**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 433-27-2 |Trifluoroacetaldehyde ethyl hemiacetal| 90 | 207-087-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Aspiration may lead to pulmonary edema. Vapors may cause dizziness
or suffocation. May cause burning sensation in the chest.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. Use dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation. A vapor suppressing foam may
be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Use only in a
chemical fume hood. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Refrigerator/flammables. Keep containers
tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 433-27-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 104.0 - 105.0 deg C @ 745.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 20 deg C ( 68.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.2410g/cm3
Molecular Formula: C4H7F3O2
Molecular Weight: 144.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Acids, moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 433-27-2: KK9000000
LD50/LC50:
CAS# 433-27-2: Oral, mouse: LD50 = 600 mg/kg.
Carcinogenicity:
Trifluoroacetaldehyde ethyl hemiacetal -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 433-27-2: No information available.
Canada
CAS# 433-27-2 is listed on Canada's NDSL List.
CAS# 433-27-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 433-27-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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2-Fluorobenzaldehyde, 97%
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3,3,5-Trimethylcyclohexanone, 97%
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cis-4-Decenal, 98%
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| 108-85-0 |
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Alpha, Alpha, Alpha,4-Tetrafluoro-O-Toluidine, 99%
| 393-39-5 |
|
4-Methoxy-3-Nitrobenzotrifluoride, 99%
| 394-25-2 |
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|
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| 342-25-6 |
|
5-Chloro-2-(Methylamino)benzophenone, 99%
| 1022-13-5 |
|
Hydroquinone sulfonic acid, potassium salt tech.
| 21799-87-1 |
|
L-Leucyl-L-Alanine, Hydrate
| 7298-84-2 |
|
Trifluoroacetaldehyde ethyl hemiacetal, 90%
| 433-27-2 |
|
4-Sulfonic Calix[4]Arene Hydrate, 95%
| 0-01-1 |
|
(n-Propyl)triphenylphosphonium bromide, 99%
| 15912-75-1 |
|
5-Nitro-2-Furaldehyde Diacetate, 98%
| 92-55-7 |
|
3-Nitro-L-Tyrosine, 99%
| 621-44-3 |
|
2-(3-Methoxyphenyl)Cyclohexanone
| 15547-89-4 |
|
2,2'-Dihydroxy-4,4'-dimethoxybenzophenone, 98%
| 131-54-4 |
|
Hippuric Acid, 98%
| 495-69-2 |
|
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| 2050-60-4 |
|
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| 622-40-2 |
|
4-Methoxybenzamide (P-Anisamide), 97%
| 3424-93-9 |
|
Manganese(III) acetate dihydrate, 98%
| 993-02-2 |
|
Hexaketocyclohexane octahydrate, 97%
| 527-31-1 |
|
Prussian blue
| 14038-43-8 |
|
(S)-2-Amino-3-Methoxypropanoic Acid Hydrochloride, 98%
| 0-00-1 |
|
trans-1,2-Dichloroethylene, 99.7%, stabilized with 950 ppm BLO and
| 156-60-5 |
|
5-Bromovaleric acid, 97%
| 2067-33-6 |
|
gamma-Decalactone, 97%
| 706-14-9 |
|
Indophenol blue, 99% (uv-vis)
| 132-31-0 |
|
TETRAACETYLETHYLENEDIAMINE, 99.5+%
| 10543-57-4 |
|
Cis-2-Aminocyclohexanol Hydrochloride, 99+%
| 6936-47-6 |
|
5-Chloro-1-phenyl-1h-tetrazole, 97%
| 14210-25-4 |
|
3-Hydroxy-3-methyl-2-butanone, 92%
| 115-22-0 |
|
Precocene I, 99%
| 17598-02-6 |
|
1,3-Dichloroacetone, 99%
| 534-07-6 |
|
2,3-Pyrazinedicarboxamide, 97%
| 6164-78-9 |
|
4-Bromobenzoic Acid 97%
| 586-76-5 |
|
Molecular Sieves, 3A, 4 to 8 Mesh
| 0-00-1 |
|
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| 69770-23-6 |
|
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| 602-85-7 |
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| 25038-87-3 |
|
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| 321-30-2 |
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| 13472-00-9 |
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|