**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 38078-09-0 |Diethylaminosulfur trifluoride | 95 | 253-771-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 14 35 5
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Reacts violently with water. Causes severe burns. Heating
may cause an explosion.
Potential Health Effects
Eye:
Causes severe eye burns.
Skin:
Causes skin burns. Substance is readily absorbed through the skin.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Flammable liquid and vapor. Reacts violently with water. Water
hydrolyzes material liberating acidic gas which in contact with metal
surfaces can generate flammable and/or explosive hydrogen gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. Do not expose spill to water. Approach spill
from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not allow water to get into the container
because of violent reaction. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Do not breathe
vapor. Use only with adequate ventilation. Keep away from heat,
sparks and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Store in freezer.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 38078-09-0:
United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: amber - fuming
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 30-32 deg C @ 3 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 23 deg C ( 73.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.316 g/ml
Molecular Formula: C4H10F3NS
Molecular Weight: 161.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Combines vigorously
or explosively with water.
Conditions to Avoid:
Contact with water, excess heat.
Incompatibilities with Other Materials:
Water, strong oxidizing agents, strong acids, strong bases, alcohols.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, oxides of
sulfur, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 38078-09-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diethylaminosulfur trifluoride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: I
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: I
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 14 Reacts violently with water.
R 35 Causes severe burns.
R 5 Heating may cause an explosion.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 38078-09-0: No information available.
Canada
CAS# 38078-09-0 is listed on Canada's DSL List.
CAS# 38078-09-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38078-09-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/03/1998 Revision #3 Date: 7/06/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Oxododecyl-beta-D-maltoside, 99+%
| 0-01-1 |
|
Ethyl methoxyacetate, 98%
| 3938-96-3 |
|
4,4-Bis(Methylthio)-2-Phenyl-But-1,3-Dien- 1,1-Dicarbonitrile, 98%
| 0-00-1 |
|
2-Ethyl-3-methylpyrazine, 99%
| 15707-23-0 |
|
2,2-Diphenylethylamine, 96%
| 3963-62-0 |
|
1,3-Dioxolane, 99%, Stab. With 50ppm BHT and 100ppm Triethylamine
| 646-06-0 |
|
3,9-Divinyl-2,4,8,10-Tetraoxaspiro 5.5 Undecane, 98%
| 78-19-3 |
|
Ammonium hexafluorotitanate(IV), 99.99%
| 16962-40-6 |
|
Trans, Trans-2,4-Heptadienal, Tech. 85-90% (GC, Total Isomers)
| 4313-03-5 |
|
Picolinic acid, 99%
| 98-98-6 |
|
2-Dodecen-1-Ylsuccinic Anhydride, Mixture of Isomers, Tech. CA 95%
| 26544-38-7 |
|
Anthracene-d10, 99+ atom % d
| 1719-06-8 |
|
3-Fluoroanisole, 99%
| 456-49-5 |
|
(S)-(+)-sec-Butanol, 99%
| 78-92-2 |
|
Acid Blue 80
| 4474-24-2 |
|
Dimethyl 3-Methyl-Trans-1,2-Cyclopropanedicarboxylate, 99%
| 28363-79-3 |
|
1-Butaneboronic acid, 99+%
| 4426-47-5 |
|
1-Methylcyclopentanol, 98%
| 1462-03-9 |
|
2-Amino-2-Methyl-1-Propanol, 99%
| 124-68-5 |
|
Yttrium(III) chloride hexahydrate
| 10025-94-2 |
|
Oxazine 4 Perchlorate, Laser Grade, 99% (UV-Vis)
| 41830-81-3 |
|
exo-2-Norbornyl formate, 99%
| 41498-71-9 |
|
Isobutyryl chloride, 98%
| 79-30-1 |
|
1,2,3-Trimethoxybenzene, 98%
| 634-36-6 |
|
Cobalt(II) chloride, anhydrous, 97%
| 7646-79-9 |
|
Benzyl-d7 chloride, 99+ atom % D
| 100-44-7 |
|
Tetrapentylammonium Chloride, 97% (Titr.)
| 4965-17-7 |
|
[tris(trimethylsilyl)]phosphine, 98%
| 15573-38-3 |
|
Quinoxaline, 99%
| 91-19-0 |
|
Tribromoacetaldehyde, 97%
| 115-17-3 |
|
Dihydro-5-phenyl-5-propyl-4,6(1h.5h)- pyrimidinedione, 99+%
| 59026-31-2 |
|
2-(Trifluoromethyl)benzyl alcohol, 97%
| 346-06-5 |
|
2,3-Dibromobutyric Acid, 98%
| 600-30-6 |
|
N-Tosylpyrrolidone
| 10019-95-1 |
|
1,2,4-Triazole, sodium derivative, tech., 90%
| 41253-21-8 |
|
1,3-Cyclopentanedione, 99%
| 3859-41-4 |
|
2-Phenylbenzothiazole, 97%
| 883-93-2 |
|
Diethylaminosulfur Trifluoride
| 38078-09-0 |
|
Chloro-dimethyl-(pentafluorophenyl)-silane , 98%
| 20082-71-7 |
|
Dicyanobis(1,10-Phenanthroline) Iron, Trihydrate, 99% (Titr.)
| 14768-11-7 |
|
(2-(1,3-Dioxan-2-yl)ethyl)triphenylphosphonium Bromide, 98%
| 69891-92-5 |
|
Diethyl 1,2-Cyclopropanedicarboxylate, 97%
| 20561-09-5 |
|
Isopropenyl chloroformate, 99% (stabilized with 50-100 ppm BHT)
| 57933-83-2 |
|
Crotonic acid, 98%
| 107-93-7 |
|
2'-(Trifluoromethyl)acetophenone, 99%
| 17408-14-9 |
|
4'-Iodoacetophenone, 98%
| 13329-40-3 |
|
Cyclooctane, 99+%
| 292-64-8 |
|
4-Bromo-2-Fluorocinnamic Acid, 97% (GC)
| 149947-19-3 |
|
Nonanoic Acid, 98+% (GC)
| 112-05-0 |
|
Selenium(iv) oxide, 99.999%
| 7446-08-4 |
|
|