3M GENERAL OFFICES -- 3M (TM) ACRYL-GREEN SPOT PUTTY, P.N. 05960, 6
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Material Safety Data Sheet
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MSDS Num: CJHHM
MSDS NAME: 3M (TM) ACRYL-GREEN SPOT PUTTY, P.N. 05960, 60-9800-0588-2
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 800-364-3577
Emergency Phone Number: 651-737-6501
Resp. Party Other MSDS No.: 10-2847-1
Review Ind: Y
Published: Y
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Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
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Ingredients
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Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
% low Wt: 35.
% high Wt: 45.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-3
OSHA STEL: N/K (FP N)
ACGIH TLV: 2 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE
% low Wt: 7.
% high Wt: 13.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM DIOXIDE
% low Wt: 7.
% high Wt: 13.
Other REC Limits: N/K (FP N)
OSHA PEL: 15 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 10 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 9003-01-4
RTECS #: AT4680000
Name: ACRYLIC ACID POLYMERS; (ACRYLIC RESIN)
% low Wt: 7.
% high Wt: 13.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE
% low Wt: 1.
% high Wt: 10.
Other REC Limits: N/K (FP N)
OSHA PEL: see Table Z-2
OSHA STEL: N/K (FP N)
ACGIH TLV: 188 MG/M3;50 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 85-68-7
RTECS #: TH9990000
Name: PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE)
% low Wt: 3.
% high Wt: 7.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Cas: 67-64-1
RTECS #: AL3150000
Name: ACETONE
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: 2400 MG/M3;1000 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 1780 MG/M3;750 PPM
ACGIH STEL: 2380 MG/M3;1000 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 71011-26-2
Name: QUATERNARY AMMONIUM COMPOUNDS, BENZYL(HYDROGENATED TALLOW ALKYL)DIMETHYL,
CHLORIDES, COMPDS. WITH HECTORITE; (TREATED CLAY)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYLBENZENE)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: 435 MG/M3;100 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 543 MG/M3;125 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 80-62-6
RTECS #: OZ5075000
Name: METHYL METHACRYLATE
< Wt: .2
Other REC Limits: N/K (FP N)
OSHA PEL: 410 MG/M3;100 PPM
OSHA STEL: N/K (FP N)
ACGIH TLV: 410 MG/M3;100 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MOD IRRIT, INCL REDNESS, SWELL, PAIN, TEARING, &
HAZY VISION. SKIN: MILD IRRIT (AFTER PRLNG/RPTD CONT), INCL REDNESS, SWELL,
& ITCH. MAY BE ABSORBED THRU SKIN & PRDCE EFTS SIMILAR TO THOSE CAUSE
D BY INHAL &/OR INGEST. INHAL: CNS DEPRESS, INCL HDCH, DIZZ, DROW,
INCOORD, SLOWED RXN TIME, SLURRED SPEECH, GIDD & UNCON. IRRIT (UPPER
RESP), INCL SORENESS OF NOSE & THROAT, COUGH & SNEEZING. DUST FR OM
CUTTING, GRINDING, SANDING/MACHINING MAY CAUSE IRRIT OF RESP SYS. INGEST: MAY
CAUSE IRRIT OF GI TISS, INCL PAIN, VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN
VOMITUS, & BLOOD IN FECES. (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: WHILE THE FOLLOWING EFTS ARE
ASSOC W/ONE OR MORE OF INDIVIDUAL INGS IN THIS PROD & ARE REQUIRED TO BE
INCLUDED ON MSDS BY U.S. OSHA HAZ COMMUNICATION STD, THEY ARE NOT EXPECTED
EFTS DURING F ORESEEABLE USE OF THI PROD. INGEST MAY CAUSE CNS DEPRESS INCL
HDCH, DIZZ, DROW, MUSC WEAK, INCOORD, SLOWED RXN TIME, FATG, BLURRED VISION,
SLURRED SPEECH, GIDD, TREMORS & CONVLS. ASPIR PNEUMIT, INCL C OUGH,
DFCLTY BRTHG, WHEEZING, COUGHING UP BLOOD & PNEUM, WHICH CAN BE FATAL.
WARNING: CONTAINS A CHEM WHICH CAN CAUSE BIRTH DEFECTS (CAS # 108.88.3). (SUP
DAT)
First Aid: EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS OF
WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IN HALATION: REMOVE
PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GET IMMEDIATE MEDICAL ATTENTION. INGESTION: CALL MD
IMMEDIATELY. ONLY INDUCE VOMITING AT INSTRUCTION OF MD. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON.
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Handling and Disposal
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Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFORMATION
REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION,
AND PERSONAL PROTECTIVE EQUIPMENT. VENTILATE AREA. EXTINGUISH ALL IGNIT ION
SOURCES. COLLECT SPILLED MATERIAL. PLACE IN A U.S. DOT-APPROVED CONTAINER.
Waste Disposal Methods: INCINERATE IN A PERMITTED HAZARDOUS WASTE INCINERATOR
IN THE PRESENCE OF A COMBUSTIBLE MATERIAL. DISPOSE OF DRIED SOLIDS IN A
SANITARY LANDFILL. SINCE REGULATIONS VARY, CONSULT APPLICABLE FEDERAL, STA TE
AND LOCAL REGULATIONS OR AUTHORITIES BEFORE DISPOSAL. U.S. EPA HAZARDOUS
WASTE NUMBER= D001 (IGNI TABLE).
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF THE REACH OF CHILDREN.
Other Precautions: FIRE AND EXPLOSION AVOIDANCE: KEEP CONTAINER TIGHTLY CLOSED.
FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME, AND
OTHER SOURCES OF IGNITION.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =17.2C, 63.F
Lower Limits: 1.00%
Upper Limits: 13.00%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: VAPORS MAY TRAVEL LONG DISTANCES ALONG THE
GROUND OR FLOOR TO AN IGNITION SOURCE AND FLASH BACK. NFPA HAZARD CODES:
HEALTH: 2; FIRE: 3; REACTIVITY: 0; UNUSUAL REACTION HAZARD: NONE. OSHA FIRE
HAZARD C LASS: CLASS IB FLAMMABLE LIQUID.
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Control Measures
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Respiratory Protection: AVOID BREATHING OF VAPORS. AVOID BREATHING OF DUST
CREATED BY CUTTING, SANDING OR GRINDING. SELECT ONE OF THE FOLLOWING NIOSH
APPROVED RESPIRATORS BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS AND I N
ACCORDANCE WITH OSHA REGULATIONS: HALF-MASK DUST RESPIRATOR.
Ventilation: PROVIDE APPROP LOC EXHST FOR GRINDING, CUTTING/SANDING CURED MATL.
USE IN WELL-VENTILATED AREA. IF EXHST VENT IS NOT ADEQ, USE APPROP RESP PROT.
Protective Gloves: POLYETHYLENE/ETHYLENE VINYL ALCOHOL, POLYTETRAFLUOROETHYLENE
(SUP DAT)
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N).
Work Hygienic Practices: AVOID EYE CONTACT. AVOID PROLONGED OR REPEATED SKIN
CONTACT. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED
AREAS THOROUGHLY WITH SOAP AND WATER. DO NOT INGEST.
Supplemental Safety and Health: EFTS OF OVEREXP: TOLUENE APPEARS ON THE NAVY
OCCUP CHEM REPRO HAZ LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO (FP N).
PROT GLOVES: (TEFLON), FLUOROELASTOMER (VITON).
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Physical/Chemical Properties
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Spec Gravity: 1.46-1.60 (H*2O=1)
Viscosity: 200000-400000 CENTIPOISE
Solubility in Water: NIL
Appearance and Odor: SMOOTH GREEN PASTE WITH A SOLVENT ODOR.
Percent Volatiles by Volume: 20-30
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE, TOXIC
VAPORS, GASES OR PARTICULATES.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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Ecological: NOT DETERMINED.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL
OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE
III OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND 40
CFR PART 372: TALC, XYLENE, TOLUENE, ETHYLBENZENE, METHYL METHACRYLATE.
Federal Regulatory Information: EPCRA HAZARD CLASS: FIRE HAZARD: YES; PRESSURE:
NO; REACTIVITY: NO; ACUTE: YES; CHRONIC: YES.
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Other Information
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Other Information: VOLATILE ORGANIC COMPOUNDS: 349 GMS/LITER CALCULATED PER
SCAQMD RULE 443.1. VOC LESS H*2O AND EXEMPT SOLVENTS: 368 GMS/LITER
CALCULATED PER SCAQMD RULE 443.1. SKIN NOTATION: LISTED SUBSTANCES INDICAT
ED WITH 'Y' UNDER SKIN REFER TO THE POTENTIAL CONTRIBUTION TO THE OVERALL
EXPOSURE BY THE CUTANEOUS ROUTE INCLUDING MUCOUS MEMBRANE AND EYE, EITHER BY
AIRBORNE OR, MORE PARTICULARLY, BY DIRECT CONTACT WITH THE SUBSTANCE.
VEHICLES CAN ALTER SKIN ABSORPTION. : TOLUENE.
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HAZCOM Label
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MSDS NAME: 3M (TM) ACRYL-GREEN SPOT PUTTY, P.N. 05960, 60-9800-0588-2
Company: MINNESOTA MINING AND MFG CO, DBA 3M
Street: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 651-737-6501
Label Required IND: Y
Date Of Label Review: 04/20/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: EYES: MODERATE IRRITATION; REDNESS,
SWELLING, PAIN, TEARING & HAZY VISION. SKIN: MILD IRRITATION; REDNESS,
SWELLING, & ITCHING. MAY BE ABSORBED THRU SKIN - EFTS SIMILAR TO INHAL
&/ OR INGEST. INHAL: CENTRAL NERVOUS SYSTEM DEPRESSION; HEADACHE,
DIZZINESS, DROWINESS, INCOORDINATION, SLOWED RXN TIME, SLURRED SPEECH,
GIDDINESS & UNCONSCIOUSNESS. IRRIT (UPPER RESP); SORENESS OF NO SE
& THROAT, COUGH & SNEEZING. INGEST: MAYCAUSE IRRITATION OF GI
TISSUE; PAIN, VOMIT, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, &
BLOOD IN FECES. CHRONIC: TOLUENE APPEARS ON THE NAVY OCCUPA TIONAL
CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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