**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 637-92-3 |tert-Butyl ethyl ether | 97 | 211-309-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Contact may cause transient eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Extremely flammable liquid and vapor. Vapor
may cause flash fire. Water may be ineffective. Material is lighter
than water and a fire may be spread by the use of water.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep away from heat, sparks and flame. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Use only with adequate ventilation. Avoid
breathing vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 637-92-3:
Spain: 5 ppm VLA-ED; 21 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 130 mm Hg @ 25 deg
Viscosity: Not available.
Boiling Point: 71 deg C @ 760 mm Hg
Freezing/Melting Point: -94 deg C
Autoignition Temperature: Not available.
Flash Point: -19 deg C ( -2.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 1.2 G/100ML (20C)
Specific Gravity/Density: .7500g/cm3
Molecular Formula: C6H14O
Molecular Weight: 102.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Prolonged exposure
to air and sunlight may form unstable peroxides.
Conditions to Avoid:
Ignition sources, excess heat, electrical sparks, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 637-92-3: KN4730200
LD50/LC50:
CAS# 637-92-3: Draize test, rabbit, eye: 100 uL/24H Moderate; Draize
test, rabbit, skin: 500 uL/4H Moderate; Inhalation, mouse: LC50 = 123
gm/m3/15M; Inhalation, rat: LC50 = >5880 mg/m3/4H; Skin, rabbit: LD50
= >2 gm/kg.
Carcinogenicity:
tert-Butyl ethyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ETHYL BUTYL ETHER
Hazard Class: 3
UN Number: 1179
Packing Group: II
IMO
Shipping Name: ETHYL BUTYL ETHER
Hazard Class: 3.2
UN Number: 1179
Packing Group: II
RID/ADR
Shipping Name: ETHYL BUTYL ETHER
Hazard Class: 3
UN Number: 1179
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 637-92-3: No information available.
Canada
CAS# 637-92-3 is listed on Canada's NDSL List.
CAS# 637-92-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 637-92-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/22/1998 Revision #3 Date: 7/07/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Hydroxy-2-quinoxalinecarboxylic acid
| 1204-75-7 |
|
(-)-Chloromethyl menthyl ether, 95% (GC), 97+% e.e.
| 26127-08-2 |
|
Ethyl L-Lactate (Pract), 90% (GC)
| 687-47-8 |
|
1,2,3,4-Tetrahydronaphthalene
| 119-64-2 |
|
Methyl sulfide, 99+%
| 75-18-3 |
|
Tetramethylammonium chloride, 98+%
| 75-57-0 |
|
2-Thiophene acetyl chloride, 99%
| 39098-97-0 |
|
Silver Perchlorate Hydrate, 99%
| 14242-05-8 |
|
Triphenyl phosphate, 99+%
| 115-86-6 |
|
4-Aminophthalonitrile
| 56765-79-8 |
|
Nickel Phthalocyanine, 95% (Titr.)
| 14055-02-8 |
|
Methyl P-Toluate
| 99-75-2 |
|
(+)-P-Menth-1-En-9-Ol, 97%
| 13835-75-1 |
|
Tetrapropylammonium hydroxide (25% in water)
| 4499-86-9 |
|
2,4-Dibromoaniline, 98%
| 615-57-6 |
|
Tert.-Butylbenzene, 99%
| 98-06-6 |
|
1,3-Dichloro-2-fluorobenzene, 98+%
| 2268-05-5 |
|
Benzamide (pract)
| 55-21-0 |
|
N-n-Butyldiethanolamine, 98%
| 102-79-4 |
|
Thiosalicylic Acid (Pract), 90% (Titr.)
| 147-93-3 |
|
3-Hydroxypicolinamide, 98+%
| 933-90-4 |
|
Dodecyltrimethylammonium chloride, 98%
| 112-00-5 |
|
Cyclohexene Sulfide, tech., ca.85%
| 286-28-2 |
|
1-(3,4-Dichlorophenyl)-1-Propanone, 99%
| 6582-42-9 |
|
4-Pentylphenol, 99% (GC)
| 14938-35-3 |
|
4-Iodobenzoic acid, 93% (titr.)
| 619-58-9 |
|
Methyl-Beta-D-Glucopyranoside Hemihydrate ,99%
| 709-50-2 |
|
N-Phenylglycine Ethyl Ester, 99% (Titr.)
| 2216-92-4 |
|
1-Phenylpyrazole, 99% (gc)
| 1126-00-7 |
|
2-Amino-3-Nitropyridine, 99%
| 4214-75-9 |
|
Thioacetamide, reagent ACS, 99+%
| 62-55-5 |
|
1-Dimethylamino-2-propanol, 99%
| 108-16-7 |
|
2,5-Dichloro-p-benzoquinone
| 615-93-0 |
|
2,3-Dimethyl-2-Butanol, 98%
| 594-60-5 |
|
Methylmalonic Acid, 96%
| 516-05-2 |
|
5-Aminovaleric Acid, 97%
| 660-88-8 |
|
Palladium on Barium Sulfate (5% Pd)
| 7440-05-3 |
|
Thioglycolic acid
| 68-11-1 |
|
1,3,5-Trimethoxybenzene, 99%
| 621-23-8 |
|
5-Methyl-2-hexanone 99%
| 110-12-3 |
|
Puromycin dihydrochloride hydrate
| 58-58-2 |
|
tert-Butyl ethyl ether, 97%
| 637-92-3 |
|
p-Anisidine
| 90-04-0 |
|
Harmine Hydrochloride Hydrate
| 343-27-1 |
|
3-Nonanone, 98%
| 925-78-0 |
|
N-Ethylcarbazole, 98.5%
| 86-28-2 |
|
(s,s)-jacobsen catalyst, 98%
| 135620-04-1 |
|
Thiourea
| 62-56-6 |
|
2-Chloro-5-Fluoronitrobenzene, 99+%
| 345-17-5 |
|
2,4-Dimethylanisole, 99%
| 6738-23-4 |
|
|