**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 1330-78-5 |Tricresyl phosphate | 99 | 215-548-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 39/23/24/25 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic : danger of very serious irreversible effects through
inhalation, in contact with skin and if swallowed. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.
Potential Health Effects
Eye:
May cause eye irritation. Causes redness and pain.
Skin:
May cause skin irritation. If absorbed, causes symptoms similar to
those of ingestion.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause headache. May cause muscle paralysis, respiratory
failure, and possible death.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
May cause paralysis. Effects may be delayed. May cause adverse
reproductive effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out
with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use water spray, fog or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Avoid ingestion and inhalation. Use only in a
chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 78-30-8:
United Kingdom, WEL - TWA: 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: 0.3 mg/m3 STEL
United States OSHA: 0.1 mg/m3 TWA
Belgium - TWA: 0.1 mg/m3 VLE
France - VME: 0.1 mg/m3 VME
Germany: 0.1 mg/m3 TWA
Germany: Skin absorber
Malaysia: 0.1 mg/m3 TWA
Netherlands: 0.1 mg/m3 MAC
Spain: 0.1 mg/m3 VLA-ED
CAS# 1330-78-5:
Russia: 0.5 mg/m3 TWA (with max 3% o- isomers); 0.1 mg/m3 TWA (wi
more than 3% o- isom
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to pale yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible
Viscosity: 34 cps @ 37.8 deg C
Boiling Point: 410 deg C
Freezing/Melting Point: -30 deg C
Autoignition Temperature: > 500 deg C (> 932.00 deg F)
Flash Point: 210 deg C ( 410.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 530 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.1600 g/ml
Molecular Formula: C21H21O4P
Molecular Weight: 368.36
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 78-30-8: TD0350000
CAS# 1330-78-5: TD0175000
LD50/LC50:
CAS# 78-30-8: Oral, mouse: LD50 = 900 mg/kg; Oral, rat: LD50 = 1160
mg/kg; Skin, rabbit: LD50 = >3700 mg/kg.
CAS# 1330-78-5: Draize test, rabbit, eye: 500 mg/24H Mild; Oral,
mouse: LD50 = 3900 mg/kg; Oral, rat: LD50 = 3 gm/kg.
Not available.
Carcinogenicity:
Triorthocresyl phosphate -
Not listed by ACGIH, IARC, or NTP.
Tricresyl phosphate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRICRESYL PHOSPHATE
Hazard Class: 6.1
UN Number: 2574
Packing Group: II
IMO
Shipping Name: TRICRESYL PHOSPHATE
Hazard Class: 6.1
UN Number: 2574
Packing Group: II
RID/ADR
Shipping Name: TRICRESYL PHOSPHATE
Hazard Class: 6.1
UN Number: 2574
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 39/23/24/25 Toxic : danger of very serious
irreversible effects through inhalation, in contact
with skin and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 78-30-8: No information available.
CAS# 1330-78-5: 2
Canada
CAS# 78-30-8 is listed on Canada's DSL List.
CAS# 1330-78-5 is listed on Canada's DSL List.
CAS# 78-30-8 is listed on Canada's Ingredient Disclosure List.
CAS# 1330-78-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 78-30-8 is listed on the TSCA inventory.
CAS# 1330-78-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #7 Date: 10/20/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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