**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 86884-89-1 |(R)-2-Methyl glycidol | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not allow contact with water. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Deep freeze (below -20C). Storage under a
nitrogen blanket has been recommended. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 86884-89-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 107 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 415 deg C ( 779.00 deg F)
Flash Point: 62 deg C ( 143.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1000g/cm3
Molecular Formula: C4H8O2
Molecular Weight: 88.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, acids, bases, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 86884-89-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(R)-2-Methyl glycidol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28 After contact with skin, wash immediately
with...
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 86884-89-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 86884-89-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 86884-89-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/19/1999 Revision #3 Date: 12/21/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
2-Amino-4'-Methylbenzophenone, 99%
| 36192-63-9 |
2-Thiophenecarbonyl chloride, 98%
| 5271-67-0 |
Hexanoyl chloride, 97%
| 142-61-0 |
N-Benzoyl-L-Tyrosine Ethyl Ester, 99%
| 3483-82-7 |
4,5-Dimethyl-2-Oxo-1,3,2-Dioxathiolane
| 4440-90-8 |
4-Octylphenyl 2-Chloro-4-(4-Heptylbenzoyl-oxy)Benzoate
| 41161-57-3 |
3,5-Dimethylaniline, 98%
| 108-69-0 |
Methyl 5-Chloropentanoate, 97%
| 14273-86-0 |
2',5'-Dihydroxyacetophenone 97%
| 490-78-8 |
n-Ethyl-2,3-xylidine, 99%
| 41115-23-5 |
3(and 4)-(Vinylbenzyl)-2-Chloroethyl Sulfone, 99% (Titr.)
| |
3-(Trifluoromethyl)phenylacetonitrile, 97+ %
| 2338-76-3 |
Methyl (1R,3S)-2,2-Dimethyl-3-(2-Oxopropyl )-Cyclopropaneacetate, 96%
| 54878-01-2 |
Methyl Benzenesulfonate, 99% (HPLC)
| 80-18-2 |
2-Ethoxybenzyl alcohol, 98%
| 71672-75-8 |
Zinc sulfide, 99.99%, < 10 microns
| 1314-98-3 |
2,5-Dimethoxybenzaldehyde, 97%
| 93-02-7 |
2,4,6-Trichloroaniline, 98.5%
| 634-93-5 |
Chrysin
| 480-40-0 |
5-Hydroxy-1-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 122431-37-2 |
Dicyclohexano-24-Crown-8, 97%
| 17455-23-1 |
Neutron activation standard, short irradiation
| |
2,6-Di-Tert- Butylphenol (Pract)
| 128-39-2 |
5-Bromoisophthalic Acid, 96% (Titr.)
| 7732-18-5 |
Palladium Atomic Absorption Standard Solution, 1mg/ml Pd in 10% HCl.
| 7440-05-3 |
(Acetic anhydride)-d6, 98.5 atom % D
| 108-24-7 |
3,6-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt, Tech.,
| 7153-21-1 |
4-Chloro-2-Methylaniline, 99%
| 95-69-2 |
o-Tolyl Isothiocyanate, 99%
| 614-69-7 |
1-(Dimethylamino)-Pyrrole 99%
| 78307-76-3 |
Picrolonic Acid, 93% (Titr.)
| 550-74-3 |
2-Chloro-4-Fluorophenol, 97+%
| 1996-41-4 |
Bis(2-Ethoxyethyl) Sebacate, 93% (GC)
| 624-10-2 |
4-tert-Butylcalix (6) Arene
| 78092-53-2 |
2-Iodobenzoic acid, 98%
| 88-67-5 |
p-Aminomethylated polystyrene: 1% divinylbenzene copolymer beads
| 0-00-1 |
1-(2-Furoyl)piperazine, 98%
| 40172-95-0 |
DL-Tropic Acid, 97%
| 529-64-6 |
2,3-Dihydroxybenzoic acid, 99%
| 303-38-8 |
Methyl alcohol-d, 99.5+ atom % D
| 67-56-1 |
Paraffin Liquid, Suitable for Nujol Mull Preparations for IR-Spect.
| 8042-47-5 |
N,n'-dicyclohexylurea, 98%
| 2387-23-7 |
1,2-Naphthoquinone-4-sulfonic acid potassi um salt, tech., 90%
| 5908-27-0 |
1,3-Benzenedimethanol, 98%
| 626-18-6 |
3-Hydroxy-4-methyl-2(3H)-thiazolethione, 97%
| 49762-08-5 |
(R)-2-Methyl glycidol
| 86884-89-1 |
(4S,2RS)-2-Methylthiazolidine-4-carboxylic acid, 97%
| 0-01-1 |
8-Anilino-1-naphthalenesulfonic acid ammonium salt, 95% (uv-vis)
| 28836-03-5 |
Bismuth Pentafluoride, 99%
| 7787-62-4 |
2-Vinylpyridine, 97%, stabilized with 0.1% tert-butylcatechol
| 100-69-6 |
|
|