**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 50-00-0 |Formaldehyde | 20 | 200-001-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 80 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 20/21/22 36/37/38 43 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. May cause
sensitization by skin contact. May cause cancer.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Vapors may cause
eye irritation. Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. In severe cases may
produce blistering, scaling and cracking. Irritant dermatitis results
from the direct injury to the skin and is characterized by redness
and thickening of the affected areas.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns.
Inhalation:
Harmful if inhaled. Effects may be delayed. May cause asthmatic
attacks due to allergic sensitization of the respiratory tract. May
cause severe irritation of the respiratory tract with sore throat,
coughing, shortness of breath and delayed lung edema.
Chronic:
Contains formaldehyde which can cause cancer in humans. There is
sufficient evidence that formaldehyde causes nasopharyngeal cancer in
humans, a rare cancer in developed countries. There is limited
evidence that formaldehyde causes cancer of the nasal cavity and
paranasal sinuses and strong but not sufficient evidence for
leukemia.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Do not ingest or inhale. Use only with
adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. See 29CFR 1910.1048 for regulatory
requirements pertaining to all occupational exposures to
formaldehyde, i.e., from formaldehyde gas, its solutions, and
materials that release formaldehyde.
Exposure Limits
CAS# 50-00-0:
United Kingdom, WEL - TWA: 2 ppm TWA; 2.5 mg/m3 TWA
United Kingdom, WEL - STEL: 2 ppm STEL; 2.5 mg/m3 STEL
United States OSHA: ; 0.75 ppm TWA; 2 ppm STEL; 0.5 ppm Action Le
(Irritant and potential cancer ha zard - see 29 CFR 1910.1048)
Belgium - STEL: 0.3 ppm VLE; 0.38 mg/m3 VLE
France - VME: 0.5 ppm VME
France - VLE: 1 ppm VLE
Germany: 0.5 ppm TWA; 0.62 mg/m3 TWA
Germany: Skin absorber
Japan: 0.5 ppm OEL; 0.61 mg/m3 OEL
Malaysia: 0.3 ppm Ceiling; 0.37 mg/m3 Ceiling
Netherlands: 2 ppm STEL; 3 mg/m3 STEL
Netherlands: 1 ppm MAC; 1.5 mg/m3 MAC
Russia: 0.5 mg/m3 TWA
Spain: 0.3 ppm VLA-EC; 0.37 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear appropriate
protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 50-00-0: LP8925000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 50-00-0: Draize test, rabbit, eye: 750 ug/24H Severe; Draize
test, rabbit, eye: 750 ug Severe; Draize test, rabbit, eye: 10 mg
Severe; Draize test, rabbit, eye: 37% Severe; Draize test, rabbit,
skin: 2 mg/24H Severe; Draize test, rabbit, skin: 50 mg/24H Moderate;
Inhalation, mouse: LC50 = 454 mg/m3/4H; Inhalation, mouse: LC50 = 505
mg/m3/2H; Inhalation, rat: LC50 = 203 mg/m3; Inhalation, rat: LC50 =
578 mg/m3/2H; Inhalation, rat: LC50 = 250 ppm/2H; Oral, mouse: LD50
= 42 mg/kg; Oral, mouse: LD50 = 385 mg/kg; Oral, mouse: LD50 = 500
mg/kg; Oral, rat: LD50 = 100 mg/kg; Oral, rat: LD50 = 500 mg/kg;
Skin, rabbit: LD50 = 270 uL/kg; Skin, rabbit: LD50 = 270 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Formaldehyde -
ACGIH: A2 - Suspected Human Carcinogen
California: carcinogen, initial date 1/1/88 (gas)
NTP: Suspect carcinogen
IARC: Group 1 carcinogen
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 50-00-0: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 51 Use only in well-ventilated areas.
WGK (Water Danger/Protection)
CAS# 50-00-0: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 50-00-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 50-00-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 50-00-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 43 May cause sensitization by skin contact.
MSDS Creation Date: 7/12/1999 Revision #3 Date: 12/16/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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