**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 38870-89-2 |Methoxyacetyl chloride | ca.95% | 254-169-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns. Irritating to eyes and respiratory
system.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Causes eye burns. May cause blindness.
Lachrymator (substance which increases the flow of tears). Contact
with the eyes may cause corneal damage.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes respiratory tract irritation. Causes chemical burns to the
respiratory tract. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Containers may explode in the
heat of a fire. Flammable liquid and vapor. Will form explosive
mixtures with air. Water hydrolyzes material liberating acidic gas
which in contact with metal surfaces can generate flammable and/or
explosive hydrogen gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Contents may
develop pressure upon prolonged storage. Do not breathe dust, vapor,
mist, or gas. Do not get in eyes, on skin, or on clothing. Use only
in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits.
Exposure Limits
CAS# 38870-89-2:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 112 - 113 deg C @ 7
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 28 deg C ( 82.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density: 1.1870g/cm3
Molecular Formula: CH3OCH2COCl
Molecular Weight: 108.52
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, contact with water,
excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 38870-89-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methoxyacetyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 38870-89-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 38870-89-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38870-89-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/06/2000 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aliquat 336
| 5137-55-3 |
|
4,4'-Isopropylidenebis(2-(2,6-Dibromophenoxy)Ethanol), 98%
| 4162-45-2 |
|
4-Benzylpyridine, 97%
| 2116-65-6 |
|
Bis(Dibenzylideneacetone)Palladium
| 32005-36-0 |
|
Lucifer Yellow CH
| 67769-47-5 |
|
1-Oxododecyl-beta-D-glucopyranoside, 99+%
| 64395-92-2 |
|
Alpha Apo Oxytetracycline,"Can be Used as Secondary Standard"
| 18695-01-7 |
|
Dimethyl carbonate, 99%
| 616-38-6 |
|
2-Nitrodiphenylamine, 99% (UV-Vis)
| 119-75-5 |
|
Diethylaluminum iodide, 25 wt% solution in toluene
| 108-88-3 |
|
2,3-Dihydro-2-Thioxo-4-Thiazoleacetic Acid Ethyl Ester, 96% (Titr.)
| 38449-49-9 |
|
Harmol hydrochloride dihydrate
| 40580-83-4 |
|
Iridium, powder, 99.9%
| 7439-88-5 |
|
Phthalimide, Potassium Derivative, 99%
| 1074-82-4 |
|
Phenethyl alcohol, 99%
| 60-12-8 |
|
1,8-Diaminonaphthalene
| 479-27-6 |
|
Ruthenium(III) Chloride Trihydrate
| 13815-94-6 |
|
2-Chloro-6-Fluorobenzaldehyde, 95%
| 387-45-1 |
|
2-Propylpentanoic acid, 99%
| 99-66-1 |
|
Chrysophanic acid
| 481-74-3 |
|
Tetracarbonyldi-Mu-Chlorodirhodium (I)
| 14523-22-9 |
|
4-tert-Butylcalix (8)Arene, 97% (elemental analysis)
| 68971-82-4 |
|
4-Chlorobenzyl cyanide, 98+%
| 140-53-4 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline), 99%
| 13680-35-8 |
|
Dl-lysine monohydrochoride
| 70-53-1 |
|
5-Bromoindole-3-Acetic Acid, 99% (Titr.)
| 40432-84-6 |
|
Guanine, 99+%
| 73-40-5 |
|
3,4-Dimethoxyphenol, 97%
| 2033-89-8 |
|
4-Aminobenzo-18-Crown-6, Sesquihydrate, Hydrochloride, 99% (TLC)
| 0-00-1 |
|
Xylidine ponceau 2r
| 3761-53-3 |
|
DL-N-Acetylhomocysteine Thiolactone, 99%
| 17896-21-8 |
|
2-Methyl-2-Oxazoline, 99% (GC)
| 1120-64-5 |
|
1,3-Diethyl-2-thiourea
| 105-55-5 |
|
Acridine Hydrochloride, 97%
| 17784-47-3 |
|
4-Iodobenzonitrile
| 3058-39-7 |
|
4-Vinylbenzo-15-Crown-5, 97%
| 31943-70-1 |
|
3-Anilinopropionitrile, 98%
| 1075-76-9 |
|
Heptafluorobutyric anhydride, 98+%
| 336-59-4 |
|
Magnesium stearate
| 557-04-0 |
|
Methoxyacetyl chloride, stabilized, ca. 95%
| 38870-89-2 |
|
Poly(styrene), secondary standard m.w. 430.100/m.n. 119.600
| 9003-53-6 |
|
3-Chloropropyl thioacetate, tech., 90+%
| 13012-54-9 |
|
2-Methyl-1-Pentanol, 98.5+%
| 105-30-6 |
|
Alpha-Acetoxy-Isobutyryl Bromide, 91% Balance Chlorine Derivative
| 40635-67-4 |
|
3-Amino-5-Hydroxypyrazole, 98%
| 6126-22-3 |
|
6-Hydroxy-1,3-Benzoxathiol-2-One, 98+%
| 4991-65-5 |
|
Vanadium(III) chloride, 99%
| 7718-98-1 |
|
N-Isopropylhydroxylamine Hydrochloride, 97%
| 50632-53-6 |
|
Methyl 3-chlorobenzoate, 98%
| 2905-65-9 |
|
1-Pyrrolyl-borane, 1m sol in THF.
| 45376-40-7 |
|
|