**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 99-54-7 |3,4-Dichloronitrobenzene, 95% | | 202-764-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Provide ventilation. Clean up
residual material by washing area with a 2-5% solution of soda ash.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 99-54-7:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Needles
Color: yellow to brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.01 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 255.0 - 256.0 deg C @ 760.00m
Freezing/Melting Point: 40.50 - 42.00 deg C
Autoignition Temperature: 420 deg C ( 788.00 deg F)
Flash Point: 123 deg C ( 253.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >300 deg C
Solubility in water: 121 PPM @ 20c
Specific Gravity/Density:
Molecular Formula: C6H3Cl2NO2
Molecular Weight: 192.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 99-54-7: CZ5250000
LD50/LC50:
CAS# 99-54-7: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 10
gm/m3/4H; Oral, mouse: LD50 = 1384 mg/kg; Oral, rat: LD50 = 953
mg/kg.
Oral Rat LD50 = 953 mg/kg (Sigma-Aldrich)
Carcinogenicity:
3,4-Dichloronitrobenzene, 95% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 22 Do not breathe dust.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
WGK (Water Danger/Protection)
CAS# 99-54-7: 3
Canada
CAS# 99-54-7 is listed on Canada's DSL List.
CAS# 99-54-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 99-54-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/20/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Butylbenzaldehyde, 98% (GC)
| 1200-14-2 |
|
Propionamide, 97%
| 79-05-0 |
|
4-Nitrobenzenesulfonamide, 97%
| 6325-93-5 |
|
1,1-Dichloroacetone, 98%
| 513-88-2 |
|
N,N-Dimethyltrimethylsilylamine, 97%
| 2083-91-2 |
|
3,6-Bis(2-Hydroxyethyl)-2,5-Diketopiperazine, 98%
| 50975-79-6 |
|
Hexacosanoic Acid, 98% (GC)
| 506-46-7 |
|
S-Benzyl-L-Cysteine, 99%
| 3054-01-1 |
|
Selenium, powder, 99.5+%, 200 mesh
| 7782-49-2 |
|
N-Ethyl-5-phenylisoxazolium-3'-sulfonate, 95%
| 4156-16-5 |
|
Zirconium(IV) chloride, anhydrous, 98%
| 10026-11-6 |
|
Ethyl Malonyl Chloride, Tech., 90+% (titr.)
| 36239-09-5 |
|
Saccharin, sodium salt hydrate, 99+%
| 82385-42-0 |
|
3,4-Dichloronitrobenzene, 95%
| 99-54-7 |
|
Aq 38s
| |
|
Allyl isothiocyanate, 94%
| 57-06-7 |
|
Phenanthrenequinone 95%
| 84-11-7 |
|
5-Fluoro-2-methylaniline, 99%
| 367-29-3 |
|
Magnesium Methyl Carbonate (1.8 M in DMF)
| 68-12-2 |
|
2-Chloro-3(Trifluoromethyl)Pyridine, 98+%
| 65753-47-1 |
|
5-Aminoindan, 96%
| 24425-40-9 |
|
R-(-)-1-Octen-3-Ol, 99%
| 3687-48-7 |
|
Germanium, Pieces, Irregular, 99.999%
| 7440-56-4 |
|
Di-Tert-Butyl Malonate
| 541-16-2 |
|
Adonitol, 99+%
| 488-81-3 |
|
Potassium perrhenate(vii), 99%
| 10466-65-6 |
|
Dl-norphenylephrine hydrochloride, 98%
| 15308-34-6 |
|
4-(4-Chlorophenyl)-4-hydroxypiperidine, 99 +%, crystalline
| 39512-49-7 |
|
1,5-Dihydroxynaphthalene, 99%
| 83-56-7 |
|
2,2-Diethoxyacetamide, 99%
| 61189-99-9 |
|
2,5-Dimethylpyrrolidine, 98%, Cis/Trans Mixture
| 3378-71-0 |
|
(S)-(+)-1,2-Propanediol, 99%
| 57-55-6 |
|
Harmane,98%
| 486-84-0 |
|
4,6-Dimethylpyrimidine, Tech., 93+%
| 1558-17-4 |
|
Diethylaluminum ethoxide, 25 wt% solution in toluene
| 108-88-3 |
|
Ethyl L-Lactate, 97% (GC)
| 687-47-8 |
|
5-Nitroisatin, 97%
| 611-09-6 |
|
3,5-Dihydroxybenzoic Acid, 97%
| 99-10-5 |
|
2-Acetylaminothiazole
| 2719-23-5 |
|
L-Tyrosine Methyl Ester, 98%
| 1080-06-4 |
|
n-Butyl propionate, 99+%
| 590-01-2 |
|
4-Methyl-3-Nitrobenzyl Chloride, 99%
| 84540-59-0 |
|
Methyl 4-Formylbenzoate Dimethyl Acetal, 95.7+% (GC)
| 42228-16-0 |
|
Ethyl palmitate, 98%
| 628-97-7 |
|
Hesperidin,97%
| 520-26-3 |
|
N,N'-bis(p-methoxybenzylidene)-alpha, alpha'-bi-p-toluidine, 99%
| 55290-05-6 |
|
6,7-Dihydroxy-3,4-Dihydroisoquinoline, 98%
| 4602-83-9 |
|
Benzoaza-15-crown-5, 99%
| 0-01-0 |
|
M-Hydroxycinnamic Acid, 99%, Predominantly Trans
| 14755-02-3 |
|
2,5-Dimethoxy-2,5-Dihydrofuran,99%,Cis/Trans Mixture
| 332-77-4 |
|
|