**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 497-19-8 |Sodium carbonate | 100 | 207-838-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes.
Potential Health Effects
Eye:
May result in corneal injury. Contact with eyes may cause severe
irritation, and possible eye burns.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause irritation of the respiratory tract
with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema.
Chronic:
Prolonged or repeated inhalation may cause nosebleeds, nasal
congestion, erosion of the teeth, perforation of the nasal septum,
chest pain and bronchitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn. Wear appropriate protective
clothing to prevent contact with skin and eyes. Wear a self-contained
breathing apparatus (SCBA) to prevent contact with thermal
decomposition products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water fog, dry chemical, carbon
dioxide or alcohol type foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
Cover with material such as dry soda ash or calcium carbonate and
place into a closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: white
Odor: odorless
pH: 11.6 (solution)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 400 deg C
Freezing/Melting Point: 851 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 400 deg C
Solubility in water: Soluble in water
Specific Gravity/Density: 1.55
Molecular Formula: Na2CO3
Molecular Weight: 105.9778
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Reacts explosively with red-hot alumium metal. Incompatible with
ammonia + silver nitrate, 2,4-dinitrotoluene, 2,4,6-trinitrotoluene,
sulfuric acid, sodium sulfide + water, lithium, phosphorus pentoxide,
fluorine, and hydrogen peroxide. Hot concentrated solutions of sodium
carbonate are mildly corrosive to steel.
Hazardous Decomposition Products:
Carbon dioxide, toxic fumes of sodium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 497-19-8: VZ4050000
LD50/LC50:
CAS# 497-19-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, eye: 50 mg Severe; Draize test, rabbit, skin: 500
mg/24H Mild; Inhalation, mouse: LC50 = 1200 mg/m3/2H; Inhalation,
rat: LC50 = 2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral, rat:
LD50 = 4090 mg/kg.
Carcinogenicity:
Sodium carbonate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 320 mg/L; 96 Hr.; Static
ConditionsCas# 497-19-8
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 497-19-8: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 497-19-8 is listed on Canada's DSL List.
CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 497-19-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/12/1999 Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Propanediol, 99%
| 57-55-6 |
|
Ethyl 2-chloroacetoacetate, 97%
| 609-15-4 |
|
Pyridine, 99+%
| 110-86-1 |
|
Pyridine, nonaqueous titration grade
| 110-86-1 |
|
Pyridine, reagent ACS
| 110-86-1 |
|
2-(4-Sulfophenylazo)1,8-Dihydroxy-3,6-Naphthalenedisulfonic Acid
| 23647-14-5 |
|
trans-4-Phenyl-3-buten-2-one, p.a.
| 1896-62-4 |
|
Pyrogallol, 99%
| 87-66-1 |
|
Quinoline, 96%
| 91-22-5 |
|
Quinoline, synthetic, 99% (gc)
| 91-22-5 |
|
p-Benzoquinone
| 106-51-4 |
|
Resorcinol, 98%
| 108-46-3 |
|
Rubidium Chloride, 99.8+%
| 7791-11-9 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, Toluene Soluble Bags
| 7646-69-7 |
|
Salicylic Acid, 99+%
| 69-72-7 |
|
3-Indazolinone, 97%
| 7364-25-2 |
|
Cellulose Acetate Propionate, Average M.W. 15000
| 9004-39-1 |
|
Cellulose Acetate Propionate, Average M.W. 75000
| 9004-39-1 |
|
Diphenylselenide, 95%
| 1132-39-4 |
|
Silver acetate, 99%
| 563-63-3 |
|
Diethyldithiocarbamic Acid, Silver Salt, 99%
| 1470-61-7 |
|
Silver Iodide, 99.999%
| 7783-96-2 |
|
Silver nitrate, 0.1N standard solution
| 7732-18-5 |
|
Silver nitrate, reagent ACS, electrophoresis grade
| 7761-88-8 |
|
Silver nitrate, ultrapure grade
| 7761-88-8 |
|
Silver(I) oxide, 99+%
| 20667-12-3 |
|
Silver sulfate, 99%
| 10294-26-5 |
|
Acetic Acid, Sodium Salt, Anhydrous, U.S.P./N.F.
| 127-09-3 |
|
Acetic Acid, Sodium Salt, Anhydrous, Reagent acs (crystals)
| 127-09-3 |
|
Acetic acid, sodium salt, trihydrate pure
| 6131-90-4 |
|
Acetic acid, sodium acetate trihydrate, reagent acs (crystals)
| 6131-90-4 |
|
1,3-Diacetoxybenzene, 99%
| 108-58-7 |
|
Sodium Bicarbonate, C.P.
| 144-55-8 |
|
Sodium Bicarbonate, Reagent ACS (Powder)
| 144-55-8 |
|
Sodium Bromide, Anhydrous, 99+%
| 7647-15-6 |
|
Sodium carbonate, anhydrous 99.95 to 100.05%
| 497-19-8 |
|
Sodium Carbonate, Anhydrous Powder, P.A.
| 497-19-8 |
|
Betaine, anhydrous, 98%
| 107-43-7 |
|
Sodium Carbonate, Anhydrous, Reagent ACS (Powder)
| 497-19-8 |
|
Sodium Chloride, P.A.
| 7647-14-5 |
|
Triphenyl phosphite, 97%
| 101-02-0 |
|
Sodium Cyanide, P.A.
| 143-33-9 |
|
Dimethyl malonate, 97%
| 108-59-8 |
|
Sodium fluoride, 97%
| 7681-49-4 |
|
Sodium fluoride, reagent ACS, powder
| 7681-49-4 |
|
Sodium Hydrosulfite, Tech., ca 85%
| 7775-14-6 |
|
Sodium Iodate, P.A.
| 7681-55-2 |
|
Desoxycorticosterone
| 64-85-7 |
|
Sodium metabisulfite, anhydrous, 97%
| 7446-09-5 |
|
Sodium Methoxide, 30 wt% Solution in Methanol
| 67-56-1 |
|
|