**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 346-06-5 |2-(Trifluoromethyl)benzyl alcohol | 97 | 206-467-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Wash clothing before reuse. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 346-06-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 90 deg C @ 20.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3260g/cm3
Molecular Formula: CF3C6H4CH2OH
Molecular Weight: 176.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acid chlorides, acid anhydrides, oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 346-06-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-(Trifluoromethyl)benzyl alcohol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 346-06-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 346-06-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 346-06-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/21/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Oxododecyl-beta-D-maltoside, 99+%
| 0-01-1 |
|
Ethyl methoxyacetate, 98%
| 3938-96-3 |
|
4,4-Bis(Methylthio)-2-Phenyl-But-1,3-Dien- 1,1-Dicarbonitrile, 98%
| 0-00-1 |
|
2-Ethyl-3-methylpyrazine, 99%
| 15707-23-0 |
|
2,2-Diphenylethylamine, 96%
| 3963-62-0 |
|
1,3-Dioxolane, 99%, Stab. With 50ppm BHT and 100ppm Triethylamine
| 646-06-0 |
|
3,9-Divinyl-2,4,8,10-Tetraoxaspiro 5.5 Undecane, 98%
| 78-19-3 |
|
Ammonium hexafluorotitanate(IV), 99.99%
| 16962-40-6 |
|
Trans, Trans-2,4-Heptadienal, Tech. 85-90% (GC, Total Isomers)
| 4313-03-5 |
|
Picolinic acid, 99%
| 98-98-6 |
|
2-Dodecen-1-Ylsuccinic Anhydride, Mixture of Isomers, Tech. CA 95%
| 26544-38-7 |
|
Anthracene-d10, 99+ atom % d
| 1719-06-8 |
|
3-Fluoroanisole, 99%
| 456-49-5 |
|
(S)-(+)-sec-Butanol, 99%
| 78-92-2 |
|
Acid Blue 80
| 4474-24-2 |
|
Dimethyl 3-Methyl-Trans-1,2-Cyclopropanedicarboxylate, 99%
| 28363-79-3 |
|
1-Butaneboronic acid, 99+%
| 4426-47-5 |
|
1-Methylcyclopentanol, 98%
| 1462-03-9 |
|
2-Amino-2-Methyl-1-Propanol, 99%
| 124-68-5 |
|
Yttrium(III) chloride hexahydrate
| 10025-94-2 |
|
Oxazine 4 Perchlorate, Laser Grade, 99% (UV-Vis)
| 41830-81-3 |
|
exo-2-Norbornyl formate, 99%
| 41498-71-9 |
|
Isobutyryl chloride, 98%
| 79-30-1 |
|
1,2,3-Trimethoxybenzene, 98%
| 634-36-6 |
|
Cobalt(II) chloride, anhydrous, 97%
| 7646-79-9 |
|
Benzyl-d7 chloride, 99+ atom % D
| 100-44-7 |
|
Tetrapentylammonium Chloride, 97% (Titr.)
| 4965-17-7 |
|
[tris(trimethylsilyl)]phosphine, 98%
| 15573-38-3 |
|
Quinoxaline, 99%
| 91-19-0 |
|
Tribromoacetaldehyde, 97%
| 115-17-3 |
|
Dihydro-5-phenyl-5-propyl-4,6(1h.5h)- pyrimidinedione, 99+%
| 59026-31-2 |
|
2-(Trifluoromethyl)benzyl alcohol, 97%
| 346-06-5 |
|
2,3-Dibromobutyric Acid, 98%
| 600-30-6 |
|
N-Tosylpyrrolidone
| 10019-95-1 |
|
1,2,4-Triazole, sodium derivative, tech., 90%
| 41253-21-8 |
|
1,3-Cyclopentanedione, 99%
| 3859-41-4 |
|
2-Phenylbenzothiazole, 97%
| 883-93-2 |
|
Diethylaminosulfur Trifluoride
| 38078-09-0 |
|
Chloro-dimethyl-(pentafluorophenyl)-silane , 98%
| 20082-71-7 |
|
Dicyanobis(1,10-Phenanthroline) Iron, Trihydrate, 99% (Titr.)
| 14768-11-7 |
|
(2-(1,3-Dioxan-2-yl)ethyl)triphenylphosphonium Bromide, 98%
| 69891-92-5 |
|
Diethyl 1,2-Cyclopropanedicarboxylate, 97%
| 20561-09-5 |
|
Isopropenyl chloroformate, 99% (stabilized with 50-100 ppm BHT)
| 57933-83-2 |
|
Crotonic acid, 98%
| 107-93-7 |
|
2'-(Trifluoromethyl)acetophenone, 99%
| 17408-14-9 |
|
4'-Iodoacetophenone, 98%
| 13329-40-3 |
|
Cyclooctane, 99+%
| 292-64-8 |
|
4-Bromo-2-Fluorocinnamic Acid, 97% (GC)
| 149947-19-3 |
|
Nonanoic Acid, 98+% (GC)
| 112-05-0 |
|
Selenium(iv) oxide, 99.999%
| 7446-08-4 |
|
|