8-Anilino-1-naphthalenesulfonic acid ammonium salt, 95% (uv-vis)
| 28836-03-5 |
|
Bismuth Pentafluoride, 99%
| 7787-62-4 |
|
2-Vinylpyridine, 97%, stabilized with 0.1% tert-butylcatechol
| 100-69-6 |
|
|