**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 766-39-2 |2,5-Furandione, 3,4-Dimethyl- | 97 | 212-165-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Can produce delayed
pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Do not allow contact with water. Keep from contact with
moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 766-39-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 223 deg C @ 760.00mm Hg
Freezing/Melting Point: 93.00 - 96.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H6O3
Molecular Weight: 126.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 766-39-2: ON4025000
LD50/LC50:
Not available.
Carcinogenicity:
2,5-Furandione, 3,4-Dimethyl- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 766-39-2: No information available.
Canada
CAS# 766-39-2 is listed on Canada's NDSL List.
CAS# 766-39-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 766-39-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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2,4-Difluorobenzaldehyde
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9-Anthracenemethanol, 98%
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Tris(acetoxyethyl)orthoformate
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Diaminoethane tetra-acetic acid trisodium salt solutions (0.01M /
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2-Chloro-P-Phenylenediamine Sulfate, 95%
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| 67-56-1 |
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| 0-01-1 |
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AZ12311148
| 0-01-1 |
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Bis(N,N-diisopropylamino)methoxyphosphine
| 92611-10-4 |
|
(3,4-Dichloro-phenyl)-trimethylsilanyloxy-acetonitrile
| 95392-03-3 |
|
Ammonium-4-Chloro-7-Sulfobenzofurazan
| 81377-14-2 |
|
2-Bromoethyl-4-bromophenyl ether, 98%
| 18800-30-1 |
|
2-Bromovaleryl chloride
| 42768-45-6 |
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2-Pyrid-3-yl-4,5-dihydro-1,3-thiazole-4-carboxylic acid
| 116247-03-1 |
|
2,3-Pyridinedicarboxylic acid, 99%
| 89-00-9 |
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2'-Fluoroacetophenone, 97%
| |
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| 0-01-1 |
|
Chromic acid mix detergent
| 7664-93-9 |
|
Potassium chromate solution, 5% w/v
| 7732-18-5 |
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Acetic acid based buffer
| 64-19-7 |
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N,N'-Dioctadecyloxacarbocyanine p-toluenesulfonate, 99% (uv-vis)
| 60711-74-2 |
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| 4837-90-5 |
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4-Chlorophthalic acid, monosodium salt, tech.
| 56047-23-5 |
|
alpha-D-Glucose pentaacetate, 98%
| 604-68-2 |
|
1-Bromo-2-(2-methoxyethoxy)ethane, 98%
| 54149-17-6 |
|
3,5-Dinitrobenzoic acid, 99%
| 99-34-3 |
|
trans-2,trans-4-Hexadienal, 95%
| 142-83-6 |
|
N-(2-Hydroxyethyl)iminodiacetic acid, 98%
| 93-62-9 |
|
4-Bromobenzo-15-Crown-5, 96%
| 0-00-1 |
|
1-Nitronaphthalene, 99%
| 86-57-7 |
|
Boron Atomic Absorption Standard Solution 1 mg/ml B in Water
| 7440-42-8 |
|
4-Epitetracycline Hydrochloride,"Can be used as Secondary Standard."
| 23313-80-6 |
|
Dowex 50x8-200 Ion-Exchange Resin
| 11119-67-8 |
|
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| 766-39-2 |
|
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| 512-69-6 |
|
Pentaerythritol, 98%
| 115-77-5 |
|
Perfluorooctyl bromide, 99.5+%
| 423-55-2 |
|
Diethyl Iminodiacetate, 99% (GC)
| 6290-05-7 |
|
3-Methylene-2-Norbornanone, 97%
| 5597-27-3 |
|
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| 5402-55-1 |
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| 13076-29-4 |
|
|