**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4165-60-0 |Nitrobenzene-d5 | 99% | 224-014-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 40 48/23/24 62 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Possible
risks of irreversible effects. Toxic : danger of serious damage to
health by prolonged exposure through inhalation and in contact with
skin. Possible risk of impaired fertility. Toxic to aquatic
organisms; may cause long-term adverse effects in the aquatic
environment.Highly toxic.Combustible liquid.Hygroscopic.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
May be fatal if absorbed through the skin. Absorption into the body
may cause cyanosis.
Ingestion:
May be fatal if swallowed. Effects may be delayed 2 to 4 hours.
Inhalation:
Harmful if inhaled. Effects may be delayed.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis, rapid heart rate, unconsciousness and possible
death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls
of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use water spray to cool fire-exposed containers. In case of fire use
water spray, dry chemical, carbon dioxide, or chemical foam.
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Personal Protective Equipment
Eyes:
Wear chemical goggles and a face shield if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 88 deg C @ 12.00mm Hg
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: slightly soluble in water
Specific Gravity/Density: Not available.
Molecular Formula: C6D5NO2
Molecular Weight: 128.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases, moist
air or water.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4165-60-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitrobenzene-d5 -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: NITROBENZENE
Hazard Class: 6.1
UN Number: 1662
Packing Group: II
IATA
Shipping Name: NITROBENZENE
Hazard Class: 6.1
UN Number: 1662
Packing Group: II
RID/ADR
Shipping Name: NITROBENZENE
Dangerous Goods Code: 6.1(12B)
UN Number: 1662
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 40 Possible risks of irreversible effects.
R 48/23/24 Toxic : danger of serious damage to
health by prolonged exposure through inhalation and in
contact with skin.
R 62 Possible risk of impaired fertility.
R 51/53 Toxic to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident of if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 28A After contact with skin, wash immediately with
plenty of water.
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
WGK (Water Danger/Protection)
CAS# 4165-60-0:
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 4165-60-0 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 4165-60-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/01/1994 Revision #2 Date: 9/02/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(Methyl Sulfoxide)-D6, 99.9 Dtom % Deuterized
| 2206-27-1 |
|
Mucobromic acid, 99+%
| 488-11-9 |
|
Fast blue rr salt - tetrafluoroborate
| 27766-45-6 |
|
Thymol
| 89-83-8 |
|
5-Methyl-3-phenylisoxazole-4-carboxylic acid, 99%
| 1136-45-4 |
|
Tin Metal
| 7440-31-5 |
|
1-Dimethylamino-but-1-en-3-one, 99% (gc)
| 2802-08-6 |
|
Titanium (IV) Oxide Anhydrous
| 13463-67-7 |
|
1,5-Diphenyl-3-pentadienone
| 538-58-9 |
|
Gitoxigenin
| 545-26-6 |
|
Quinaldine, 95% (GC)
| 91-63-4 |
|
Bromelain
| 9001-00-7 |
|
Titanium(IV) chloride
| 7550-45-0 |
|
D,L-selenomethionine, 99+%(tlc)
| 2578-28-1 |
|
4-Phenylpyrimidine, 96%
| 3438-48-0 |
|
6-Methoxy-8-Nitroquinoline, 99%
| 85-81-4 |
|
1-(4'-Bromophenoxy)-1-Ethoxyethane
| 39255-20-4 |
|
4-Fluorophenylhydrazine Hydrochloride, 97%
| 823-85-8 |
|
2,4,6-Trihydroxybenzoic Acid Monohydrate, 95%
| 83-30-7 |
|
4-Amino-2-Butanol, 99+%
| 39884-48-5 |
|
Cobalt(II) Carbonate Hydrate, 47-50% Co (Dry Substance)
| 513-79-1 |
|
N-Fluoro-3,5-Dichloropyridinium Triflate, 90-95%
| 107264-06-2 |
|
1,11-Dibromoundecane, 98+%
| 16696-65-4 |
|
Toluene
| 108-88-3 |
|
Isobutyl nitrite, 94%, stabilized with 0.2% anhydrous potassium
| 542-56-3 |
|
3,4,5-Trimethoxytoluene, 97%
| 6443-69-2 |
|
Benzyltrimethylammonium dichloroiodate, 99%
| 114971-52-7 |
|
Dodecylamine hydrochloride, 99%
| 929-73-7 |
|
5-Chloromethyl-2-Oxazolidinone, 98%
| 22625-57-6 |
|
Malonaldehyde bis(diethyl acetal), 97%
| 122-31-6 |
|
Lithium tri-tert-butoxyaluminohydride, 93- 98%
| 17476-04-9 |
|
5-Norbornene-2,3-dicarboxylic anhydride, 99% (titr.)
| 826-62-0 |
|
3-Carboxy-proxyl, free radical
| 2154-68-9 |
|
4,4-Dimethyl-2-pentanone, 99%
| 590-50-1 |
|
2-(2-Aminothiazole-4-yl)-2-Methoxyiminoacetic Acid, 97%
| 65872-41-5 |
|
3-Fluorobenzaldehyde, 98+%
| 456-48-4 |
|
Nitrobenzene-d5, 99 atom % d
| 4165-60-0 |
|
3-Methoxy-2-nitrobenzoic acid, 99%
| 4920-80-3 |
|
3-Ethyl-2-Methylbenzoxazolium Iodide, 97% (titr.)
| 5260-37-7 |
|
Bicine, 99+%
| 150-25-4 |
|
Dimethylaminoacetonitrile, 98%
| 926-64-7 |
|
Aq 29d
| |
|
S-Propionylthiocholine Iodide, 98%
| 1866-73-5 |
|
Iodomethane-d3, 99+ atom % D
| 74-88-4 |
|
Tricresyl Phosphate
| 78-30-8 |
|
Tetrahydropyran, 99+%
| 142-68-7 |
|
Methylenediphosphonic acid, 98 %
| 1984-15-2 |
|
Flavine-adenine dinucleotide, 96% (uv-vis)
| 146-14-5 |
|
Biphenyldiisopropylsilyl chloride
| |
|
Benzyltributylammonium Bromide, 99%
| 25316-59-0 |
|
|