**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-18-3 |Methyl sulfide | >99 | 200-846-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Extremely flammable
liquid and vapor. Vapor may cause flash fire. Vapors are heavier than
air and may travel to a source of ignition and flash back. Vapors can
spread along the ground and collect in low or confined areas. This
liquid floats on water and may travel to a source of ignition and
spread fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
away from heat, sparks and flame. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Use only with adequate ventilation. Avoid
breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Flammables-area. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 75-18-3:
Russia: 50 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless
Odor: stench
pH: Not available.
Vapor Pressure: 502 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 38 deg C @ 760 mm Hg
Freezing/Melting Point: -98 deg C
Autoignition Temperature: 205 deg C ( 401.00 deg F)
Flash Point: -48 deg C ( -54.40 deg F)
Explosion Limits, lower: 2.20 vol %
Explosion Limits, upper: 19.70 vol %
Decomposition Temperature: 450 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: .840 g/ml
Molecular Formula: (CH3)2S
Molecular Weight: 62.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-18-3: PV5075000
LD50/LC50:
CAS# 75-18-3: Draize test, rabbit, eye: 250 ug/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 31620
ug/m3; Inhalation, rat: LC50 = 40250 ppm; Oral, mouse: LD50 = 3700
mg/kg; Oral, rat: LD50 = 3300 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Methyl sulfide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIMETHYL SULPHIDE
Hazard Class: 3
UN Number: 1164
Packing Group: II
IMO
Shipping Name: DIMETHYL SULPHIDE
Hazard Class: 3.1
UN Number: 1164
Packing Group: II
RID/ADR
Shipping Name: DIMETHYL SULPHIDE
Hazard Class: 3
UN Number: 1164
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 75-18-3: 2
Canada
CAS# 75-18-3 is listed on Canada's DSL List.
CAS# 75-18-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-18-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 1/24/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Hydroxy-2-quinoxalinecarboxylic acid
| 1204-75-7 |
|
(-)-Chloromethyl menthyl ether, 95% (GC), 97+% e.e.
| 26127-08-2 |
|
Ethyl L-Lactate (Pract), 90% (GC)
| 687-47-8 |
|
1,2,3,4-Tetrahydronaphthalene
| 119-64-2 |
|
Methyl sulfide, 99+%
| 75-18-3 |
|
Tetramethylammonium chloride, 98+%
| 75-57-0 |
|
2-Thiophene acetyl chloride, 99%
| 39098-97-0 |
|
Silver Perchlorate Hydrate, 99%
| 14242-05-8 |
|
Triphenyl phosphate, 99+%
| 115-86-6 |
|
4-Aminophthalonitrile
| 56765-79-8 |
|
Nickel Phthalocyanine, 95% (Titr.)
| 14055-02-8 |
|
Methyl P-Toluate
| 99-75-2 |
|
(+)-P-Menth-1-En-9-Ol, 97%
| 13835-75-1 |
|
Tetrapropylammonium hydroxide (25% in water)
| 4499-86-9 |
|
2,4-Dibromoaniline, 98%
| 615-57-6 |
|
Tert.-Butylbenzene, 99%
| 98-06-6 |
|
1,3-Dichloro-2-fluorobenzene, 98+%
| 2268-05-5 |
|
Benzamide (pract)
| 55-21-0 |
|
N-n-Butyldiethanolamine, 98%
| 102-79-4 |
|
Thiosalicylic Acid (Pract), 90% (Titr.)
| 147-93-3 |
|
3-Hydroxypicolinamide, 98+%
| 933-90-4 |
|
Dodecyltrimethylammonium chloride, 98%
| 112-00-5 |
|
Cyclohexene Sulfide, tech., ca.85%
| 286-28-2 |
|
1-(3,4-Dichlorophenyl)-1-Propanone, 99%
| 6582-42-9 |
|
4-Pentylphenol, 99% (GC)
| 14938-35-3 |
|
4-Iodobenzoic acid, 93% (titr.)
| 619-58-9 |
|
Methyl-Beta-D-Glucopyranoside Hemihydrate ,99%
| 709-50-2 |
|
N-Phenylglycine Ethyl Ester, 99% (Titr.)
| 2216-92-4 |
|
1-Phenylpyrazole, 99% (gc)
| 1126-00-7 |
|
2-Amino-3-Nitropyridine, 99%
| 4214-75-9 |
|
Thioacetamide, reagent ACS, 99+%
| 62-55-5 |
|
1-Dimethylamino-2-propanol, 99%
| 108-16-7 |
|
2,5-Dichloro-p-benzoquinone
| 615-93-0 |
|
2,3-Dimethyl-2-Butanol, 98%
| 594-60-5 |
|
Methylmalonic Acid, 96%
| 516-05-2 |
|
5-Aminovaleric Acid, 97%
| 660-88-8 |
|
Palladium on Barium Sulfate (5% Pd)
| 7440-05-3 |
|
Thioglycolic acid
| 68-11-1 |
|
1,3,5-Trimethoxybenzene, 99%
| 621-23-8 |
|
5-Methyl-2-hexanone 99%
| 110-12-3 |
|
Puromycin dihydrochloride hydrate
| 58-58-2 |
|
tert-Butyl ethyl ether, 97%
| 637-92-3 |
|
p-Anisidine
| 90-04-0 |
|
Harmine Hydrochloride Hydrate
| 343-27-1 |
|
3-Nonanone, 98%
| 925-78-0 |
|
N-Ethylcarbazole, 98.5%
| 86-28-2 |
|
(s,s)-jacobsen catalyst, 98%
| 135620-04-1 |
|
Thiourea
| 62-56-6 |
|
2-Chloro-5-Fluoronitrobenzene, 99+%
| 345-17-5 |
|
2,4-Dimethylanisole, 99%
| 6738-23-4 |
|
|