**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7550-45-0 |Titanium tetrachloride | >99 | 231-441-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes severe eye burns. Lachrymator (substance which increases
the flow of tears). Causes redness and pain.
Skin:
Contact with liquid is corrosive and causes severe burns and
ulceration. Causes redness and pain.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract.
Inhalation:
Effects may be delayed. Causes chemical burns to the respiratory
tract. May cause lung damage. Inhalation may be fatal as a result of
spasm, inflammation, edema of the larynx and bronchi, chemical
pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. SPEEDY ACTION IS CRITICAL!
Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Will react with water to form toxic
and corrosive fumes. May react exothermically with water, causing
liberation of heat and possible spattering of material. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas. Contact with metals may evolve flammable
hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. If water is the only media
available, use in flooding amounts. Do NOT get water inside
containers. Cool containers with flooding quantities of water until
well after fire is out. For small fires, use dry chemical or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Do not flush into a sewer. Clean up spills immediately, observing
precautions in the Protective Equipment section. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Isolate area and deny entry. Provide ventilation. Do not expose
spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not allow water
to get into the container because of violent reaction. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale. Wash clothing
before reuse. Keep from contact with clothing and other combustible
materials. Discard contaminated shoes.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from water. Keep away from metals. Corrosives
area. Keep containers tightly closed. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7550-45-0:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear light yellow
Odor: penetrating odor
pH: Acidic. Forms HCl.
Vapor Pressure: 12 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 136 deg C
Freezing/Melting Point: -24 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Hydrolizes to form hydrochloric acid.
Specific Gravity/Density: 1.726
Molecular Formula: TiCl4
Molecular Weight: 189.71
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Reacts violently with water. Darkens on
exposure to light.
Conditions to Avoid:
Moisture, metals, excess heat.
Incompatibilities with Other Materials:
Alcohols, ammonia, reactive metals, water.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, chloride
fumes, titanium oxychlorides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7550-45-0: XR1925000
LD50/LC50:
CAS# 7550-45-0: Inhalation, mouse: LC50 = 100 mg/m3/2H; Inhalation,
rat: LC50 = 400 mg/m3.
Carcinogenicity:
Titanium tetrachloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TITANIUM TETRACHLORIDE
(forbidden to ship via passenger or cargo air)
Hazard Class: 8
UN Number: 1838
Packing Group: II
IMO
Shipping Name: TITANIUM TETRACHLORIDE
Hazard Class: 8
UN Number: 1838
Packing Group: II
RID/ADR
Shipping Name: TITANIUM TETRACHLORIDE
Hazard Class: 8
UN Number: 1838
Packing group: II
USA RQ: CAS# 7550-45-0: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7550-45-0: 1
Canada
CAS# 7550-45-0 is listed on Canada's DSL List.
CAS# 7550-45-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7550-45-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/29/1998 Revision #3 Date: 4/09/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(Methyl Sulfoxide)-D6, 99.9 Dtom % Deuterized
| 2206-27-1 |
|
Mucobromic acid, 99+%
| 488-11-9 |
|
Fast blue rr salt - tetrafluoroborate
| 27766-45-6 |
|
Thymol
| 89-83-8 |
|
5-Methyl-3-phenylisoxazole-4-carboxylic acid, 99%
| 1136-45-4 |
|
Tin Metal
| 7440-31-5 |
|
1-Dimethylamino-but-1-en-3-one, 99% (gc)
| 2802-08-6 |
|
Titanium (IV) Oxide Anhydrous
| 13463-67-7 |
|
1,5-Diphenyl-3-pentadienone
| 538-58-9 |
|
Gitoxigenin
| 545-26-6 |
|
Quinaldine, 95% (GC)
| 91-63-4 |
|
Bromelain
| 9001-00-7 |
|
Titanium(IV) chloride
| 7550-45-0 |
|
D,L-selenomethionine, 99+%(tlc)
| 2578-28-1 |
|
4-Phenylpyrimidine, 96%
| 3438-48-0 |
|
6-Methoxy-8-Nitroquinoline, 99%
| 85-81-4 |
|
1-(4'-Bromophenoxy)-1-Ethoxyethane
| 39255-20-4 |
|
4-Fluorophenylhydrazine Hydrochloride, 97%
| 823-85-8 |
|
2,4,6-Trihydroxybenzoic Acid Monohydrate, 95%
| 83-30-7 |
|
4-Amino-2-Butanol, 99+%
| 39884-48-5 |
|
Cobalt(II) Carbonate Hydrate, 47-50% Co (Dry Substance)
| 513-79-1 |
|
N-Fluoro-3,5-Dichloropyridinium Triflate, 90-95%
| 107264-06-2 |
|
1,11-Dibromoundecane, 98+%
| 16696-65-4 |
|
Toluene
| 108-88-3 |
|
Isobutyl nitrite, 94%, stabilized with 0.2% anhydrous potassium
| 542-56-3 |
|
3,4,5-Trimethoxytoluene, 97%
| 6443-69-2 |
|
Benzyltrimethylammonium dichloroiodate, 99%
| 114971-52-7 |
|
Dodecylamine hydrochloride, 99%
| 929-73-7 |
|
5-Chloromethyl-2-Oxazolidinone, 98%
| 22625-57-6 |
|
Malonaldehyde bis(diethyl acetal), 97%
| 122-31-6 |
|
Lithium tri-tert-butoxyaluminohydride, 93- 98%
| 17476-04-9 |
|
5-Norbornene-2,3-dicarboxylic anhydride, 99% (titr.)
| 826-62-0 |
|
3-Carboxy-proxyl, free radical
| 2154-68-9 |
|
4,4-Dimethyl-2-pentanone, 99%
| 590-50-1 |
|
2-(2-Aminothiazole-4-yl)-2-Methoxyiminoacetic Acid, 97%
| 65872-41-5 |
|
3-Fluorobenzaldehyde, 98+%
| 456-48-4 |
|
Nitrobenzene-d5, 99 atom % d
| 4165-60-0 |
|
3-Methoxy-2-nitrobenzoic acid, 99%
| 4920-80-3 |
|
3-Ethyl-2-Methylbenzoxazolium Iodide, 97% (titr.)
| 5260-37-7 |
|
Bicine, 99+%
| 150-25-4 |
|
Dimethylaminoacetonitrile, 98%
| 926-64-7 |
|
Aq 29d
| |
|
S-Propionylthiocholine Iodide, 98%
| 1866-73-5 |
|
Iodomethane-d3, 99+ atom % D
| 74-88-4 |
|
Tricresyl Phosphate
| 78-30-8 |
|
Tetrahydropyran, 99+%
| 142-68-7 |
|
Methylenediphosphonic acid, 98 %
| 1984-15-2 |
|
Flavine-adenine dinucleotide, 96% (uv-vis)
| 146-14-5 |
|
Biphenyldiisopropylsilyl chloride
| |
|
Benzyltributylammonium Bromide, 99%
| 25316-59-0 |
|
|