**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 64-17-5 |Ethyl Alcohol | >95% | 200-578-6 |
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methyl alcohol | 3.6% | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 77-09-8 |Phenolphthalein | <1.0 | 201-004-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F
Risk Phrases: 11 20/21/22 68/20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Harmful : possible risk of irreversible effects through
inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause painful sensitization to
light. May cause chemical conjunctivitis and corneal damage.
Methanol is a mild to moderate eye irritant. Inhalation, ingestion
or skin absorption of methanol can cause significant disturbances in
vision, including blindness.
Skin:
Causes moderate skin irritation. Harmful if absorbed through the
skin. May cause cyanosis of the extremities. Methanol can be absorbed
through the skin, producing systemic effects that include visual
disturbances.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause systemic toxicity with
acidosis. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause narcotic
effects in high concentration. Vapors may cause dizziness or
suffocation. Harmful if inhaled.
Chronic:
Possible cancer hazard based on tests with laboratory animals. May
cause reproductive and fetal effects. Laboratory experiments have
resulted in mutagenic effects. Animal studies have reported the
development of tumors. Prolonged exposure may cause liver, kidney,
and heart damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Gently lift eyelids and flush continuously with
water.
Skin:
Get medical aid. Wash clothing before reuse. Flush skin with plenty
of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively. Persons with skin or eye
disorders or liver, kidney, chronic respiratory diseases, or central
and peripheral nervous sytem diseases may be at increased risk from
exposure to this substance.
Antidote:
Replace fluid and electrolytes.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Flammable Liquid. Can release vapors that form
explosive mixtures at temperatures above the flashpoint. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. A vapor suppressing
foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Flammables-area. Do not store
near perchlorates, peroxides, chromic acid or nitric acid.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible
exposure limits.
Exposure Limits
CAS# 64-17-5:
United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA
United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA
Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE
France - VME: 1000 ppm VME; 1900 mg/m3 VME
France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE
Germany: 500 ppm TWA; 960 mg/m3 TWA
Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA
Netherlands: 500 ppm MAC; 1000 mg/m3 MAC
Russia: 1000 mg/m3 TWA
Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 77-09-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: pale-yellow
Odor: Mild, rather pleasant, like wine or whis
pH: Not available.
Vapor Pressure: 59.3 mm Hg @ 20 deg C(ETHANOL)
Viscosity: 1.200 cP @ 20 deg C (Etha
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 13 deg C ( 55.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 0.790@20C (Ethanol)
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alkali metals, ammonia, hydrazine,
peroxides, sodium, acid anhydrides, calcium hypochlorite, chromyl
chloride, nitrosyl perchlorate, bromine pentafluoride, perchloric
acid, silver nitrate, mercuric nitrate, potassium tert-butoxide,
magnesium perchlorate, acid chlorides, platinum, uranium
hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide,
disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride,
permanganic acid, ruthenium (VIII) oxide, uranyl perchlorate,
potassium dioxide.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 64-17-5: KQ6300000
CAS# 67-56-1: PC1400000
CAS# 77-09-8: SM8380000
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat:
LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit:
LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 =
9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 77-09-8.
Carcinogenicity:
Ethyl Alcohol -
Not listed by ACGIH, IARC, or NTP.
Methyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Phenolphthalein -
California: carcinogen, initial date 5/15/98
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @
24-24.3CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling
(Unspecified)Bacteria: Phytobacterium phosphoreum: EC50 = 34900
mg/L; 5-30 min; Microtox testWhen spilled on land it is apt to
volatilize, biodegrade, and leach into the ground water, but no data
on the rates of these processes could be found. Its fate in ground
water is unknown. When released into water it will volatilize and
probably biodegrade. It would not be expected to adsorb to
sediment
or bioconcentrate in fish.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
IMO
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
RID/ADR
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing group: II
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 68/20/21/22 Harmful : possible risk of
irreversible effects through inhalation, in contact
with skin and if swallowed.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 77-09-8: 1
Canada
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 77-09-8 is listed on Canada's DSL List.
CAS# 64-17-5 is listed on Canada's Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 77-09-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 77-09-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 4/20/1998 Revision #8 Date: 10/12/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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