**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 534-07-6 |1,3-Dichloroacetone | 99 | 208-585-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI T+
Risk Phrases: 24 26/28 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic in contact with skin. Very toxic by inhalation and if
swallowed. Irritating to eyes and skin.Hygroscopic (absorbs moisture
from the air).The toxicological properties of this material have not
been fully investigated.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Causes severe eye irritation. Contact of the eye with the
undiluted compound may result in death.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated.
Inhalation:
May be fatal if inhaled. The toxicological properties of this
substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. SPEEDY ACTION IS CRITICAL! Treat patient as for
inhalation.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Combustible
material; may burn but does not ignite readily.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Sweep
up or absorb material, then place into a suitable clean, dry, closed
container for disposal. Avoid generating dusty conditions. Remove
all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 534-07-6:
Russia: 0.05 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white to pale yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.4 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 172.0 - 173.0 deg C @ 760.00m
Freezing/Melting Point: 45 deg C
Autoignition Temperature: 590 deg C ( 1,094.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.3830g/cm3
Molecular Formula: C3H4Cl2O
Molecular Weight: 126.97
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases - reducing agents - moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 534-07-6: UC1430000
LD50/LC50:
CAS# 534-07-6: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, skin: 500 mg Severe; Inhalation, mouse: LC50 = 27 mg/m3/2H;
Inhalation, mouse: LC50 = 27 mg/m3; Inhalation, rat: LC50 = 29
mg/m3/2H; Inhalation, rat: LC50 = 29 mg/m3; Oral, mouse: LD50 =
18900 ug/kg; Oral, rat: LD50 = 20 mg/kg; Skin, rabbit: LD50 = 53
mg/kg.
Oral, mice: LD50 = 18.9 mg/kg
rabbits: LD50 = 250 mg/kg
six rabbits died within one hour of ocular application of the
undiluted test compound. Carcinogenicity:
1,3-Dichloroacetone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1,3-DICHLOROACETONE
Hazard Class: 6.1
UN Number: 2649
Packing Group: II
IMO
Shipping Name: 1,3-DICHLOROACETONE
Hazard Class: 6.1
UN Number: 2649
Packing Group: II
RID/ADR
Shipping Name: 1,3-DICHLOROACETONE
Hazard Class: 6.1
UN Number: 2649
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI T+
Risk Phrases:
R 24 Toxic in contact with skin.
R 26/28 Very toxic by inhalation and if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 534-07-6: No information available.
Canada
CAS# 534-07-6 is listed on Canada's DSL List.
CAS# 534-07-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 534-07-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/22/1998 Revision #3 Date: 10/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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