**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 873-94-9 |3,3,5-Trimethylcyclohexanone | 97% | 212-855-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Use with adequate
ventilation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 873-94-9:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 8 mbar @ 50 C
Viscosity: 2.54 MPA 20.00 deg
Boiling Point: 188.8 deg C @ 760.00mm Hg
Freezing/Melting Point: - 10.00 - - 0.00 deg
Autoignition Temperature: 430 deg C ( 806.00 deg F)
Flash Point: 64 deg C ( 147.20 deg F)
Explosion Limits, lower: 1.10 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 13 g/l (20 c)
Specific Gravity/Density: .8880g/cm3
Molecular Formula: C9H16O
Molecular Weight: 140.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 873-94-9: GW2185000
LD50/LC50:
CAS# 873-94-9: Inhalation, rat: LC50 = 14200 mg/m3.
Carcinogenicity:
3,3,5-Trimethylcyclohexanone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 873-94-9: 1
Canada
CAS# 873-94-9 is listed on Canada's DSL List.
CAS# 873-94-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 873-94-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methacrylonitrile, 99% (stabilized with 50 ppm MEHQ)
| 126-98-7 |
|
Boron Trifluoride Dimethanol Complex (50-52 wt% BF3)
| 67-56-1 |
|
Dimethylsulfamoyl Chloride, 99% (GC)
| 13360-57-1 |
|
2,4-Dichloroanisole, 99+%
| 553-82-2 |
|
2-Fluorobenzaldehyde, 97%
| 446-52-6 |
|
Benzoylacetonitrile
| 614-16-4 |
|
3-Fluorobenzonitrile, 98%
| 403-54-3 |
|
3,3,5-Trimethylcyclohexanone, 97%
| 873-94-9 |
|
cis-4-Decenal, 98%
| 21662-09-9 |
|
Cyclohexyl bromide, 99%
| 108-85-0 |
|
Alpha, Alpha, Alpha,4-Tetrafluoro-O-Toluidine, 99%
| 393-39-5 |
|
4-Methoxy-3-Nitrobenzotrifluoride, 99%
| 394-25-2 |
|
Isatoic Anhydride, 98% (Titr.)
| 118-48-9 |
|
2,4'-Difluorobenzophenone, 98%
| 342-25-6 |
|
5-Chloro-2-(Methylamino)benzophenone, 99%
| 1022-13-5 |
|
Hydroquinone sulfonic acid, potassium salt tech.
| 21799-87-1 |
|
L-Leucyl-L-Alanine, Hydrate
| 7298-84-2 |
|
Trifluoroacetaldehyde ethyl hemiacetal, 90%
| 433-27-2 |
|
4-Sulfonic Calix[4]Arene Hydrate, 95%
| 0-01-1 |
|
(n-Propyl)triphenylphosphonium bromide, 99%
| 15912-75-1 |
|
5-Nitro-2-Furaldehyde Diacetate, 98%
| 92-55-7 |
|
3-Nitro-L-Tyrosine, 99%
| 621-44-3 |
|
2-(3-Methoxyphenyl)Cyclohexanone
| 15547-89-4 |
|
2,2'-Dihydroxy-4,4'-dimethoxybenzophenone, 98%
| 131-54-4 |
|
Hippuric Acid, 98%
| 495-69-2 |
|
Dibutyl oxalate, 99%
| 2050-60-4 |
|
N-(2-Hydroxyethyl)Morpholine, 99%
| 622-40-2 |
|
4-Methoxybenzamide (P-Anisamide), 97%
| 3424-93-9 |
|
Manganese(III) acetate dihydrate, 98%
| 993-02-2 |
|
Hexaketocyclohexane octahydrate, 97%
| 527-31-1 |
|
Prussian blue
| 14038-43-8 |
|
(S)-2-Amino-3-Methoxypropanoic Acid Hydrochloride, 98%
| 0-00-1 |
|
trans-1,2-Dichloroethylene, 99.7%, stabilized with 950 ppm BLO and
| 156-60-5 |
|
5-Bromovaleric acid, 97%
| 2067-33-6 |
|
gamma-Decalactone, 97%
| 706-14-9 |
|
Indophenol blue, 99% (uv-vis)
| 132-31-0 |
|
TETRAACETYLETHYLENEDIAMINE, 99.5+%
| 10543-57-4 |
|
Cis-2-Aminocyclohexanol Hydrochloride, 99+%
| 6936-47-6 |
|
5-Chloro-1-phenyl-1h-tetrazole, 97%
| 14210-25-4 |
|
3-Hydroxy-3-methyl-2-butanone, 92%
| 115-22-0 |
|
Precocene I, 99%
| 17598-02-6 |
|
1,3-Dichloroacetone, 99%
| 534-07-6 |
|
2,3-Pyrazinedicarboxamide, 97%
| 6164-78-9 |
|
4-Bromobenzoic Acid 97%
| 586-76-5 |
|
Molecular Sieves, 3A, 4 to 8 Mesh
| 0-00-1 |
|
M-(p-tert-butylphenoxy)benzaldehyde, 99%
| 69770-23-6 |
|
Lysergol
| 602-85-7 |
|
Poly(Vinyl Methyl Ketone) Average M.W. 500.000
| 25038-87-3 |
|
Adenine Sulfate, Dihydrate, 98% (Titr.)
| 321-30-2 |
|
2-(4-Aminophenyl)ethylamine, 95%
| 13472-00-9 |
|
|