**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 513-79-1 |Cobalt(II) Carbonate Hydrate | ca 100 | 208-169-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes.Air sensitive.Cancer suspect agent.
Potential Health Effects
Eye:
Causes mild eye irritation.
Skin:
May cause skin irritation. May cause allergic contact dermatitis.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause kidney damage. Effects may
be cumulative. Human fatalities have been reported from acute
poisoning.
Inhalation:
May cause respiratory tract irritation. May cause pulmonary fibrosis
and permanent damage. Systemic intoxication is cumulative and has
been fatal.
Chronic:
Repeated exposure may cause sensitization dermatitis. Cobalt
compounds may cause cancer based upon animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Sweep up, then place into a suitable
container for disposal. Avoid generating dusty conditions. Place
under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Handle under an inert
atmosphere. Store protected from air. Use only in a chemical fume
hood. Wash clothing before reuse.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed. Do not expose to air. Store under an inert
atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 513-79-1:
United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m
TWA (as Co)
United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/
STEL (as Co)
Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co)
Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA
Co)
Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED
Co)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: red-violet
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: practically insoluble
Specific Gravity/Density: 4.1300g/cm3
Molecular Formula: CCoO3.xH2O
Molecular Weight: 118.94
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Oxidizes when
exposed to air.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to air, excess
heat, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents, air.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 513-79-1: FF9450050
LD50/LC50:
CAS# 513-79-1: Oral, rat: LD50 = 640 mg/kg.
Carcinogenicity:
Cobalt(II) Carbonate Hydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 513-79-1: No information available.
Canada
CAS# 513-79-1 is listed on Canada's DSL List.
CAS# 513-79-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 513-79-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/07/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Mucobromic acid, 99+%
| 488-11-9 |
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Fast blue rr salt - tetrafluoroborate
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Thymol
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5-Methyl-3-phenylisoxazole-4-carboxylic acid, 99%
| 1136-45-4 |
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Tin Metal
| 7440-31-5 |
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1-Dimethylamino-but-1-en-3-one, 99% (gc)
| 2802-08-6 |
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Titanium (IV) Oxide Anhydrous
| 13463-67-7 |
|
1,5-Diphenyl-3-pentadienone
| 538-58-9 |
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Gitoxigenin
| 545-26-6 |
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Quinaldine, 95% (GC)
| 91-63-4 |
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Bromelain
| 9001-00-7 |
|
Titanium(IV) chloride
| 7550-45-0 |
|
D,L-selenomethionine, 99+%(tlc)
| 2578-28-1 |
|
4-Phenylpyrimidine, 96%
| 3438-48-0 |
|
6-Methoxy-8-Nitroquinoline, 99%
| 85-81-4 |
|
1-(4'-Bromophenoxy)-1-Ethoxyethane
| 39255-20-4 |
|
4-Fluorophenylhydrazine Hydrochloride, 97%
| 823-85-8 |
|
2,4,6-Trihydroxybenzoic Acid Monohydrate, 95%
| 83-30-7 |
|
4-Amino-2-Butanol, 99+%
| 39884-48-5 |
|
Cobalt(II) Carbonate Hydrate, 47-50% Co (Dry Substance)
| 513-79-1 |
|
N-Fluoro-3,5-Dichloropyridinium Triflate, 90-95%
| 107264-06-2 |
|
1,11-Dibromoundecane, 98+%
| 16696-65-4 |
|
Toluene
| 108-88-3 |
|
Isobutyl nitrite, 94%, stabilized with 0.2% anhydrous potassium
| 542-56-3 |
|
3,4,5-Trimethoxytoluene, 97%
| 6443-69-2 |
|
Benzyltrimethylammonium dichloroiodate, 99%
| 114971-52-7 |
|
Dodecylamine hydrochloride, 99%
| 929-73-7 |
|
5-Chloromethyl-2-Oxazolidinone, 98%
| 22625-57-6 |
|
Malonaldehyde bis(diethyl acetal), 97%
| 122-31-6 |
|
Lithium tri-tert-butoxyaluminohydride, 93- 98%
| 17476-04-9 |
|
5-Norbornene-2,3-dicarboxylic anhydride, 99% (titr.)
| 826-62-0 |
|
3-Carboxy-proxyl, free radical
| 2154-68-9 |
|
4,4-Dimethyl-2-pentanone, 99%
| 590-50-1 |
|
2-(2-Aminothiazole-4-yl)-2-Methoxyiminoacetic Acid, 97%
| 65872-41-5 |
|
3-Fluorobenzaldehyde, 98+%
| 456-48-4 |
|
Nitrobenzene-d5, 99 atom % d
| 4165-60-0 |
|
3-Methoxy-2-nitrobenzoic acid, 99%
| 4920-80-3 |
|
3-Ethyl-2-Methylbenzoxazolium Iodide, 97% (titr.)
| 5260-37-7 |
|
Bicine, 99+%
| 150-25-4 |
|
Dimethylaminoacetonitrile, 98%
| 926-64-7 |
|
Aq 29d
| |
|
S-Propionylthiocholine Iodide, 98%
| 1866-73-5 |
|
Iodomethane-d3, 99+ atom % D
| 74-88-4 |
|
Tricresyl Phosphate
| 78-30-8 |
|
Tetrahydropyran, 99+%
| 142-68-7 |
|
Methylenediphosphonic acid, 98 %
| 1984-15-2 |
|
Flavine-adenine dinucleotide, 96% (uv-vis)
| 146-14-5 |
|
Biphenyldiisopropylsilyl chloride
| |
|
Benzyltributylammonium Bromide, 99%
| 25316-59-0 |
|
|