**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 22734-04-9 |1-Cyclopenteneacetonitrile | 95 | 245-182-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. May cause
irritation and dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Metabolism may release cyanide, which may
result in headache, dizziness, weakness, collapse, unconsciousness
and possible death.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Aspiration may
lead to pulmonary edema. May be metabolized to cyanide which in
turns act by inhibiting cytochrome oxidase impairing cellular
respiration. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Antidote:
Always have a cyanide antidote kit on hand when working with cyanide
compounds. Get medical advice to use.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 22734-04-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear light yellow
Odor: acetic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 124 - 124 deg C @ 100.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 69 deg C ( 156.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9510g/cm3
Molecular Formula: C7H9N
Molecular Weight: 107.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 22734-04-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Cyclopenteneacetonitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 22734-04-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22734-04-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22734-04-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Formaldehyde sodium bisulfite addition compound, 95%
| 870-72-4 |
|
1-(1'-Methylethyl)-4-piperidone, 99%
| 5355-68-0 |
|
1,4-Diaminobutane Dihydrochloride, 99+%
| 333-93-7 |
|
(+)-Diisopropyl l-tartrate, 99%
| 2217-15-4 |
|
Europium atomic absorption standard solution, 1 mg/ml Eu in 2% HNO3
| 7440-53-1 |
|
Silver (I) sulfide, 99.9%
| 21548-73-2 |
|
1-Benzyl-3-Methyl-4-Piperidone, 99%
| 34737-89-8 |
|
4-Nitrobenzyl chloride, 98% (hplc)
| 100-14-1 |
|
2,6-Dichlorotoluene, 99+%
| 118-69-4 |
|
N,N-Dimethylallylamine, 98% (GC)
| 2155-94-4 |
|
2-(2-Aminoethylamino)-5-Nitropyridine, 98%
| 29602-39-9 |
|
alpha,alpha'-Dichloro-p-xylene, 98%
| 623-25-6 |
|
3-Nitrobenzenesulfonic acid monohydrate, 95% (titr.)
| 5337-19-9 |
|
2-(Chloromethyl)-quinoline hydrochloride 97%
| 3747-74-8 |
|
4-Chloro-2-Fluorobenzylamine Hydrochloride 94% (Titr.)
| 0-00-1 |
|
3-Chlorobenzylbromide, 98+%
| 766-80-3 |
|
alpha-(Chloromethyl)-2,4-dichlorobenzyl alcohol, 98%
| 13692-14-3 |
|
4,4'-Bis(dimethylamino)benzil
| 17078-27-2 |
|
(S)-(+)-2-Aminobutane, 98%
| 513-49-5 |
|
Trioctanoin, 98% (gc)
| 538-23-8 |
|
(2R,3R)-1,4-Di-O-Tosyl-2,3-O-Isopropylidene-D-Threitol, 99+%
| 51064-65-4 |
|
Ethyl 2-Hydroxyisobutyrate, 99%
| 80-55-7 |
|
D-(-)-Leucinol, 97% (97+% e.e.)
| 53448-09-2 |
|
gamma-(4-Fluorophenyl)-gamma-butyrolactone 98%
| 51787-96-3 |
|
4-Aminobenzotrifluoride, 99%
| 455-14-1 |
|
2-Iodoanisole, 97%
| 529-28-2 |
|
3,5-Dibromosalicylaldehyde, 98%
| 90-59-5 |
|
Hydrocinnamonitrile, 99+%
| 645-59-0 |
|
Crotonylchloride, Tech., 90%
| 7732-18-5 |
|
N,n'-diphenyl-p-phenylenediamine (pract), 97% (titr.)
| 74-31-7 |
|
Methyl (z)-2-benzoylamino-3-dimethylaminopropenoate, 98%
| 56952-04-6 |
|
1,2-Phenylenediacetic acid, 99%
| 7500-53-0 |
|
6-Fluoro-1,2,3,4-Tetrahydro-2-Methyl-Quinoline, 98%
| 42835-89-2 |
|
4-Ethoxycarbonyloxy-3,5-dimethoxybenzoic acid, 96%
| 18780-67-1 |
|
Palmitic Acid
| 57-10-3 |
|
2-Methylbenzselenazole, 99%
| 2818-88-4 |
|
Octanophenone, 99+%
| 1674-37-9 |
|
Samarium(iii) oxide, 99.9%
| 12060-58-1 |
|
Cholesteryl benzoate, 98%
| 604-32-0 |
|
5-Thio-d-glucose, predominantly alpha-anomer
| 20408-97-3 |
|
Trichloromethanesulfonyl Chloride (Pract)
| 2547-61-7 |
|
4,4'-Bis(Heptyloxy)Azoxybenzene
| 2635-26-9 |
|
2-(P-Tolyl)Pyridine, 94% (GC)
| 4467-06-5 |
|
3,3'-Dithiodipropionic Acid, 99%
| 1119-62-6 |
|
n-Butyllithium, 2.5M solution in hexanes
| 109-72-8 |
|
2-Hydroxy-9-fluorenone, 97%
| 6949-73-1 |
|
(S)-Ethyl 2-Pyrrolidone-5-Carboxylate, 99%
| 7149-65-7 |
|
Copper chromite, catalyst
| 12018-10-9 |
|
1-Cyclopenteneacetonitrile, 95%
| 22734-04-9 |
|
Triisopropanolamine,98%
| 122-20-3 |
|
|