**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 147-93-3 |Thiosalicylic Acid | 90 | 205-704-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.Air
sensitive.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Mercaptans may cause nausea and headache.
Exposure to high concentrations of mercaptans can produce
unconsciousness with cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), cold extremities and rapid
pulse.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Exposure to high
concentrations of mercaptans can produce unconsciousness with
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), cold extremities and rapid pulse. Mercaptans may cause
nausea and headache.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Store
protected from light. Handle under an inert atmosphere. Store
protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not expose
to air. Store protected from light. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 147-93-3:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 165.00 - 168.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in alcohol and ether
Specific Gravity/Density:
Molecular Formula: C7H6O2S
Molecular Weight: 154.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, exposure to air, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 147-93-3: DH3325000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Thiosalicylic Acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 147-93-3: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 147-93-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 147-93-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 147-93-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 11/20/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Hydroxy-2-quinoxalinecarboxylic acid
| 1204-75-7 |
|
(-)-Chloromethyl menthyl ether, 95% (GC), 97+% e.e.
| 26127-08-2 |
|
Ethyl L-Lactate (Pract), 90% (GC)
| 687-47-8 |
|
1,2,3,4-Tetrahydronaphthalene
| 119-64-2 |
|
Methyl sulfide, 99+%
| 75-18-3 |
|
Tetramethylammonium chloride, 98+%
| 75-57-0 |
|
2-Thiophene acetyl chloride, 99%
| 39098-97-0 |
|
Silver Perchlorate Hydrate, 99%
| 14242-05-8 |
|
Triphenyl phosphate, 99+%
| 115-86-6 |
|
4-Aminophthalonitrile
| 56765-79-8 |
|
Nickel Phthalocyanine, 95% (Titr.)
| 14055-02-8 |
|
Methyl P-Toluate
| 99-75-2 |
|
(+)-P-Menth-1-En-9-Ol, 97%
| 13835-75-1 |
|
Tetrapropylammonium hydroxide (25% in water)
| 4499-86-9 |
|
2,4-Dibromoaniline, 98%
| 615-57-6 |
|
Tert.-Butylbenzene, 99%
| 98-06-6 |
|
1,3-Dichloro-2-fluorobenzene, 98+%
| 2268-05-5 |
|
Benzamide (pract)
| 55-21-0 |
|
N-n-Butyldiethanolamine, 98%
| 102-79-4 |
|
Thiosalicylic Acid (Pract), 90% (Titr.)
| 147-93-3 |
|
3-Hydroxypicolinamide, 98+%
| 933-90-4 |
|
Dodecyltrimethylammonium chloride, 98%
| 112-00-5 |
|
Cyclohexene Sulfide, tech., ca.85%
| 286-28-2 |
|
1-(3,4-Dichlorophenyl)-1-Propanone, 99%
| 6582-42-9 |
|
4-Pentylphenol, 99% (GC)
| 14938-35-3 |
|
4-Iodobenzoic acid, 93% (titr.)
| 619-58-9 |
|
Methyl-Beta-D-Glucopyranoside Hemihydrate ,99%
| 709-50-2 |
|
N-Phenylglycine Ethyl Ester, 99% (Titr.)
| 2216-92-4 |
|
1-Phenylpyrazole, 99% (gc)
| 1126-00-7 |
|
2-Amino-3-Nitropyridine, 99%
| 4214-75-9 |
|
Thioacetamide, reagent ACS, 99+%
| 62-55-5 |
|
1-Dimethylamino-2-propanol, 99%
| 108-16-7 |
|
2,5-Dichloro-p-benzoquinone
| 615-93-0 |
|
2,3-Dimethyl-2-Butanol, 98%
| 594-60-5 |
|
Methylmalonic Acid, 96%
| 516-05-2 |
|
5-Aminovaleric Acid, 97%
| 660-88-8 |
|
Palladium on Barium Sulfate (5% Pd)
| 7440-05-3 |
|
Thioglycolic acid
| 68-11-1 |
|
1,3,5-Trimethoxybenzene, 99%
| 621-23-8 |
|
5-Methyl-2-hexanone 99%
| 110-12-3 |
|
Puromycin dihydrochloride hydrate
| 58-58-2 |
|
tert-Butyl ethyl ether, 97%
| 637-92-3 |
|
p-Anisidine
| 90-04-0 |
|
Harmine Hydrochloride Hydrate
| 343-27-1 |
|
3-Nonanone, 98%
| 925-78-0 |
|
N-Ethylcarbazole, 98.5%
| 86-28-2 |
|
(s,s)-jacobsen catalyst, 98%
| 135620-04-1 |
|
Thiourea
| 62-56-6 |
|
2-Chloro-5-Fluoronitrobenzene, 99+%
| 345-17-5 |
|
2,4-Dimethylanisole, 99%
| 6738-23-4 |
|
|