**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 91-22-5 |QUINOLINE, SYNTHETIC | 99% | 202-051-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21/22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Irritating to
eyes.Hygroscopic (absorbs moisture from the air).Light
sensitive.Toxic.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury. May
cause retinitis. May cause retinal damage.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. If absorbed, may cause
symptoms similar to those for ingestion. If absorbed, causes
symptoms similar to those of inhalation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory muscle paralysis. Other symptoms include
lethargy, irritation, sore throat, nose bleeds, hoarseness, cough,
chest tightness, difficulty breathing, nausea, vomiting, dizziness,
fever.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not get on skin or
in eyes. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Do not store in direct sunlight. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible
substances. Material darkens in color on storage.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 91-22-5:
Russia: 0.5 mg/m3 TWA
Russia: 0.1 mg/m3 STEL
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow to brown
Odor: Peculiar odor.
pH: Not available.
Vapor Pressure: < 0.1 mbar @ 20
Viscosity: Not available.
Boiling Point: 237.1 deg C
Freezing/Melting Point: -14.78 deg C
Autoignition Temperature: 480 deg C ( 896.00 deg F)
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: 7.00 vol %
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density: 1.0950g/cm3
Molecular Formula: C9H7N
Molecular Weight: 129.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Substance undergoes
color change upon exposure to light and air.
Conditions to Avoid:
Incompatible materials, light, excess heat, exposure to moist air or
water.
Incompatibilities with Other Materials:
Linseed oil + thionyl chloride, perchromates, dinitrogen tetroxide,
hydrogenperoxide, maleic anhydride. May attack some plastics. May be
combustible when exposed to heat or flames.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 91-22-5: VA9275000
LD50/LC50:
CAS# 91-22-5: Draize test, rabbit, skin: 100 mg/24H Moderate; Oral,
rat: LD50 = 331 mg/kg; Skin, rabbit: LD50 = 540 uL/kg.
Carcinogenicity:
QUINOLINE, SYNTHETIC -
California: carcinogen, initial date 10/24/97
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
"Several studies of aquatic toxicity have shown lethal concentrations
in about 10 different types of fish to range from 5 to 50 mg/l. The
toxic threshold in Daphnia is 52 mg/l." (Patty's Industrial Hygiene
and Toxicology, 4th Ed.)
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: QUINOLINE
Hazard Class: 6.1
UN Number: 2656
Packing Group: III
IMO
Shipping Name: QUINOLINE
Hazard Class: 6.1
UN Number: 2656
Packing Group: III
RID/ADR
Shipping Name: QUINOLINE
Hazard Class: 6.1
UN Number: 2656
Packing group: III
USA RQ: CAS# 91-22-5: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 91-22-5: 2
Canada
CAS# 91-22-5 is listed on Canada's DSL List.
CAS# 91-22-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 91-22-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,2-Propanediol, 99%
| 57-55-6 |
|
Ethyl 2-chloroacetoacetate, 97%
| 609-15-4 |
|
Pyridine, 99+%
| 110-86-1 |
|
Pyridine, nonaqueous titration grade
| 110-86-1 |
|
Pyridine, reagent ACS
| 110-86-1 |
|
2-(4-Sulfophenylazo)1,8-Dihydroxy-3,6-Naphthalenedisulfonic Acid
| 23647-14-5 |
|
trans-4-Phenyl-3-buten-2-one, p.a.
| 1896-62-4 |
|
Pyrogallol, 99%
| 87-66-1 |
|
Quinoline, 96%
| 91-22-5 |
|
Quinoline, synthetic, 99% (gc)
| 91-22-5 |
|
p-Benzoquinone
| 106-51-4 |
|
Resorcinol, 98%
| 108-46-3 |
|
Rubidium Chloride, 99.8+%
| 7791-11-9 |
|
Sodium Hydride, 60% Dispersion in Mineral Oil, Toluene Soluble Bags
| 7646-69-7 |
|
Salicylic Acid, 99+%
| 69-72-7 |
|
3-Indazolinone, 97%
| 7364-25-2 |
|
Cellulose Acetate Propionate, Average M.W. 15000
| 9004-39-1 |
|
Cellulose Acetate Propionate, Average M.W. 75000
| 9004-39-1 |
|
Diphenylselenide, 95%
| 1132-39-4 |
|
Silver acetate, 99%
| 563-63-3 |
|
Diethyldithiocarbamic Acid, Silver Salt, 99%
| 1470-61-7 |
|
Silver Iodide, 99.999%
| 7783-96-2 |
|
Silver nitrate, 0.1N standard solution
| 7732-18-5 |
|
Silver nitrate, reagent ACS, electrophoresis grade
| 7761-88-8 |
|
Silver nitrate, ultrapure grade
| 7761-88-8 |
|
Silver(I) oxide, 99+%
| 20667-12-3 |
|
Silver sulfate, 99%
| 10294-26-5 |
|
Acetic Acid, Sodium Salt, Anhydrous, U.S.P./N.F.
| 127-09-3 |
|
Acetic Acid, Sodium Salt, Anhydrous, Reagent acs (crystals)
| 127-09-3 |
|
Acetic acid, sodium salt, trihydrate pure
| 6131-90-4 |
|
Acetic acid, sodium acetate trihydrate, reagent acs (crystals)
| 6131-90-4 |
|
1,3-Diacetoxybenzene, 99%
| 108-58-7 |
|
Sodium Bicarbonate, C.P.
| 144-55-8 |
|
Sodium Bicarbonate, Reagent ACS (Powder)
| 144-55-8 |
|
Sodium Bromide, Anhydrous, 99+%
| 7647-15-6 |
|
Sodium carbonate, anhydrous 99.95 to 100.05%
| 497-19-8 |
|
Sodium Carbonate, Anhydrous Powder, P.A.
| 497-19-8 |
|
Betaine, anhydrous, 98%
| 107-43-7 |
|
Sodium Carbonate, Anhydrous, Reagent ACS (Powder)
| 497-19-8 |
|
Sodium Chloride, P.A.
| 7647-14-5 |
|
Triphenyl phosphite, 97%
| 101-02-0 |
|
Sodium Cyanide, P.A.
| 143-33-9 |
|
Dimethyl malonate, 97%
| 108-59-8 |
|
Sodium fluoride, 97%
| 7681-49-4 |
|
Sodium fluoride, reagent ACS, powder
| 7681-49-4 |
|
Sodium Hydrosulfite, Tech., ca 85%
| 7775-14-6 |
|
Sodium Iodate, P.A.
| 7681-55-2 |
|
Desoxycorticosterone
| 64-85-7 |
|
Sodium metabisulfite, anhydrous, 97%
| 7446-09-5 |
|
Sodium Methoxide, 30 wt% Solution in Methanol
| 67-56-1 |
|
|