**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 79-30-1 |Isobutyryl chloride | 98 | 201-194-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes severe burns.The toxicological properties
of this material have not been fully
investigated.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further
exposure.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Containers may explode in the heat of a
fire. Water Reactive. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. May be ignited by heat, sparks, and flame.
Reacts with water to form acidic gases which when in contact with
metal may liberate flammable and/or hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use dry chemical, carbon dioxide,
or alcohol-resistant foam. Do NOT get water inside containers. Do NOT
use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 79-30-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: .07 atm @ 20 deg C
Viscosity: Not available.
Boiling Point: 92 deg C
Freezing/Melting Point: -90 deg C
Autoignition Temperature: Not available.
Flash Point: 7 deg C ( 44.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.0170g/cm3
Molecular Formula: C4H7ClO
Molecular Weight: 106.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 79-30-1: UC3944000
LD50/LC50:
CAS# 79-30-1: Draize test, rabbit, eye: 100 uL/24H Severe.
Rat: LC50 = 11.6-19.0 mg/L
Carcinogenicity:
Isobutyryl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOBUTYRYL CHLORIDE
Hazard Class: 3 (8)
UN Number: 2395
Packing Group: II
IMO
Shipping Name: ISOBUTYRYL CHLORIDE
Hazard Class: 3.2 (8)
UN Number: 2395
Packing Group: II
RID/ADR
Shipping Name: ISOBUTYRYL CHLORIDE
Hazard Class: 3
UN Number: 2395
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 35 Causes severe burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 79-30-1: 1
Canada
CAS# 79-30-1 is listed on Canada's DSL List.
CAS# 79-30-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79-30-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/02/1998 Revision #3 Date: 10/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Oxododecyl-beta-D-maltoside, 99+%
| 0-01-1 |
|
Ethyl methoxyacetate, 98%
| 3938-96-3 |
|
4,4-Bis(Methylthio)-2-Phenyl-But-1,3-Dien- 1,1-Dicarbonitrile, 98%
| 0-00-1 |
|
2-Ethyl-3-methylpyrazine, 99%
| 15707-23-0 |
|
2,2-Diphenylethylamine, 96%
| 3963-62-0 |
|
1,3-Dioxolane, 99%, Stab. With 50ppm BHT and 100ppm Triethylamine
| 646-06-0 |
|
3,9-Divinyl-2,4,8,10-Tetraoxaspiro 5.5 Undecane, 98%
| 78-19-3 |
|
Ammonium hexafluorotitanate(IV), 99.99%
| 16962-40-6 |
|
Trans, Trans-2,4-Heptadienal, Tech. 85-90% (GC, Total Isomers)
| 4313-03-5 |
|
Picolinic acid, 99%
| 98-98-6 |
|
2-Dodecen-1-Ylsuccinic Anhydride, Mixture of Isomers, Tech. CA 95%
| 26544-38-7 |
|
Anthracene-d10, 99+ atom % d
| 1719-06-8 |
|
3-Fluoroanisole, 99%
| 456-49-5 |
|
(S)-(+)-sec-Butanol, 99%
| 78-92-2 |
|
Acid Blue 80
| 4474-24-2 |
|
Dimethyl 3-Methyl-Trans-1,2-Cyclopropanedicarboxylate, 99%
| 28363-79-3 |
|
1-Butaneboronic acid, 99+%
| 4426-47-5 |
|
1-Methylcyclopentanol, 98%
| 1462-03-9 |
|
2-Amino-2-Methyl-1-Propanol, 99%
| 124-68-5 |
|
Yttrium(III) chloride hexahydrate
| 10025-94-2 |
|
Oxazine 4 Perchlorate, Laser Grade, 99% (UV-Vis)
| 41830-81-3 |
|
exo-2-Norbornyl formate, 99%
| 41498-71-9 |
|
Isobutyryl chloride, 98%
| 79-30-1 |
|
1,2,3-Trimethoxybenzene, 98%
| 634-36-6 |
|
Cobalt(II) chloride, anhydrous, 97%
| 7646-79-9 |
|
Benzyl-d7 chloride, 99+ atom % D
| 100-44-7 |
|
Tetrapentylammonium Chloride, 97% (Titr.)
| 4965-17-7 |
|
[tris(trimethylsilyl)]phosphine, 98%
| 15573-38-3 |
|
Quinoxaline, 99%
| 91-19-0 |
|
Tribromoacetaldehyde, 97%
| 115-17-3 |
|
Dihydro-5-phenyl-5-propyl-4,6(1h.5h)- pyrimidinedione, 99+%
| 59026-31-2 |
|
2-(Trifluoromethyl)benzyl alcohol, 97%
| 346-06-5 |
|
2,3-Dibromobutyric Acid, 98%
| 600-30-6 |
|
N-Tosylpyrrolidone
| 10019-95-1 |
|
1,2,4-Triazole, sodium derivative, tech., 90%
| 41253-21-8 |
|
1,3-Cyclopentanedione, 99%
| 3859-41-4 |
|
2-Phenylbenzothiazole, 97%
| 883-93-2 |
|
Diethylaminosulfur Trifluoride
| 38078-09-0 |
|
Chloro-dimethyl-(pentafluorophenyl)-silane , 98%
| 20082-71-7 |
|
Dicyanobis(1,10-Phenanthroline) Iron, Trihydrate, 99% (Titr.)
| 14768-11-7 |
|
(2-(1,3-Dioxan-2-yl)ethyl)triphenylphosphonium Bromide, 98%
| 69891-92-5 |
|
Diethyl 1,2-Cyclopropanedicarboxylate, 97%
| 20561-09-5 |
|
Isopropenyl chloroformate, 99% (stabilized with 50-100 ppm BHT)
| 57933-83-2 |
|
Crotonic acid, 98%
| 107-93-7 |
|
2'-(Trifluoromethyl)acetophenone, 99%
| 17408-14-9 |
|
4'-Iodoacetophenone, 98%
| 13329-40-3 |
|
Cyclooctane, 99+%
| 292-64-8 |
|
4-Bromo-2-Fluorocinnamic Acid, 97% (GC)
| 149947-19-3 |
|
Nonanoic Acid, 98+% (GC)
| 112-05-0 |
|
Selenium(iv) oxide, 99.999%
| 7446-08-4 |
|
|