**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 590-42-1 |tert-Butyl isothiocyanate | 99.0 | 209-682-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 10 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed.Toxic.Lachrymator (substance which increases the flow of
tears).Moisture sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes severe digestive tract burns with
abdominal pain, vomiting, and possible death.
Inhalation:
Harmful if inhaled. Causes severe respiratory tract irritation.
Inhalation of high concentrations may cause pulmonary edema.
Chronic:
Prolonged or repeated exposure may cause nausea, dizziness, and
headache. Repeated contact may result in skin burns. Prolonged
contact may cause severe eye irritation or burns. Prolonged or
repeated exposure may cause lung irritation, chest pain, and
pulmonary edema.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Do not allow contact with water. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 590-42-1:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 10 deg C
Autoignition Temperature: Not available.
Flash Point: 38 deg C ( 100.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9550g/cm3
Molecular Formula: C5H9NS
Molecular Weight: 115.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, strong bases, alcohols, amines, heat,
moisture.
Hazardous Decomposition Products:
Nitrogen oxides, oxides of sulfur, irritating and toxic fumes and
gases.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 590-42-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl isothiocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.*
Hazard Class: 6.1 (3)
UN Number: 3080
Packing Group: II
IMO
Shipping Name: ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 3080
Packing Group: II
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, FLAMMABLE, N.O.S.
Hazard Class: 6.1
UN Number: 3080
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 590-42-1: No information available.
Canada
CAS# 590-42-1 is listed on Canada's NDSL List.
CAS# 590-42-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 590-42-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Nuclear Fast Red
| 6409-77-4 |
|
5-Sulfosalicylic acid dihydrate, p.a.
| 5965-83-3 |
|
5-Chloro-1-methyl-4-nitroimidazole
| 4897-25-0 |
|
Ethyl 2-ethylacetoacetate
| 607-97-6 |
|
tert-Butyl isothiocyanate, 99% (gc)
| 590-42-1 |
|
2-(4-Chlorosulfonylphenyl)ethyltrimethoxysilane 50% solution in
| 75-09-2 |
|
Methyl 2-Chloropropionate, 96%
| 17639-93-9 |
|
Sulfur, 99.5+%, Refined
| 7704-34-9 |
|
Sulfuric Acid, 95-98%, C.P.
| 7664-93-9 |
|
3-Octylthiophene, 90%
| 65016-62-8 |
|
7-Methoxycoumarin, 98+%
| 531-59-9 |
|
L-allo-Threonine, 99%
| 28954-12-3 |
|
1-(4-Chloromethylphenyl)-2-phenylethane, 98%
| 80676-35-3 |
|
L-Tartaric Acid, Reagent ACS, 99+%
| 87-69-4 |
|
3-Chloro-4-Fluorophenol, 99%
| 2612-57-9 |
|
2-Chloro-2-methylpropane, 99%
| 507-20-0 |
|
Testosterone, 99+% (tlc)
| 58-22-0 |
|
4-(4-Ethoxyphenylazo)-M-Phenylenediamine Monohydrochloride, 98%
| 2313-87-3 |
|
Tert-Amyl Alcohol, P.A.
| 75-85-4 |
|
Sodium amide
| 7782-92-5 |
|
4-(3-Phenylpropyl)pyridine, 97%
| 2057-49-0 |
|
Tetrachloroethylene
| 127-18-4 |
|
Tetradecane
| 629-59-4 |
|
Tetraethylammonium Bromide, 99+%
| 71-91-0 |
|
Tetrahydrofuran, 99+%, Stabilized with 0.025% BHT
| 109-99-9 |
|
Ethyl 3,5-dimethyl-1H-pyrrole-2-carboxylate, 98%
| 2199-44-2 |
|
Tetrahydroxy-P-Benzoquinone, 97% (Titr.)
| 319-89-1 |
|
1,2,3,4-Tetrahydronaphthalene, 95-98%
| 119-64-2 |
|
BOC-L-Phenylalanine, 99+%
| 13734-34-4 |
|
Antimony
| 7440-36-0 |
|
Tetramethylammonium hydroxide pentahydrate
| 75-59-2 |
|
Tetramethylammonium hydroxide, 25% in water
| 75-59-2 |
|
Thallous acetate, 99% (Titr.)
| 563-68-8 |
|
D-Leucine Methyl Ester Hydrochloride, 98%
| 5845-53-4 |
|
Thiamine hydrochloride
| 67-03-8 |
|
Ethyl 2-oxo-4-phenylbutyrate, 97%
| 64920-29-2 |
|
Mercaptoacetic acid, 80% in water
| 68-11-1 |
|
2-Chloromethyl-3,5-dimethyl-4-methoxypyridine hydrochloride
| 86604-75-3 |
|
Thiourea, P.A.
| 62-56-6 |
|
Sebacoyl Chloride, 99% (titr.)
| 111-19-3 |
|
Sodium Perchlorate Monohydrate, P.A.
| 7791-07-3 |
|
2'-Aminoacetophenone, 97% (GC)
| 551-93-9 |
|
1-Naphthoxyacetic acid, 97%
| 2976-75-2 |
|
2-Amino-4,6-dimethoxpyrimidine, 98%
| 36315-01-2 |
|
Carbamazepine, 99%
| 298-46-4 |
|
R-(+)-3-Pyrrolidnol, 98%
| 2799-21-5 |
|
Trimethylene sulfide, 97%
| 287-27-4 |
|
(S)-3-Pyrrolidinol, 99%
| 100243-39-8 |
|
D-(+)-Phenyllactic Acid, 98%
| 7326-19-4 |
|
Potassium trifluoromethanesulfonate, 99%
| 2926-27-4 |
|
|