HACH COMPANY -- FERROVER M IRON REAGENT, 21057
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Material Safety Data Sheet
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MSDS Num: CJHQN
MSDS NAME: FERROVER M IRON REAGENT, 21057
Responsible Party
Name: HACH COMPANY
Box: 907
City: AMES IA 50010
Info Phone: 800-227-4224
Emergency Phone Number: 303-623-5716
Resp. Party Other MSDS No.: M00135, CHANGE # 14686
Review Ind: Y
Published: Y
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Contractor Summary
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Name: HACH COMPANY
Address: 100 DAYTON RD.
Box: 907
City: AMES IA 50010
Phone: 800-227-4224
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Ingredients
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Cas: 7772-98-7
RTECS #: XN6476000
Name: THIOSULFURIC ACID, DISODIUM SALT; (SODIUM THIOSULFATE ANHYDROUS)
< Wt: 55.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 7681-57-4
RTECS #: UX8225000
Name: PYROSULFUROUS ACID, DISODIUM SALT; (SODIUM METABISULFITE)
< Wt: 30.
Other REC Limits: N/K (FP N)
OSHA PEL: 5 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 5 MG/M3
ACGIH STEL: N/K (FP N)
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Cas: 7775-14-6
RTECS #: JP2100000
Name: SODIUM HYDROSULFITE
< Wt: 20.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Cas: 68-04-2
RTECS #: GE8300000
Name: CITRIC ACID, TRISODIUM SALT; (SODIUM CITRATE)
< Wt: 10.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Name: 1,10-PHENANTHROLINE-P-TOLUENESULFONIC ACID SALT MFR'S INVALID CAS#
92798-16-0
< Wt: 5.
Other REC Limits: N/K (FP N)
OSHA PEL: N/K (FP N)
OSHA STEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
ACGIH STEL: N/K (FP N)
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THIS PRODUCT MAY BE IRRITATING TO EYES AND RESPIRATORY
TRACT, AND MAY CAUSE ALLERGIC RESPIRATORY TRACT REACTION. ACUTE TOXICITY:
MODERATELY TOXIC. TARGET ORGANS: NOT DETERMINED. CHRONIC TOXICITY: NOT
DETERMINED.
Explanation Of Carcinogenicity: CARCINOGENICITY TESTING WAS CONCLUSIVE FOR AN
INGREDIENT (SODIUM METABISULFITE) OF THIS MIXTURE. IARC LISTED.
Signs And Symptions Of Overexposure: MAY CAUSE EYE AND RESPIRATORY TRACT
IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. INGESTION OF LARGE
AMOUNTS MAY CAUSE DIARRHEA, STOMACH PAIN, AND VOMITING. CAN CAUSE COUGHING,
DIFFICULTY IN BR EATHING, AND CHEST PAIN. SODIUM THIOSULFATE, ANHYDROUS MAY
CAUSE IRRITATION. SODIUM METABISULFITE MAY CAUSE IRRITATION, ALLERGEN,
MODERATELY TOXIC. SODIUM HYDROSULFITE CAUSE MODERATE EYE IRRITATION ,
ALLERGEN. SODIUM CITRATE MAY CAUSE IRRITATION.
1,10-PHENANTHROLINE-P-TOLUENESULFONIC ACID SALT MAY CAUSE IRRITATION.
Medical Cond Aggravated By Exposure: PRE-EXISTING EYES AND RESPIRATORY
CONDITIONS. SOME ASTHMATICS ARE SAID TO BE DANGEROUSLY SENSITIVE TO MINUTE
AMOUNTS OF SULFITE IN FOOD.
First Aid: EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINTUES. CALL
PHYSICIAN. SKIN: WASH WITH SOAP AND PLENTY OF WATER. INGESTION: DO NOT INDUCE
VOMITING. GIVE 1-2 GLASSES OF WATER. CALL A PHYSICIAN IMM EDIATELY. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH
AIR. GIVE ARTIFICIAL RESPIRATION IF NECESSARY. CALL PHYSICIAN.
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Handling and Disposal
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Spill Release Procedures: SCOOP SPILLED MATERIAL INTO A BEAKER AND DISSOLVE
WITH WATER. NEUTRALIZE TO A PH BETWEEN 6 AND 9 WITH AN ALKALI SUCH AS SODA
ASH. FLUSH NEUTRALIZED WASTE TO THE DRAIN WITH AN EXCESS OF WATER.
Neutralizing Agent: ALKALI SUCH AS SODA ASH.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND
LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY, DARK PLACE. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE DUST.
Other Precautions: SPECIAL NOTE: SULFITES ARE STRONG SENSITIZERS. INHALATION
AND INGESTION CAN CAUSE ALLERGIC RESPIRATORY REACTIONS IN ASTHMATICS. PERSONS
WITH RESPIRATORY CONDITIONS SHOULD TAKE SPECIAL CARE WHEN WORKIN G WITH
PRODUCTS THAT CONTAIN SULFITES.
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Fire and Explosion Hazard Information
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Extinguishing Media: DRY CHEMICAL, ALCOHOL FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: SODIUM HYDROSULFITE IS A FLAMMABLE SOLID. HEATS
SPONTANEOUSLY IN CONTACT WITH WATER; MAY REACT WITH OXIDIZERS. SUSCEPTIBLITY
TO SPONTANEOUS HEATING: IN CONTACT WITH WATER AND AIR. SHOCK SENSITIVITY: N
ONE. NFPA CODES: HEALTH: 2; FLAMMABILITY: 0; REACTIVITY: 1.
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Protective Gloves: DISPOSABLE LATEX GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
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Physical/Chemical Properties
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Melt/Freeze Pt: =192.C, 377.6F
M.P/F.P Text: DECOMPOSES
Spec Gravity: 2.27
PH: 5% SOL'N=5.29
Solubility in Water: SOLUBLE
Appearance and Odor: SOLID WHITE POWDER WITH SO*2 ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH EXTREME HEAT OR FLAMES, EXCESS
MOISTURE, EXPOSURE TO LIGHT.
Materials To Avoid: CONTACT WITH WATER, ACIDS, COMBUSTIBLES, ORGANICS OR
OXIDIZERS, SODIUM NITRITE, ALUMINUM POWDER.
Hazardous Decomposition Products: TOXIC FUMES OF SO*X, NA*2O IN FIRE; CORROSIVE
FUMES IN CONTACT WITH WATER OR ACID.
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Toxicological Information
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Toxicological Information: AN INGREDIENT OF THIS MIXTURE IS AN EXPERIMENTAL
MUTAGEN.
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Ecological Information
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MSDS Transport Information
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Transport Information: D.O.T.: PROPER SHIPPING NAME: NOT CURRENTLY REGULATED;
HAZARD CLASS: N/A; ID: N/A; GROUP: N/A. I.C.A.O.: PROPER SHIPPING NAME: NOT
CURRENTLY REGULATED; HAZARD CLASS: N/A; ID: N/A; GROUP: N/A. I.M.O.: PROPER
SHIPPING NAME: NOT CURRENTLY REGULATED; HAZARD CLASS: N/A; ID: N/A; GROUP:
N/A.
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Regulatory Information
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Sara Title III Information: NO INGREDIENTS LISTED.
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Other Information
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Other Information: PHYSICAL DATA: ACID: NOT DETERMINED; METAL
CORROSIVITY-ALUMINUM: 0.003 IN/YR; STEEL: 0.106 IN/YR. REFERENCES: 1) TLV'S
THRESHOLD LIM VALUES & BIOLOGICAL EXPOS INDICES FOR 1988-1989. AMERICAN
CONFERENC E OF GOVERNMENTAL INDUS HYGIENISTS, 1988. 2) AIR CONTAMINANTS, FED
REGISTER, VOL 54, # 12, THURSDAY, JANUARY 19, 1989. PP. 2332-2983. 3)
IN-HOUSE INFO. 4) TECHNICAL JUDGMENT. 5) OUTSIDE TESTING. 6) GO SSELIN, R.E.
ET AL-CLINICAL TOXICOLOGY OF COMMERCIAL PRODS, 5TH ED. BALTIMORE: THE
WILLIAMS & WILKINS CO., 1984. 7) IARC MONOGRAPHS ON EVALUATION OF CARCIN
RISK TO HUMANS, WORLD HLTH ORGANIZATION (VOL 54) 1992, FRANCE.
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HAZCOM Label
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MSDS NAME: FERROVER M IRON REAGENT, 21057
Company: HACH COMPANY
Street: 100 DAYTON RD.
PO Box: 907
City: AMES IA
Zipcode: 50010
Health Emergency Phone: 303-623-5716
Label Required IND: Y
Date Of Label Review: 05/03/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: THIS PRODUCT MAY BE IRRITATING TO EYES AND
RESPIRATORY TRACT, AND MAY CAUSE ALLERGIC RESPIRATORY TRACT REACTION. ACUTE
TOXICITY: MODERATELY TOXIC. INGESTION OF LARGE AMOUNTS MAY CAUSE DIARRHEA ,
SOTMACH PAIN, AND VOMITING. CAN CAUSE COUGHING, DIFFICULTY IN BREATHING, AND
CHEST PAIN. TARGET ORGANS: NOT DETERMINED. CHRONIC TOXICITY: MAY CAUSE
ALLERGIC RESPIRATORY TRACT REACTION. NOT DETERMIN ED.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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