**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13360-57-1 |Dimethylsulfamoyl chloride | 99 | 236-412-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 21/22 26 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Very toxic by
inhalation. Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May be harmful if absorbed through the skin. May
cause skin rash (in milder cases), and cold and clammy skin with
cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Do NOT get water inside
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not breathe dust, vapor, mist, or gas. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Do not allow contact with water. Use only
in a chemical fume hood. Discard contaminated shoes. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 13360-57-1:
Germany: 0.1 mg/m3 TWA
Germany: Skin absorber
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 80 deg C @ 16.00 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 94 deg C ( 201.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3370 g/cm3
Molecular Formula: C2H6ClNO2S
Molecular Weight: 143.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13360-57-1: WO7185500
LD50/LC50:
CAS# 13360-57-1: Oral, mouse: LD50 = 900 mg/kg.
Carcinogenicity:
Dimethylsulfamoyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13360-57-1: 3
Canada
CAS# 13360-57-1 is listed on Canada's NDSL List.
CAS# 13360-57-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13360-57-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methacrylonitrile, 99% (stabilized with 50 ppm MEHQ)
| 126-98-7 |
|
Boron Trifluoride Dimethanol Complex (50-52 wt% BF3)
| 67-56-1 |
|
Dimethylsulfamoyl Chloride, 99% (GC)
| 13360-57-1 |
|
2,4-Dichloroanisole, 99+%
| 553-82-2 |
|
2-Fluorobenzaldehyde, 97%
| 446-52-6 |
|
Benzoylacetonitrile
| 614-16-4 |
|
3-Fluorobenzonitrile, 98%
| 403-54-3 |
|
3,3,5-Trimethylcyclohexanone, 97%
| 873-94-9 |
|
cis-4-Decenal, 98%
| 21662-09-9 |
|
Cyclohexyl bromide, 99%
| 108-85-0 |
|
Alpha, Alpha, Alpha,4-Tetrafluoro-O-Toluidine, 99%
| 393-39-5 |
|
4-Methoxy-3-Nitrobenzotrifluoride, 99%
| 394-25-2 |
|
Isatoic Anhydride, 98% (Titr.)
| 118-48-9 |
|
2,4'-Difluorobenzophenone, 98%
| 342-25-6 |
|
5-Chloro-2-(Methylamino)benzophenone, 99%
| 1022-13-5 |
|
Hydroquinone sulfonic acid, potassium salt tech.
| 21799-87-1 |
|
L-Leucyl-L-Alanine, Hydrate
| 7298-84-2 |
|
Trifluoroacetaldehyde ethyl hemiacetal, 90%
| 433-27-2 |
|
4-Sulfonic Calix[4]Arene Hydrate, 95%
| 0-01-1 |
|
(n-Propyl)triphenylphosphonium bromide, 99%
| 15912-75-1 |
|
5-Nitro-2-Furaldehyde Diacetate, 98%
| 92-55-7 |
|
3-Nitro-L-Tyrosine, 99%
| 621-44-3 |
|
2-(3-Methoxyphenyl)Cyclohexanone
| 15547-89-4 |
|
2,2'-Dihydroxy-4,4'-dimethoxybenzophenone, 98%
| 131-54-4 |
|
Hippuric Acid, 98%
| 495-69-2 |
|
Dibutyl oxalate, 99%
| 2050-60-4 |
|
N-(2-Hydroxyethyl)Morpholine, 99%
| 622-40-2 |
|
4-Methoxybenzamide (P-Anisamide), 97%
| 3424-93-9 |
|
Manganese(III) acetate dihydrate, 98%
| 993-02-2 |
|
Hexaketocyclohexane octahydrate, 97%
| 527-31-1 |
|
Prussian blue
| 14038-43-8 |
|
(S)-2-Amino-3-Methoxypropanoic Acid Hydrochloride, 98%
| 0-00-1 |
|
trans-1,2-Dichloroethylene, 99.7%, stabilized with 950 ppm BLO and
| 156-60-5 |
|
5-Bromovaleric acid, 97%
| 2067-33-6 |
|
gamma-Decalactone, 97%
| 706-14-9 |
|
Indophenol blue, 99% (uv-vis)
| 132-31-0 |
|
TETRAACETYLETHYLENEDIAMINE, 99.5+%
| 10543-57-4 |
|
Cis-2-Aminocyclohexanol Hydrochloride, 99+%
| 6936-47-6 |
|
5-Chloro-1-phenyl-1h-tetrazole, 97%
| 14210-25-4 |
|
3-Hydroxy-3-methyl-2-butanone, 92%
| 115-22-0 |
|
Precocene I, 99%
| 17598-02-6 |
|
1,3-Dichloroacetone, 99%
| 534-07-6 |
|
2,3-Pyrazinedicarboxamide, 97%
| 6164-78-9 |
|
4-Bromobenzoic Acid 97%
| 586-76-5 |
|
Molecular Sieves, 3A, 4 to 8 Mesh
| 0-00-1 |
|
M-(p-tert-butylphenoxy)benzaldehyde, 99%
| 69770-23-6 |
|
Lysergol
| 602-85-7 |
|
Poly(Vinyl Methyl Ketone) Average M.W. 500.000
| 25038-87-3 |
|
Adenine Sulfate, Dihydrate, 98% (Titr.)
| 321-30-2 |
|
2-(4-Aminophenyl)ethylamine, 95%
| 13472-00-9 |
|
|