**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 5137-55-3 |Methyl tricaprylammonium chloride | 85-95 | 225-896-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 5.0 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 68603-15-6 |Alcohols, c6-12 | <10.0 | 271-642-9 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22 36/38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin. Risk of serious
damage to eyes.Hygroscopic (absorbs moisture from the air).Toxic.
Potential Health Effects
Eye:
May result in corneal injury. Causes severe eye irritation and
possible burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns.
Inhalation:
May cause severe respiratory tract irritation and possible burns.
Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution. This liquid
floats on water and may travel to a source of ignition and spread
fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Flush area with dilute (5%) acetic acid, and collect
rinsate for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Use
with adequate ventilation. Use only in a chemical fume hood. Discard
contaminated shoes.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 5137-55-3:
CAS# 7732-18-5:
CAS# 68603-15-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: viscous colorless to pale orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 1500 mPas 30 deg C
Boiling Point: 225 deg C @ 760.00mm Hg
Freezing/Melting Point: -20 deg C
Autoignition Temperature: Not available.
Flash Point: 132 deg C ( 269.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in benzene, chloroform, isopropa
Specific Gravity/Density: .8840g/cm3
Molecular Formula: C25H54ClN
Molecular Weight: 404.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5137-55-3: BR8575000
CAS# 7732-18-5: ZC0110000
CAS# 68603-15-6: AZ0878000
LD50/LC50:
CAS# 5137-55-3: Draize test, rabbit, skin: 0.5 mL Severe; Oral,
mouse: LD50 = 280 mg/kg; Oral, rat: LD50 = 223 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 68603-15-6.
Carcinogenicity:
Methyl tricaprylammonium chloride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Alcohols, c6-12 -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 5137-55-3: 2
CAS# 7732-18-5: No information available.
CAS# 68603-15-6: 1
Canada
CAS# 5137-55-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 68603-15-6 is listed on Canada's DSL List.
CAS# 5137-55-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 68603-15-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5137-55-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 68603-15-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 4/07/1999 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aliquat 336
| 5137-55-3 |
|
4,4'-Isopropylidenebis(2-(2,6-Dibromophenoxy)Ethanol), 98%
| 4162-45-2 |
|
4-Benzylpyridine, 97%
| 2116-65-6 |
|
Bis(Dibenzylideneacetone)Palladium
| 32005-36-0 |
|
Lucifer Yellow CH
| 67769-47-5 |
|
1-Oxododecyl-beta-D-glucopyranoside, 99+%
| 64395-92-2 |
|
Alpha Apo Oxytetracycline,"Can be Used as Secondary Standard"
| 18695-01-7 |
|
Dimethyl carbonate, 99%
| 616-38-6 |
|
2-Nitrodiphenylamine, 99% (UV-Vis)
| 119-75-5 |
|
Diethylaluminum iodide, 25 wt% solution in toluene
| 108-88-3 |
|
2,3-Dihydro-2-Thioxo-4-Thiazoleacetic Acid Ethyl Ester, 96% (Titr.)
| 38449-49-9 |
|
Harmol hydrochloride dihydrate
| 40580-83-4 |
|
Iridium, powder, 99.9%
| 7439-88-5 |
|
Phthalimide, Potassium Derivative, 99%
| 1074-82-4 |
|
Phenethyl alcohol, 99%
| 60-12-8 |
|
1,8-Diaminonaphthalene
| 479-27-6 |
|
Ruthenium(III) Chloride Trihydrate
| 13815-94-6 |
|
2-Chloro-6-Fluorobenzaldehyde, 95%
| 387-45-1 |
|
2-Propylpentanoic acid, 99%
| 99-66-1 |
|
Chrysophanic acid
| 481-74-3 |
|
Tetracarbonyldi-Mu-Chlorodirhodium (I)
| 14523-22-9 |
|
4-tert-Butylcalix (8)Arene, 97% (elemental analysis)
| 68971-82-4 |
|
4-Chlorobenzyl cyanide, 98+%
| 140-53-4 |
|
4,4'-Methylene-Bis-(2,6-Diethylaniline), 99%
| 13680-35-8 |
|
Dl-lysine monohydrochoride
| 70-53-1 |
|
5-Bromoindole-3-Acetic Acid, 99% (Titr.)
| 40432-84-6 |
|
Guanine, 99+%
| 73-40-5 |
|
3,4-Dimethoxyphenol, 97%
| 2033-89-8 |
|
4-Aminobenzo-18-Crown-6, Sesquihydrate, Hydrochloride, 99% (TLC)
| 0-00-1 |
|
Xylidine ponceau 2r
| 3761-53-3 |
|
DL-N-Acetylhomocysteine Thiolactone, 99%
| 17896-21-8 |
|
2-Methyl-2-Oxazoline, 99% (GC)
| 1120-64-5 |
|
1,3-Diethyl-2-thiourea
| 105-55-5 |
|
Acridine Hydrochloride, 97%
| 17784-47-3 |
|
4-Iodobenzonitrile
| 3058-39-7 |
|
4-Vinylbenzo-15-Crown-5, 97%
| 31943-70-1 |
|
3-Anilinopropionitrile, 98%
| 1075-76-9 |
|
Heptafluorobutyric anhydride, 98+%
| 336-59-4 |
|
Magnesium stearate
| 557-04-0 |
|
Methoxyacetyl chloride, stabilized, ca. 95%
| 38870-89-2 |
|
Poly(styrene), secondary standard m.w. 430.100/m.n. 119.600
| 9003-53-6 |
|
3-Chloropropyl thioacetate, tech., 90+%
| 13012-54-9 |
|
2-Methyl-1-Pentanol, 98.5+%
| 105-30-6 |
|
Alpha-Acetoxy-Isobutyryl Bromide, 91% Balance Chlorine Derivative
| 40635-67-4 |
|
3-Amino-5-Hydroxypyrazole, 98%
| 6126-22-3 |
|
6-Hydroxy-1,3-Benzoxathiol-2-One, 98+%
| 4991-65-5 |
|
Vanadium(III) chloride, 99%
| 7718-98-1 |
|
N-Isopropylhydroxylamine Hydrochloride, 97%
| 50632-53-6 |
|
Methyl 3-chlorobenzoate, 98%
| 2905-65-9 |
|
1-Pyrrolyl-borane, 1m sol in THF.
| 45376-40-7 |
|
|