**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 609-15-4 |Ethyl 2-chloroacetoacetate | 97 | 210-180-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. May be ignited by
heat, sparks, and flame. Containers may explode when heated.
Combustible liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce
vapors. Water spray may reduce vapor but may not prevent ignition in
closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Take
precautionary measures against static discharges. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 609-15-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: 3.3 (saturated aq. sol.)
Vapor Pressure: 1 mbar @ 20 deg C
Viscosity: Not available.
Boiling Point: 200 deg C
Freezing/Melting Point: -80 deg C
Autoignition Temperature: 220 deg C ( 428.00 deg F)
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: 1.70
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.1900g/cm3
Molecular Formula: C6H9ClO3
Molecular Weight: 164.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids, bases, oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 609-15-4 unlisted.
LD50/LC50:
Not available.
Oral, rat: LD50=402mg/kg.
Carcinogenicity:
Ethyl 2-chloroacetoacetate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.*
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2929
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 609-15-4: 2
Canada
CAS# 609-15-4 is listed on Canada's NDSL List.
CAS# 609-15-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 609-15-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/23/1998 Revision #3 Date: 10/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Propanediol, 99%
| 57-55-6 |
|
Ethyl 2-chloroacetoacetate, 97%
| 609-15-4 |
|
Pyridine, 99+%
| 110-86-1 |
|
Pyridine, nonaqueous titration grade
| 110-86-1 |
|
Pyridine, reagent ACS
| 110-86-1 |
|
2-(4-Sulfophenylazo)1,8-Dihydroxy-3,6-Naphthalenedisulfonic Acid
| 23647-14-5 |
|
trans-4-Phenyl-3-buten-2-one, p.a.
| 1896-62-4 |
|
Pyrogallol, 99%
| 87-66-1 |
|
Quinoline, 96%
| 91-22-5 |
|
Quinoline, synthetic, 99% (gc)
| 91-22-5 |
|
p-Benzoquinone
| 106-51-4 |
|
Resorcinol, 98%
| 108-46-3 |
|
Rubidium Chloride, 99.8+%
| 7791-11-9 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, Toluene Soluble Bags
| 7646-69-7 |
|
Salicylic Acid, 99+%
| 69-72-7 |
|
3-Indazolinone, 97%
| 7364-25-2 |
|
Cellulose Acetate Propionate, Average M.W. 15000
| 9004-39-1 |
|
Cellulose Acetate Propionate, Average M.W. 75000
| 9004-39-1 |
|
Diphenylselenide, 95%
| 1132-39-4 |
|
Silver acetate, 99%
| 563-63-3 |
|
Diethyldithiocarbamic Acid, Silver Salt, 99%
| 1470-61-7 |
|
Silver Iodide, 99.999%
| 7783-96-2 |
|
Silver nitrate, 0.1N standard solution
| 7732-18-5 |
|
Silver nitrate, reagent ACS, electrophoresis grade
| 7761-88-8 |
|
Silver nitrate, ultrapure grade
| 7761-88-8 |
|
Silver(I) oxide, 99+%
| 20667-12-3 |
|
Silver sulfate, 99%
| 10294-26-5 |
|
Acetic Acid, Sodium Salt, Anhydrous, U.S.P./N.F.
| 127-09-3 |
|
Acetic Acid, Sodium Salt, Anhydrous, Reagent acs (crystals)
| 127-09-3 |
|
Acetic acid, sodium salt, trihydrate pure
| 6131-90-4 |
|
Acetic acid, sodium acetate trihydrate, reagent acs (crystals)
| 6131-90-4 |
|
1,3-Diacetoxybenzene, 99%
| 108-58-7 |
|
Sodium Bicarbonate, C.P.
| 144-55-8 |
|
Sodium Bicarbonate, Reagent ACS (Powder)
| 144-55-8 |
|
Sodium Bromide, Anhydrous, 99+%
| 7647-15-6 |
|
Sodium carbonate, anhydrous 99.95 to 100.05%
| 497-19-8 |
|
Sodium Carbonate, Anhydrous Powder, P.A.
| 497-19-8 |
|
Betaine, anhydrous, 98%
| 107-43-7 |
|
Sodium Carbonate, Anhydrous, Reagent ACS (Powder)
| 497-19-8 |
|
Sodium Chloride, P.A.
| 7647-14-5 |
|
Triphenyl phosphite, 97%
| 101-02-0 |
|
Sodium Cyanide, P.A.
| 143-33-9 |
|
Dimethyl malonate, 97%
| 108-59-8 |
|
Sodium fluoride, 97%
| 7681-49-4 |
|
Sodium fluoride, reagent ACS, powder
| 7681-49-4 |
|
Sodium Hydrosulfite, Tech., ca 85%
| 7775-14-6 |
|
Sodium Iodate, P.A.
| 7681-55-2 |
|
Desoxycorticosterone
| 64-85-7 |
|
Sodium metabisulfite, anhydrous, 97%
| 7446-09-5 |
|
Sodium Methoxide, 30 wt% Solution in Methanol
| 67-56-1 |
|
|