**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 645-59-0 |Hydrocinnamonitrile, 99+% | 99+% | 211-447-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May cause cardiac disturbances. The
toxicological properties of this substance have not been fully
investigated. May cause tissue anoxia, characterized by weakness,
headache, dizziness, confusion, cyanosis (bluish skin due to
deficient oxygenation of the blood), weak and irregular heart beat,
collapse, unconsciousness, convulsions, coma and death. May cause
central nervous system effects.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. The toxicological properties of this
substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with skin and eyes. Do not ingest or
inhale. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 645-59-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 261 deg C @ 760.00mm Hg
Freezing/Melting Point: -2 - -1 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0010g/cm3
Molecular Formula: C9H9N
Molecular Weight: 131.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 645-59-0: MW5604750
LD50/LC50:
CAS# 645-59-0: Oral, mouse: LD50 = 116 mg/kg.
Carcinogenicity:
Hydrocinnamonitrile, 99+% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 645-59-0: No information available.
Canada
CAS# 645-59-0 is listed on Canada's NDSL List.
CAS# 645-59-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 645-59-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Formaldehyde sodium bisulfite addition compound, 95%
| 870-72-4 |
|
1-(1'-Methylethyl)-4-piperidone, 99%
| 5355-68-0 |
|
1,4-Diaminobutane Dihydrochloride, 99+%
| 333-93-7 |
|
(+)-Diisopropyl l-tartrate, 99%
| 2217-15-4 |
|
Europium atomic absorption standard solution, 1 mg/ml Eu in 2% HNO3
| 7440-53-1 |
|
Silver (I) sulfide, 99.9%
| 21548-73-2 |
|
1-Benzyl-3-Methyl-4-Piperidone, 99%
| 34737-89-8 |
|
4-Nitrobenzyl chloride, 98% (hplc)
| 100-14-1 |
|
2,6-Dichlorotoluene, 99+%
| 118-69-4 |
|
N,N-Dimethylallylamine, 98% (GC)
| 2155-94-4 |
|
2-(2-Aminoethylamino)-5-Nitropyridine, 98%
| 29602-39-9 |
|
alpha,alpha'-Dichloro-p-xylene, 98%
| 623-25-6 |
|
3-Nitrobenzenesulfonic acid monohydrate, 95% (titr.)
| 5337-19-9 |
|
2-(Chloromethyl)-quinoline hydrochloride 97%
| 3747-74-8 |
|
4-Chloro-2-Fluorobenzylamine Hydrochloride 94% (Titr.)
| 0-00-1 |
|
3-Chlorobenzylbromide, 98+%
| 766-80-3 |
|
alpha-(Chloromethyl)-2,4-dichlorobenzyl alcohol, 98%
| 13692-14-3 |
|
4,4'-Bis(dimethylamino)benzil
| 17078-27-2 |
|
(S)-(+)-2-Aminobutane, 98%
| 513-49-5 |
|
Trioctanoin, 98% (gc)
| 538-23-8 |
|
(2R,3R)-1,4-Di-O-Tosyl-2,3-O-Isopropylidene-D-Threitol, 99+%
| 51064-65-4 |
|
Ethyl 2-Hydroxyisobutyrate, 99%
| 80-55-7 |
|
D-(-)-Leucinol, 97% (97+% e.e.)
| 53448-09-2 |
|
gamma-(4-Fluorophenyl)-gamma-butyrolactone 98%
| 51787-96-3 |
|
4-Aminobenzotrifluoride, 99%
| 455-14-1 |
|
2-Iodoanisole, 97%
| 529-28-2 |
|
3,5-Dibromosalicylaldehyde, 98%
| 90-59-5 |
|
Hydrocinnamonitrile, 99+%
| 645-59-0 |
|
Crotonylchloride, Tech., 90%
| 7732-18-5 |
|
N,n'-diphenyl-p-phenylenediamine (pract), 97% (titr.)
| 74-31-7 |
|
Methyl (z)-2-benzoylamino-3-dimethylaminopropenoate, 98%
| 56952-04-6 |
|
1,2-Phenylenediacetic acid, 99%
| 7500-53-0 |
|
6-Fluoro-1,2,3,4-Tetrahydro-2-Methyl-Quinoline, 98%
| 42835-89-2 |
|
4-Ethoxycarbonyloxy-3,5-dimethoxybenzoic acid, 96%
| 18780-67-1 |
|
Palmitic Acid
| 57-10-3 |
|
2-Methylbenzselenazole, 99%
| 2818-88-4 |
|
Octanophenone, 99+%
| 1674-37-9 |
|
Samarium(iii) oxide, 99.9%
| 12060-58-1 |
|
Cholesteryl benzoate, 98%
| 604-32-0 |
|
5-Thio-d-glucose, predominantly alpha-anomer
| 20408-97-3 |
|
Trichloromethanesulfonyl Chloride (Pract)
| 2547-61-7 |
|
4,4'-Bis(Heptyloxy)Azoxybenzene
| 2635-26-9 |
|
2-(P-Tolyl)Pyridine, 94% (GC)
| 4467-06-5 |
|
3,3'-Dithiodipropionic Acid, 99%
| 1119-62-6 |
|
n-Butyllithium, 2.5M solution in hexanes
| 109-72-8 |
|
2-Hydroxy-9-fluorenone, 97%
| 6949-73-1 |
|
(S)-Ethyl 2-Pyrrolidone-5-Carboxylate, 99%
| 7149-65-7 |
|
Copper chromite, catalyst
| 12018-10-9 |
|
1-Cyclopenteneacetonitrile, 95%
| 22734-04-9 |
|
Triisopropanolamine,98%
| 122-20-3 |
|
|