**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-57-0 |Tetramethylammonium chloride | >98 | 200-880-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 21 25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. Irritating to
eyes, respiratory system and skin.Hygroscopic (absorbs moisture from
the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-57-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: characteristic odor
pH: 6-8 (100g/l water)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 300 deg C (decomposes)
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >300 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.17
Molecular Formula: C4H12ClN
Molecular Weight: 109.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, nitrogen oxides
(NOx) and ammonia (NH3).
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-57-0: BS7700000
LD50/LC50:
CAS# 75-57-0: Oral, rat: LD50 = 50 mg/kg.
Dermal, rat: LD50 = 537 mg/kg (Merck)
mg/kg.
LDLo = 6 mg/kg.
Carcinogenicity:
Tetramethylammonium chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-57-0: 2
Canada
CAS# 75-57-0 is listed on Canada's DSL List.
CAS# 75-57-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-57-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/08/1998 Revision #3 Date: 2/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Hydroxy-2-quinoxalinecarboxylic acid
| 1204-75-7 |
|
(-)-Chloromethyl menthyl ether, 95% (GC), 97+% e.e.
| 26127-08-2 |
|
Ethyl L-Lactate (Pract), 90% (GC)
| 687-47-8 |
|
1,2,3,4-Tetrahydronaphthalene
| 119-64-2 |
|
Methyl sulfide, 99+%
| 75-18-3 |
|
Tetramethylammonium chloride, 98+%
| 75-57-0 |
|
2-Thiophene acetyl chloride, 99%
| 39098-97-0 |
|
Silver Perchlorate Hydrate, 99%
| 14242-05-8 |
|
Triphenyl phosphate, 99+%
| 115-86-6 |
|
4-Aminophthalonitrile
| 56765-79-8 |
|
Nickel Phthalocyanine, 95% (Titr.)
| 14055-02-8 |
|
Methyl P-Toluate
| 99-75-2 |
|
(+)-P-Menth-1-En-9-Ol, 97%
| 13835-75-1 |
|
Tetrapropylammonium hydroxide (25% in water)
| 4499-86-9 |
|
2,4-Dibromoaniline, 98%
| 615-57-6 |
|
Tert.-Butylbenzene, 99%
| 98-06-6 |
|
1,3-Dichloro-2-fluorobenzene, 98+%
| 2268-05-5 |
|
Benzamide (pract)
| 55-21-0 |
|
N-n-Butyldiethanolamine, 98%
| 102-79-4 |
|
Thiosalicylic Acid (Pract), 90% (Titr.)
| 147-93-3 |
|
3-Hydroxypicolinamide, 98+%
| 933-90-4 |
|
Dodecyltrimethylammonium chloride, 98%
| 112-00-5 |
|
Cyclohexene Sulfide, tech., ca.85%
| 286-28-2 |
|
1-(3,4-Dichlorophenyl)-1-Propanone, 99%
| 6582-42-9 |
|
4-Pentylphenol, 99% (GC)
| 14938-35-3 |
|
4-Iodobenzoic acid, 93% (titr.)
| 619-58-9 |
|
Methyl-Beta-D-Glucopyranoside Hemihydrate ,99%
| 709-50-2 |
|
N-Phenylglycine Ethyl Ester, 99% (Titr.)
| 2216-92-4 |
|
1-Phenylpyrazole, 99% (gc)
| 1126-00-7 |
|
2-Amino-3-Nitropyridine, 99%
| 4214-75-9 |
|
Thioacetamide, reagent ACS, 99+%
| 62-55-5 |
|
1-Dimethylamino-2-propanol, 99%
| 108-16-7 |
|
2,5-Dichloro-p-benzoquinone
| 615-93-0 |
|
2,3-Dimethyl-2-Butanol, 98%
| 594-60-5 |
|
Methylmalonic Acid, 96%
| 516-05-2 |
|
5-Aminovaleric Acid, 97%
| 660-88-8 |
|
Palladium on Barium Sulfate (5% Pd)
| 7440-05-3 |
|
Thioglycolic acid
| 68-11-1 |
|
1,3,5-Trimethoxybenzene, 99%
| 621-23-8 |
|
5-Methyl-2-hexanone 99%
| 110-12-3 |
|
Puromycin dihydrochloride hydrate
| 58-58-2 |
|
tert-Butyl ethyl ether, 97%
| 637-92-3 |
|
p-Anisidine
| 90-04-0 |
|
Harmine Hydrochloride Hydrate
| 343-27-1 |
|
3-Nonanone, 98%
| 925-78-0 |
|
N-Ethylcarbazole, 98.5%
| 86-28-2 |
|
(s,s)-jacobsen catalyst, 98%
| 135620-04-1 |
|
Thiourea
| 62-56-6 |
|
2-Chloro-5-Fluoronitrobenzene, 99+%
| 345-17-5 |
|
2,4-Dimethylanisole, 99%
| 6738-23-4 |
|
|