**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 119-13-1 | Tocopherol | 0.03 | 204-299-0 |
|----------------|--------------------------------------|----------|-----------|
| 5989-27-5 |d-Limonene | 100 | 227-813-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 10 38 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to skin. May cause sensitization by skin
contact. Very toxic to aquatic organisms; may cause long-term adverse
effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Prolonged and/or repeated contact may cause defatting of the skin and
dermatitis.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
In 2-year gavage studies, there was clear evidence of carcinogenic
activity of d-limonene for male rats, as shown by increased
incidences of tubular cell hyperplasia, adenomas, and adenocarcinomas
of the kidney. There was NO evidence of carcinogenic activity of
d-limonene for female rats, for male mice, or for female mice.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with soap and plenty of
water. Remove contaminated clothing and shoes. Get medical aid if
symptoms occur. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors are heavier than air and may
travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas. This liquid
floats on water and may travel to a source of ignition and spread
fire.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Forms smooth, slippery surfaces on
floors, posing an accident risk. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Avoid contact
with heat, sparks and flame. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Use only with adequate ventilation. Avoid breathing
vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Separate from oxidizing
materials. Partially filled containers should be blanketed with
nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use. Wear a
NIOSH/MSHA or European Standard EN 149 approved
full-facepiece airline respirator in the positive
pressure mode with emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear almost colorless
Odor: citrus-like odor
pH: Not available.
Vapor Pressure: 1.4 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 175-176 deg C @ 760mmHg
Freezing/Melting Point: -74 deg C
Autoignition Temperature: 255 deg C ( 491.00 deg F)
Flash Point: 48 deg C ( 118.40 deg F)
Explosion Limits, lower: .70 vol %
Explosion Limits, upper: 6.10 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8400g/cm3
Molecular Formula: C10H16
Molecular Weight: 136.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 119-13-1 unlisted.
CAS# 5989-27-5: GW6360000
LD50/LC50:
Not available.
CAS# 5989-27-5: Oral, mouse: LD50 = 5600 mg/kg; Oral, rat: LD50 =
4400 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Tocopherol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
d-Limonene -
IARC: Group 3 carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Terpene Hydrocarbons, N.O.S.
Hazard Class: 3
UN Number: 2319
Packing Group: III
IMO
Shipping Name: Terpene Hydrocarbons, N.O.S.
Hazard Class: 3
UN Number: 2319
Packing Group: III
RID/ADR
Shipping Name: Terpene Hydrocarbons, N.O.S.
Dangerous Goods Code: 3
UN Number: 2319
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 60 This material and/or its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
WGK (Water Danger/Protection)
CAS# 119-13-1: No information available.
CAS# 5989-27-5: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 119-13-1 is listed on Canada's DSL List.
CAS# 5989-27-5 is listed on Canada's DSL List.
CAS# 119-13-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 5989-27-5 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 119-13-1 is listed on the TSCA inventory.
CAS# 5989-27-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/21/1998 Revision #3 Date: 8/29/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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