**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67-03-8 |Thiazolium | 100 | 200-641-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Low hazard for usual industrial handling.
Inhalation:
Dust is irritating to the respiratory tract. May cause respiratory
tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 67-03-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: almost white
Odor: None reported
pH: 2.7-3.4 (at 10 g/l)
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point: 260 deg C
Autoignition Temperature: 365 deg C ( 689.00 deg F)
Flash Point: 100 deg C ( 212.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 260 deg C
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.4
Molecular Formula: C12H17N4OSCl.HCl
Molecular Weight: 300.6582
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation, moisture,
excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of
sulfur, irritating and toxic fumes and gases, carbon dioxide,
nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-03-8: XI7350000
LD50/LC50:
CAS# 67-03-8: Oral, mouse: LD50 = 8224 mg/kg; Oral, rat: LD50 = 3710
mg/kg.
Carcinogenicity:
Thiazolium -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-03-8: 1
Canada
CAS# 67-03-8 is listed on Canada's DSL List.
CAS# 67-03-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-03-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/20/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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3-Octylthiophene, 90%
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7-Methoxycoumarin, 98+%
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L-allo-Threonine, 99%
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4-(4-Ethoxyphenylazo)-M-Phenylenediamine Monohydrochloride, 98%
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| 75-85-4 |
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| 7782-92-5 |
|
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| 2057-49-0 |
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Tetrachloroethylene
| 127-18-4 |
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Tetradecane
| 629-59-4 |
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| 109-99-9 |
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1,2,3,4-Tetrahydronaphthalene, 95-98%
| 119-64-2 |
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BOC-L-Phenylalanine, 99+%
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| 7440-36-0 |
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| 75-59-2 |
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| 5845-53-4 |
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Thiamine hydrochloride
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Ethyl 2-oxo-4-phenylbutyrate, 97%
| 64920-29-2 |
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| 68-11-1 |
|
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| 86604-75-3 |
|
Thiourea, P.A.
| 62-56-6 |
|
Sebacoyl Chloride, 99% (titr.)
| 111-19-3 |
|
Sodium Perchlorate Monohydrate, P.A.
| 7791-07-3 |
|
2'-Aminoacetophenone, 97% (GC)
| 551-93-9 |
|
1-Naphthoxyacetic acid, 97%
| 2976-75-2 |
|
2-Amino-4,6-dimethoxpyrimidine, 98%
| 36315-01-2 |
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| 298-46-4 |
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R-(+)-3-Pyrrolidnol, 98%
| 2799-21-5 |
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| 287-27-4 |
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(S)-3-Pyrrolidinol, 99%
| 100243-39-8 |
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| 7326-19-4 |
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Potassium trifluoromethanesulfonate, 99%
| 2926-27-4 |
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|