**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 68-12-2 |Dimethylformamide | 1.8 M | 200-679-5 |
|----------------|--------------------------------------|----------|-----------|
| 4861-79-4 |Magnesium Methyl Carbonate | | 225-466-4 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Use agent most appropriate to
extinguish fire. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 68-12-2:
United Kingdom, WEL - TWA: 10 ppm TWA; 30 mg/m3 TWA
United Kingdom, WEL - STEL: 20 ppm STEL; 61 mg/m3 STEL
United States OSHA: 10 ppm TWA; 30 mg/m3 TWA
Belgium - TWA: 10 ppm VLE; 30 mg/m3 VLE
France - VME: 10 ppm VME; 30 mg/m3 VME
Germany: 10 ppm TWA; 30 mg/m3 TWA
Germany: Skin absorber
Japan: 10 ppm OEL; 30 mg/m3 OEL
Malaysia: 10 ppm TWA; 30 mg/m3 TWA
Netherlands: 5 ppm MAC; 15 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 10 ppm VLA-ED; 30 mg/m3 VLA-ED
CAS# 4861-79-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 57 deg C ( 134.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.103
Molecular Formula: C3H6MgO4
Molecular Weight: 130.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 68-12-2: LQ2100000
CAS# 4861-79-4: OM3660000
LD50/LC50:
CAS# 68-12-2: Inhalation, mouse: LC50 = 9400 mg/m3/2H; Inhalation,
rat: LC50 = 3421 ppm/1H; Inhalation, rat: LC50 = 3421 ppm/3H;
Inhalation, rat: LC50 = 1948 ppm/4H; Oral, mouse: LD50 = 2900 mg/kg;
Oral, rabbit: LD50 = 5 gm/kg; Oral, rat: LD50 = 2800 mg/kg; Skin,
rabbit: LD50 = 4720 mg/kg; Skin, rat: LD50 = >3.2 gm/kg.
CAS# 4861-79-4.
Carcinogenicity:
Dimethylformamide -
Not listed by ACGIH, IARC, or NTP.
Magnesium Methyl Carbonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
USA RQ: CAS# 68-12-2: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 68-12-2: 1
CAS# 4861-79-4: No information available.
Canada
CAS# 68-12-2 is listed on Canada's DSL List.
CAS# 4861-79-4 is listed on Canada's NDSL List.
CAS# 68-12-2 is listed on Canada's Ingredient Disclosure List.
CAS# 4861-79-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 68-12-2 is listed on the TSCA inventory.
CAS# 4861-79-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/10/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Butylbenzaldehyde, 98% (GC)
| 1200-14-2 |
|
Propionamide, 97%
| 79-05-0 |
|
4-Nitrobenzenesulfonamide, 97%
| 6325-93-5 |
|
1,1-Dichloroacetone, 98%
| 513-88-2 |
|
N,N-Dimethyltrimethylsilylamine, 97%
| 2083-91-2 |
|
3,6-Bis(2-Hydroxyethyl)-2,5-Diketopiperazine, 98%
| 50975-79-6 |
|
Hexacosanoic Acid, 98% (GC)
| 506-46-7 |
|
S-Benzyl-L-Cysteine, 99%
| 3054-01-1 |
|
Selenium, powder, 99.5+%, 200 mesh
| 7782-49-2 |
|
N-Ethyl-5-phenylisoxazolium-3'-sulfonate, 95%
| 4156-16-5 |
|
Zirconium(IV) chloride, anhydrous, 98%
| 10026-11-6 |
|
Ethyl Malonyl Chloride, Tech., 90+% (titr.)
| 36239-09-5 |
|
Saccharin, sodium salt hydrate, 99+%
| 82385-42-0 |
|
3,4-Dichloronitrobenzene, 95%
| 99-54-7 |
|
Aq 38s
| |
|
Allyl isothiocyanate, 94%
| 57-06-7 |
|
Phenanthrenequinone 95%
| 84-11-7 |
|
5-Fluoro-2-methylaniline, 99%
| 367-29-3 |
|
Magnesium Methyl Carbonate (1.8 M in DMF)
| 68-12-2 |
|
2-Chloro-3(Trifluoromethyl)Pyridine, 98+%
| 65753-47-1 |
|
5-Aminoindan, 96%
| 24425-40-9 |
|
R-(-)-1-Octen-3-Ol, 99%
| 3687-48-7 |
|
Germanium, Pieces, Irregular, 99.999%
| 7440-56-4 |
|
Di-Tert-Butyl Malonate
| 541-16-2 |
|
Adonitol, 99+%
| 488-81-3 |
|
Potassium perrhenate(vii), 99%
| 10466-65-6 |
|
Dl-norphenylephrine hydrochloride, 98%
| 15308-34-6 |
|
4-(4-Chlorophenyl)-4-hydroxypiperidine, 99 +%, crystalline
| 39512-49-7 |
|
1,5-Dihydroxynaphthalene, 99%
| 83-56-7 |
|
2,2-Diethoxyacetamide, 99%
| 61189-99-9 |
|
2,5-Dimethylpyrrolidine, 98%, Cis/Trans Mixture
| 3378-71-0 |
|
(S)-(+)-1,2-Propanediol, 99%
| 57-55-6 |
|
Harmane,98%
| 486-84-0 |
|
4,6-Dimethylpyrimidine, Tech., 93+%
| 1558-17-4 |
|
Diethylaluminum ethoxide, 25 wt% solution in toluene
| 108-88-3 |
|
Ethyl L-Lactate, 97% (GC)
| 687-47-8 |
|
5-Nitroisatin, 97%
| 611-09-6 |
|
3,5-Dihydroxybenzoic Acid, 97%
| 99-10-5 |
|
2-Acetylaminothiazole
| 2719-23-5 |
|
L-Tyrosine Methyl Ester, 98%
| 1080-06-4 |
|
n-Butyl propionate, 99+%
| 590-01-2 |
|
4-Methyl-3-Nitrobenzyl Chloride, 99%
| 84540-59-0 |
|
Methyl 4-Formylbenzoate Dimethyl Acetal, 95.7+% (GC)
| 42228-16-0 |
|
Ethyl palmitate, 98%
| 628-97-7 |
|
Hesperidin,97%
| 520-26-3 |
|
N,N'-bis(p-methoxybenzylidene)-alpha, alpha'-bi-p-toluidine, 99%
| 55290-05-6 |
|
6,7-Dihydroxy-3,4-Dihydroisoquinoline, 98%
| 4602-83-9 |
|
Benzoaza-15-crown-5, 99%
| 0-01-0 |
|
M-Hydroxycinnamic Acid, 99%, Predominantly Trans
| 14755-02-3 |
|
2,5-Dimethoxy-2,5-Dihydrofuran,99%,Cis/Trans Mixture
| 332-77-4 |
|
|