**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 481-74-3 |Chrysophanic acid | ca.100 | 207-572-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Causes irritation of mucous
membrane. Exposure may cause coughing, breathing difficulty, and
possible pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from oxidizing agents.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 481-74-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: golden yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 196 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: <.1g/100ml @ 18C
Specific Gravity/Density:
Molecular Formula: C15H10O4
Molecular Weight: 254.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 481-74-3: CB6725000
LD50/LC50:
Not available.
Carcinogenicity:
Chrysophanic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 481-74-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 481-74-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 481-74-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aliquat 336
| 5137-55-3 |
|
4,4'-Isopropylidenebis(2-(2,6-Dibromophenoxy)Ethanol), 98%
| 4162-45-2 |
|
4-Benzylpyridine, 97%
| 2116-65-6 |
|
Bis(Dibenzylideneacetone)Palladium
| 32005-36-0 |
|
Lucifer Yellow CH
| 67769-47-5 |
|
1-Oxododecyl-beta-D-glucopyranoside, 99+%
| 64395-92-2 |
|
Alpha Apo Oxytetracycline,"Can be Used as Secondary Standard"
| 18695-01-7 |
|
Dimethyl carbonate, 99%
| 616-38-6 |
|
2-Nitrodiphenylamine, 99% (UV-Vis)
| 119-75-5 |
|
Diethylaluminum iodide, 25 wt% solution in toluene
| 108-88-3 |
|
2,3-Dihydro-2-Thioxo-4-Thiazoleacetic Acid Ethyl Ester, 96% (Titr.)
| 38449-49-9 |
|
Harmol hydrochloride dihydrate
| 40580-83-4 |
|
Iridium, powder, 99.9%
| 7439-88-5 |
|
Phthalimide, Potassium Derivative, 99%
| 1074-82-4 |
|
Phenethyl alcohol, 99%
| 60-12-8 |
|
1,8-Diaminonaphthalene
| 479-27-6 |
|
Ruthenium(III) Chloride Trihydrate
| 13815-94-6 |
|
2-Chloro-6-Fluorobenzaldehyde, 95%
| 387-45-1 |
|
2-Propylpentanoic acid, 99%
| 99-66-1 |
|
Chrysophanic acid
| 481-74-3 |
|
Tetracarbonyldi-Mu-Chlorodirhodium (I)
| 14523-22-9 |
|
4-tert-Butylcalix (8)Arene, 97% (elemental analysis)
| 68971-82-4 |
|
4-Chlorobenzyl cyanide, 98+%
| 140-53-4 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline), 99%
| 13680-35-8 |
|
Dl-lysine monohydrochoride
| 70-53-1 |
|
5-Bromoindole-3-Acetic Acid, 99% (Titr.)
| 40432-84-6 |
|
Guanine, 99+%
| 73-40-5 |
|
3,4-Dimethoxyphenol, 97%
| 2033-89-8 |
|
4-Aminobenzo-18-Crown-6, Sesquihydrate, Hydrochloride, 99% (TLC)
| 0-00-1 |
|
Xylidine ponceau 2r
| 3761-53-3 |
|
DL-N-Acetylhomocysteine Thiolactone, 99%
| 17896-21-8 |
|
2-Methyl-2-Oxazoline, 99% (GC)
| 1120-64-5 |
|
1,3-Diethyl-2-thiourea
| 105-55-5 |
|
Acridine Hydrochloride, 97%
| 17784-47-3 |
|
4-Iodobenzonitrile
| 3058-39-7 |
|
4-Vinylbenzo-15-Crown-5, 97%
| 31943-70-1 |
|
3-Anilinopropionitrile, 98%
| 1075-76-9 |
|
Heptafluorobutyric anhydride, 98+%
| 336-59-4 |
|
Magnesium stearate
| 557-04-0 |
|
Methoxyacetyl chloride, stabilized, ca. 95%
| 38870-89-2 |
|
Poly(styrene), secondary standard m.w. 430.100/m.n. 119.600
| 9003-53-6 |
|
3-Chloropropyl thioacetate, tech., 90+%
| 13012-54-9 |
|
2-Methyl-1-Pentanol, 98.5+%
| 105-30-6 |
|
Alpha-Acetoxy-Isobutyryl Bromide, 91% Balance Chlorine Derivative
| 40635-67-4 |
|
3-Amino-5-Hydroxypyrazole, 98%
| 6126-22-3 |
|
6-Hydroxy-1,3-Benzoxathiol-2-One, 98+%
| 4991-65-5 |
|
Vanadium(III) chloride, 99%
| 7718-98-1 |
|
N-Isopropylhydroxylamine Hydrochloride, 97%
| 50632-53-6 |
|
Methyl 3-chlorobenzoate, 98%
| 2905-65-9 |
|
1-Pyrrolyl-borane, 1m sol in THF.
| 45376-40-7 |
|
|